Skip to main content

Advertisement

Log in

Effect of Minor Er on the Microstructure and Properties of Al-6.0Mg-0.4Mn-0.1Cr-0.1Zr Alloys

  • Published:
Journal of Materials Engineering and Performance Aims and scope Submit manuscript

Abstract

As-cast Al-6.0Mg-0.4Mn-0.1Cr-0.1Zr alloys containing different additions of Er were prepared. Then, the specimens were carried out homogenization heat treatment, hot rolling, cold rolling, and annealing. The effects of minor Er on the microstructure and properties of Al-6.0Mg-0.4Mn-0.1Cr-0.1Zr alloy were investigated. Results show that addition of Er can refine the microstructure and improve the mechanical properties of the alloys. As for the annealed alloys, the addition of 0.33%Er can increase the tensile strength by 29 MPa. Strength increment is mainly attributed to refinement and the precipitation of Al3Er and Al3(Er, Zr). Additionally, the minor Er can improve the corrosion resistance of the alloys, which can be attributed to the compact composite oxide film of Er-O and Al-O, purification, and modification.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. D.K. Xu, P.A. Rometsch, and N. Birbilis, Improved Solution Treatment for an As-Rolled Al-Zn-Mg-Cu Alloy. Part I. Characterisation of Constituent Particles and Overheating, Mater. Sci. Eng. A, 2012, 534, p 234–243

    Article  CAS  Google Scholar 

  2. D.K. Xu, P.A. Rometsch, and N. Birbilis, Improved Solution Treatment for an As-Rolled Al-Zn-Mg-Cu Alloy. Part II. Microstructure and Mechanical Properties, Mater. Sci. Eng. A, 2012, 534, p 244–252

    Article  CAS  Google Scholar 

  3. B.J. Wang, D.K. Xu, J.H. Dong, and W. Ke, Effect of Texture on Biodegradable Behavior of an As-Extruded Mg-3% Al-1% Zn Alloy in Phosphate Buffer Saline Medium, J. Mater. Sci. Technol., 2016, 32, p 646–652

    Article  Google Scholar 

  4. S. Lathabai and P.G. Lloyd, The Effect of Scandium on the Microstructure, Mechanical Properties and Weldability of a Cast Al-Mg Alloy, Acta Mater., 2002, 50(17), p 4275–4292

    Article  CAS  Google Scholar 

  5. R.G. Guan, Y.F. Shen, Z.Y. Zhao, and X. Wang, A high-Strength, Ductile Al-0.35Sc-0.2Zr Alloy with Good Electrical Conductivity Strengthened by Coherent Nanosized-Precipitates, J. Mater. Sci. Technol., 2016, 33, p 215–223

    Article  Google Scholar 

  6. A. Medjahed, A. Henniche, M. Derradji, T.F. Yu, Y. Wang, R.Z. Wu, L.G. Hou, J.H. Zhang, X.L. Li, and M.L. Zhang, Effects of Cu/Mg Ratio on the Microstructure, Mechanical and Corrosion Properties of Al-Li-Cu-Mg-X Alloys, Mater. Sci. Eng. A, 2018, 718, p 241–249

    Article  CAS  Google Scholar 

  7. Y. Wang, Z. Li, T.F. Yu, A. Medjahed, R.Z. Wu, L.G. Hou, J.H. Zhang, X.L. Li, and M.L. Zhang, Effect of Sc and Zr on Microstructure and Mechanical Properties of As-Cast Al-Li-Cu Alloys, Adv. Eng. Mater., 2017, https://doi.org/10.1002/adem.201700898

    Article  Google Scholar 

  8. A. Medjahed, H. Moula, A. Zegaoui, M. Derradji, A. Henniche, R.Z. Wu, L.G. Hou, J.H. Zhang, and M.L. Zhang, Influence of the Rolling Direction on the Microstructure, Mechanical, Anisotropy and Gamma Rays Shielding Properties of an Al-Cu-Li-Mg-X Alloy, Mater. Sci. Eng. A, 2018, 732, p 129–137

    Article  CAS  Google Scholar 

  9. M. Song, K. Du, Z.Y. Huang, H. Huang, and Z.R. Nie, Deformation-Induced Dissolution and Growth of Precipitates in an Al-Mg-Er Alloy During High-Cycle Fatigue, Acta Mater., 2014, 81, p 409–419

    Article  CAS  Google Scholar 

  10. H.Y. Li, J. Bin, J.J. Liu, and Z.H. Gao, Synergetic Effect of Er and Zr on the Precipitation Hardening of Al-Er-Zr Alloy, Scr. Mater., 2012, 67(1), p 73–76

    Article  CAS  Google Scholar 

  11. D. Zhemchuzhnikova, A. Mogucheva, and R. Kaibyshev, Mechanical Properties and Fracture Behavior of an Al-Mg-Sc-Zr Alloy at Ambient and Subzero Temperatures, Mater. Sci. Eng. A, 2013, 565, p 132–141

    Article  CAS  Google Scholar 

  12. K.B. Hyde, A.F. Norman, and P.B. Prangnell, The Effect of Cooling Rate on the Morphology of Primary AlSc Intermetallic Particles in Al-Sc Alloys, Acta Mater., 2011, 49(8), p 1327–1337

    Article  Google Scholar 

  13. Y.L. Liu, L. Luo, C.F. Han, L.Y. Ou, J.J. Wang, and C.Z. Liu, Effect of Fe, Si and Cooling Rate on the Formation of Fe- and Mn-Rich Intermetallics in Al-5Mg-0.8Mn Alloy, J. Mater. Sci. Technol., 2015, 32(4), p 305–312

    Article  CAS  Google Scholar 

  14. H.Y. Li, Z.H. Gao, H. Yin, H.F. Jiang, X.J. Su, and J. Bin, Effects of Er and Zr Additions on Precipitation and Recrystallization of Pure Aluminum, Scr. Mater., 2013, 68, p 59–62

    Article  CAS  Google Scholar 

  15. S.P. Wen, Z.B. Xing, H. Huang, B.L. Li, W. Wang, and Z.R. Nie, The Effect of Erbium on the Microstructure and Mechanical Properties of Al-Mg-Mn-Zr Alloy, Mater. Sci. Eng. A, 2009, 56, p 42–49

    Article  Google Scholar 

  16. X.L. Ji, Z.R. Nie, and Z.B. Xing, Effects of Rare Earth Er on As-Cast Microstructure of Al-Mg Alloy, Light Alloy Fabr. Technol., 2005, 33(10), p 19–21

    Google Scholar 

  17. H. Pan, Z. Han, and B. Liu, Study on Dendritic Growth in Pressurized Solidification of Mg-Al Alloy Using Phase Field Simulation, J. Mater. Sci. Technol., 2015, 32(1), p 68–75

    Article  Google Scholar 

  18. M.J. Jones and F.J. Humphreys, Interaction of Recrystallization and Precipitation: the Effect of Al3Sc on the Recrystallization Behaviour of Deformed Aluminium, Acta Mater., 2003, 51(8), p 2149–2159

    Article  CAS  Google Scholar 

  19. J.D. Robson, Modelling the Overlap of Nucleation, Growth and Coarsening During Precipitation, Acta Mater., 2004, 52(15), p 4669–4676

    Article  CAS  Google Scholar 

  20. Z.H. Gao, H.Y. Li, Y.Q. Lai, Y.X. Ou, and D.W. Li, Effects of Minor Zr and Er on Microstructure and Mechanical Properties of Pure Aluminum, Mater. Sci. Eng. A, 2013, 580(10), p 92–98

    Article  CAS  Google Scholar 

  21. J. Beretka, M.J. Ridge, Dehydration Products of Aluminium Hydroxides, J. Chem. Soc. A, 1967, 6, p 2106–2109

    Article  Google Scholar 

  22. M.X. Gong, L.J. Yan, Y.J. Wang, and H. Du, Study on Seawater Corrosion Resisting Properties of Al-Mg-RE Alloy Gauze, J. Rare Earth, 1999, 18(4), p 248–253

    CAS  Google Scholar 

  23. S. Jain, M.L.C. Lim, J.L. Hudson, and J.R. Scully, Spreading of Intergranular Corrosion on the Surface of Sensitized Al-4.4Mg Alloys: A General Finding, Corros. Sci., 2012, 59(3), p 136–147

    Article  CAS  Google Scholar 

  24. F. Rosalbino, E. Angelini, D.S. Negri, A. Saccone, and S. Delfino, Influence of the Rare Earth Content on the Electrochemical Behaviour of Al-Mg-Er Alloys, Intermetallics, 2003, 11(5), p 435–441

    Article  CAS  Google Scholar 

  25. Y.S. Ding, The Effect of Mg Content on Intergranular Corrosion of Al-Mg-Mn Alloys After Annealing, Mater. Sci. Forum, 2016, 877, p 514–521

    Article  Google Scholar 

Download references

Acknowledgments

This paper was supported by National Natural Science Foundation (51671063, 51771060), Heilongjian Province Natural Science Foundation (ZD2017010), the Fundamental Research Funds for the Central Universities (HEUCFG201834), Harbin City Application Technology Research and Development Project (2015AE4AE005, 2015RQXXJ001, 2016AB2AG013), and Key Laboratory of Lightweight and High Strength Structural Materials of Jiangxi Province (No. 2017BCD40003).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ruizhi Wu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chen, H., Yu, T., Qi, Z. et al. Effect of Minor Er on the Microstructure and Properties of Al-6.0Mg-0.4Mn-0.1Cr-0.1Zr Alloys. J. of Materi Eng and Perform 27, 5709–5717 (2018). https://doi.org/10.1007/s11665-018-3678-y

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11665-018-3678-y

Keywords

Navigation