Abstract
The microstructure, tensile properties, and corrosion behavior of die-cast Mg-7Al-1Ca-xSn (x = 0, 0.5, 1.0, and 2.0 wt.%) alloys were studied using OM, SEM/EDS, tensile test, weight loss test, and electrochemical test. The experimental results showed that Sn addition effectively refined grains and intermetallic phases and increased the amount of intermetallic phases. Meanwhile, Sn addition to the alloys suppressed the formation of the (Mg,Al)2Ca phase and resulted in the formation of the ternary CaMgSn phase and the binary Mg2Sn phase. The Mg-7Al-1Ca-0.5Sn alloy exhibited best tensile properties at room temperature, while Mg-7Al-1Ca-1.0Sn alloy exhibited best tensile properties at elevated temperature. The corrosion resistance of studied alloys was improved by the Sn addition, and the Mg-7Al-1Ca-0.5Sn alloy presented the best corrosion resistance.
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References
A.A. Luo, Magnesium Casting Technology for Structural Applications, J. Magnes. Alloys, 2013, 1, p 2–22
K. Strobel, M.A. Easton, V. Tyagi, M. Murray, M.A. Gibson, G. Savage, and T.B. Abbott, Evaluation of Castability of High Pressure Die Cast Magnesium Based Alloys, Int. J. Cast Met. Res., 2010, 23, p 81–91
M. Liu, P.J. Uggowitzer, A.V. Nagasekhar, P. Schmutz, M. Easton, G.L. Song, and A. Atrens, Calculated Phase Diagrams and the Corrosion of Die-cast Mg-Al Alloys, Corros. Sci., 2009, 51, p 602–619
C.H. Cáceres, J.R. Griffiths, C.J. Davidson, and C.L. Newton, Effects of Solidification Rate and Ageing on the Microstructure and Mechanical Properties of AZ91 Alloy, Mater. Sci. Eng. A, 2002, 325, p 344–355
A.A. Luo, Recent Magnesium Alloy Development for Elevated Temperature Applications, Int. Mater. Rev., 2004, 49, p 13–30
B. Kondori and R. Mahmudi, Impression Creep Characteristics of A Cast Mg Alloy, Metall. Mater. Trans. A, 2009, 40, p 2007–2015
Y.C. Zhang, L. Yang, J. Dai, G.L. Guo, and Z. Liu, Effect of Ca and Sr on Microstructure and Compressive Creep Property of Mg-4Al-RE Alloys, Mater. Sci. Eng. A, 2014, 610, p 309–314
B.H. Kim, S.W. Lee, Y.H. Park, and I.M. Park, The Microstructure, Tensile Properties, and Creep Behavior of AZ91, AS52 and TAS652 Alloy, J. Alloys Compd., 2010, 493, p 502–506
B. Kondori and R. Mahmudi, Effect of Ca Additions on the Microstructure, Thermal Stability and Mechanical Properties of a Cast AM60 Magnesium Alloy, Mater. Sci. Eng. A, 2010, 527, p 2014–2021
J. Bai, Y.S. Sun, S. Xun, F. Xue, and T.B. Zhu, Microstructure and Tensile Creep Behavior of Mg-4Al Based Magnesium Alloys with Alkaline-Earth Elements Sr and Ca Additions, Mater. Sci. Eng. A, 2006, 419, p 181–188
K. Hirai, H. Somekawa, Y. Takigawa, and K. Higashi, Effects of Ca and Sr Addition on Mechanical Properties of a Cast AZ91 Magnesium Alloy at Room and Elevated Temperature, Mater. Sci. Eng. A, 2005, 403, p 276–280
F. Wang, J.B. Li, J. Liu, D. Lv, P.L. Mao, and Z. Liu, Influences of Ca and Y Addition on the Microstructure and Corrosion Resistance of Vacuum Die-cast AZ91 Alloy, Acta Metall. Sin. (Engl. Lett.), 2014, 27, p 609–614
H. Watanabe, M. Yamaguchi, Y. Takigawa, and K. Higashi, Mechanical Properties of Mg-Al-Ca Alloy Processed by Hot Extrusion, Mater. Sci. Eng. A, 2007, 454–455, p 384–388
B. Tang, S.S. Li, X.S. Wang, D.B. Zeng, and R. Wu, Effect of Ca/Sr Composite Addition into AZ91D Alloy on Hot-crack Mechanism, Scr. Mater., 2005, 53, p 1077–1082
Y. Turen, Effect of Sn Addition on Microstructure, Mechanical and Casting Properties of AZ91 Alloy, Mater. Des., 2013, 49, p 1009–1015
B. Kim, J. Do, S. Lee, and I. Park, In Situ Fracture Observation and Fracture Toughness Analysis of Squeeze Cast AZ51-xSn Magnesium Alloys, Mater. Sci. Eng. A, 2010, 527, p 6745–6757
R. Mahmudi and S. Moeendarbari, Effects of Sn Additions on the Microstructure and Impression Creep Behavior of AZ91 Magnesium Alloy, Mater. Sci. Eng. A, 2013, 566, p 30–39
J.H. Chen, Z.H. Chen, H.G. Yan, F.Q. Zhang, and K. Liao, Effects of Sn Addition on Microstructure and Mechanical Properties of Mg-Zn-Al Alloys, J. Alloys Compd., 2008, 461, p 209–215
M.B. Yang and F.S. Pan, Effects of Sn Addition on As-cast Microstructure, Mechanical Properties and Casting Fluidity of ZA84 Magnesium Alloy, Mater. Des., 2010, 31, p 68–75
K.C. Park, B.H. Kim, H. Kimura, Y.H. Park, and I.M. Park, Microstructure and Corrosion Properties of Mg-xSn-5Al-1Zn (x = 0, 1, 5 and 9 mass%) Alloys, Mater. Trans., 2010, 51, p 472–476
B.H. Kim, S.M. Jo, Y.C. Lee, Y.H. Park, and I.M. Park, Microstructure, Tensile Properties and Creep Behavior of Mg-4Al-2Sn Containing Ca Alloy Produced by Different Casting Technologies, Mater. Sci. Eng. A, 2012, 535, p 40–47
Q. Xiang, R.Z. Wu, and M.L. Zhang, Influence of Sn on Microstructure and Mechanical Properties of Mg-5Li-3Al-2Zn Alloys, J. Alloys Compd., 2009, 477, p 832–835
A. Suzuki, N.D. Saddock, J.W. Jones, and T.M. Pollock, Structure and Transition of Eutectic (Mg,Al)2Ca Laves Phase in a Die-cast Mg-Al-Ca Base Alloy, Scr. Mater., 2004, 51, p 1005–1010
F. Wang, Y. Wang, P.L. Mao, B.Y. Yu, and Q.Y. Guo, Effects of Combined Addition of Y and Ca on Microstructure and Mechanical Properties of Die Casting AZ91 Alloy, Trans. Nonferrous Met. Soc. China, 2010, 20, p 311–317
J. Song, S.M. Xiong, M. Li, and J. Allison, The Correlation between Microstructure and Mechanical Properties of High-pressure Die-cast AM50 Alloy, J. Alloys Compd., 2009, 477, p 863–869
Z.M. Shi, M. Liu, and A. Atrens, Measurement of the Corrosion Rate of Magnesium Alloys using Tafel Extrapolation, Corros. Sci., 2010, 52, p 579–588
H.R. Bakhsheshi-Rad, M.R. Abdul-Kadir, M.H. Idris, and S. Farahany, Relationship Between the Corrosion Behavior and the Thermal Characteristics and Microstructure of Mg-0.5Ca-xZn Alloys, Corros. Sci., 2012, 64, p 184–197
G. Song and A. Atrens, Understanding Magnesium Corrosion—a Framework for Improved Alloy Performance, Adv. Eng. Mater., 2003, 5, p 837–858
S.M. Liang, R.S. Chen, J.J. Blandin, M. Suery, and E.H. Han, Thermal Analysis and Solidification Pathways of Mg-Al-Ca System Alloys, Mater. Sci. Eng. A, 2008, 480, p 365–372
A. Suzuki, N.D. Saddock, J.W. Jones, and T.M. Pollock, Solidification Paths and Eutectic Intermetallic Phases in Mg-Al-Ca Ternary Alloys, Acta Mater., 2005, 53, p 2823–2834
C. Zhang, H.B. Cao, V. Firouzdor, S. Kou, and Y.A. Chang, Microstructure Investigations of Directionally Solidified Mg-rich Alloys Containing Al, Ca and Sn, Intermetallics, 2010, 18, p 1597–1602
F. Wang, S.J. Sun, B. Yu, F. Zhang, P.L. Mao, and Z. Liu, First Principles Investigation of Binary Intermetallics in Mg-Al-Ca-Sn Alloy: Stability, Electronic Structures, Elastic Properties and Thermodynamic Properties, Trans. Nonferrous Met. Soc. China, 2016, 26, p 203–212
J.R. Terbush, O.H. Chen, J.W. Jones, and T.M. Pollock, The Dependence of Creep Behavior on Elemental Partitioning in Mg-5Al-3Ca-xSn Alloys, Metall. Mater. Trans. A, 2012, 43, p 3120–3134
W.D. Callister and D.G. Rethwisch, Jr., Materials Science and Engineering: An Introduction, 8th ed., Wiley, Hoboken, 2009
Y.Z. Lü, Q.D. Wang, X.Q. Zeng, W.J. Ding, C.Q. Zhai, and Y.P. Zhu, Effects of Rare Earths on the Microstructure, Properties and Fracture Behavior of Mg-Al alloys, Mater. Sci. Eng. A, 2000, 278, p 66–76
Y.Z. Lü, Q.D. Wang, W.J. Ding, X.Q. Zeng, and Y.P. Zhu, Fracture Behavior of AZ91 Magnesium Alloy, Mater. Lett., 2000, 44, p 265–268
D.H. Stjohn, M.A. Easton, M. Qian, and J.A. Taylor, Grain Refinement of Magnesium Alloys: A Review of Recent Research, Theoretical Developments, and Their Application, Metall. Mater. Trans. A, 2013, 44, p 2935–2949
A.A. Luo, B.R. Powell, and A.K. Sachdev, Computational Phase Equilibria and Experimental Investigation of Magnesium-Aluminum-Calcium Alloys, Intermetallics, 2012, 24, p 22–29
B.H. Kim, K.C. Park, Y.H. Park, and I.M. Park, Microstructure and Creep Properties of Mg-4Al-2Sn-1(Ca, Sr) Alloys, Trans. Nonferrous Met. Soc. China, 2010, 20, p 1184–1191
B.H. Kim, K.C. Park, Y.H. Park, and I.M. Park, Investigations of the Properties of Mg-4Al-2Sn-1Ca-xCe Alloys, Mater. Sci. Eng. A, 2010, 527, p 6372–6377
Q. Liu, W.L. Cheng, H. Zhang, C.X. Xu, and J.S. Zhang, The Role of Ca on the Microstructure and Corrosion Behavior of Mg-8Sn-1Al-1Zn-Ca Alloys, J. Alloys Compd., 2014, 590, p 162–167
K.D. Ralston, N. Birbilis, and C.H.J. Davies, Revealing the Relationship between Grain Size and Corrosion Rate of Metals, Scr. Mater., 2010, 63, p 1201–1204
S. Amira, D. Dubé, R. Tremblay, and E. Ghali, Influence of the Microstructure on the Corrosion Behavior of AXJ530 Magnesium Alloy in 3.5% NaCl Solution, Mater. Charact., 2008, 59, p 1508–1517
J.Y. Choi and W.J. Kim, Significant Effects of Adding Trace Amounts of Ti on the Microstructure and Corrosion Properties of Mg-6Al-1Zn Magnesium Alloy, J. Alloys Compd., 2014, 614, p 49–55
Acknowledgments
This study was financially Supported by National Natural Science Foundation of China (Nos. 51504153 and 51571145), Natural Science Foundation of Liaoning Province (No. 201602548) and Science and Technology Project of Shenyang (No. 17-11-8-00).
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Wang, F., Dong, H., Sun, S. et al. Microstructure, Tensile Properties, and Corrosion Behavior of Die-Cast Mg-7Al-1Ca-xSn Alloys. J. of Materi Eng and Perform 27, 612–623 (2018). https://doi.org/10.1007/s11665-018-3145-9
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DOI: https://doi.org/10.1007/s11665-018-3145-9