Abstract
Zr55Cu30Al10Ni5 bulk metallic glass and its composites were prepared by suction casting into a copper mold. The effect of MoSi2 content on the tribological behavior of Zr55Cu30Al10Ni5 BMG was studied by using a high-speed reciprocating friction and wear tester. The results indicate that the friction coefficient and wear resistance of the BMGs can be improved by a certain amount of crystalline phase induced by MoSi2 content from 1 to 3% and deteriorated with MoSi2 content of 4%. The wear mechanism of both the metallic glass and its composite is abrasive wear. The mechanism of crystalline phase-dependent tribological properties of the composite was discussed based on the wear track and mechanical properties in the present work. The wear behavior of Zr55Cu30Al10Ni5 BMG and its composite indicates that a good combination of the toughness and the hardness can make the composite be well wear resistant.
Similar content being viewed by others
References
A. Inoue, T. Zhang, and T. Masumoto, Al-La-Ni Amorphous Alloy with a Wide Supercooled Liquid Region, Mater. Trans., JIM, 1989, 30, p 965–972
W.L. Johnson, Bulk Glass-forming Metallic Alloys: Science and Technology, MRS Bull., 1999, 24, p 42–56
W.H. Wang, C. Dong, and C.H. Shek, Bulk Metallic Glasses, Mater. Sci. Eng., 2004, R44, p 45–89
M.F. Ashby and A.L. Greer, Metallic Glasses as Structural Materials, Scripta Mater., 2006, 54, p 321–326
H.C. Yim, R.D. Conner, F. Szues, and W.L. Johnson, Processing, Microstructure and Properties of Ductile Metal Particulate Reinforced Zr57Nb5Al10Cu15.4Ni12.6 Bulk Metallic Glass Composites, Acta Mater., 2002, 50, p 2737–2745
D.C. Hofmann, J.Y. Suh, A. Wiest, G. Duan, M.L. Lind, M.D. Demetriou et al., Designing Metallic Glass Matrix Composites with High Toughness and Tensile Ductility, Nature, 2008, 451, p 1085–1089
M. Martin, L. Meyer, L. Kecskes, and N.N. Thadhani, Uniaxial and Biaxial Compressive Response of a Bulk Metallic Composite over a Range of Strain Rates and Temperatures, J. Mater. Res., 2009, 24, p 66–78
Y. Wu, D.Q. Zhou, W.L. Song, H. Wang, Z.Y. Zhang, D. Ma et al., Ductilizing Bulk Metallic Glass Composite by Tailoring Stacking Fault Energy, Phys. Rev. Lett., 2012, 109, p 245506
J.H. Chen, M.Q. Jiang, Y. Chen, and L.H. Dai, Strain Rate Dependent Shear Banding Behavior of a Zr-based Bulk Metallic Glass Composite, Mater. Sci. Eng., A, 2013, 576, p 134–139
C.C. Hays, C.P. Kim, and W.L. Johnson, Microstructure Controlled Shear Band Pattern Formation and Enhanced Plasticity of Bulk Metallic Glasses Containing in situ Formed Ductile Phase Dendrite Dispersions, Phys. Rev. Lett., 2000, 84, p 2901–2904
J. Das, S.K. Roy, W. Löser, J. Eckert, and L. Schultz, Novel In Situ Nanostructure-Dendrite Composites in Zr-Base Multicomponent Alloy System, Mater. Manuf. Proc., 2004, 19, p 423–437
K.B. Kim, J. Das, F. Baier, and J. Eckert, Propagation of Shear Bands in Ti66.1Cu8Ni4.8Sn7.2Nb13.9 Nanostructure-dendrite Composite during Deformation, Appl. Phys. Lett., 2005, 86, p 171909
T. Gloriant, Microhardness and Abrasive Wear Resistance of Metallic Glasses and Nanostructured Composite Materials, J. Non-cryst. Solid, 2003, 316, p 96–103
A.L. Greer, K.L. Rutherford, and M. Hutchings, Wear Resistance of Amorphous Alloys and Related Materials, Int. Mate. Rev., 2002, 47, p 87–112
X.F. Wu, G.A. Zhang, and F.F. Wu, Wear Behaviour of Zr-based In Situ Bulk Metallic Glass Matrix Composites, Bull. Mater. Sci., 2016, 39, p 703–709
J. Eckert, U. Kühn, N. Mattern, A. Reger-Leonhard, and M. Heilmair, Bulk Nanostructured Zr-based Multiphase Alloys with High Strength and Good Ductility, Scripta Mater., 2001, 44, p 1587–1590
P.J. Tao, Y.Z. Yang, Z.W. Xie, and Y.D. He, Research on Friction and Wear Behavior of a Bulk Metallic Glass under Different Sliding Velocity, Mater. Lett., 2015, 156, p 177–179
L.F. Liu, H.A. Zhang, and C. Shi, Sliding Tribological Characteristics of a Zr-based Bulk Metallic Glass Near the Glass Transition Temperature, Tribol. Lett., 2009, 33, p 205–210
L.H. Dai and Y.L. Bai, Basic Mechanical Behaviors and Mechanics of Shear Banding in BMGs, Int. J. Impact. Engi., 2008, 35, p 704–716
W.H. Wang and H.Y. Bai, Carbon-addition-induced Bulk ZrTiCuNiBe Amorphous Matrix Composite Containing ZrC Particles, Mater. Lett., 2000, 44, p 59–63
M. Calin, J. Eckert, and L. Schultz, Improved Mechanical Behavior of Cu-Ti-based Bulk Metallic Glass by in situ Formation of Nanoscale Precipitates, Scripta Mater., 2003, 48, p 653–658
A. Inoue, W. Zhang, T. Tsurui, A.R. Yavari, and A.L. Greer, Unusual Room-Temperature Compressive Plasticity in Nanocrystal-Toughened Bulk Copper-Zirconium Glass, Philos. Mag. Lett., 2005, 85, p 221–229
H. Choi-Yim and W.L. Johnson, Bulk Metallic Glass Matrix Composite, Appl. Phys. Lett., 1997, 71, p 3808–3810
H. Choi-Yim, R. Busch, U. Köster, and W.L. Johnson, Synthesis and Sharacterization of Particulate Reinforced Zr57Nb5Al10Cu15.4Ni12.6 Bulk Metallic Glass Composites, Acta Mater., 1999, 47, p 2455–2462
G. He, J. Eckert, W. Löser, and L. Schultz, Novel Ti-base Nanostructure-dendrite Composite with Enhanced Plasticity, Nat. Mater., 2003, 2, p 33–37
M.E. Siegrist and J.F. Löffler, Bulk Metallic Glass–graphite Composites, Scripta Mater., 2007, 56, p 1079–1082
Y. Liu, Y.T. Zhu, X.K. Luo, and Z.M. Liu, Wear Behavior of a Zr-based Bulk Metallic Glass and Its Composites, J. Alloys Comp., 2010, 503, p 138–144
H. Chen, Y. He, G.J. Shiflet, and S.J. Poon, Mechanical Properties of Partially Crystallized Aluminum Based Metallic Glasses, Scripta Metall. Mater., 1991, 25, p 1421–1424
A.M. Hodge and T.G. Nieh, Evaluating Abrasive Wear of Amorphous Alloys Using Nanoscratch Technique, Intermetallics, 2004, 12, p 741–748
P.G. Boswell, The Wear Resistance of a Liquid Quenched Metallic Glass, J. Mater. Sci., 1979, 4, p 1505–1507
C.J. Gilbert, R.O. Ritchie, and W.L. Johnson, Fracture Toughness and Fatigue-Crack Propagation in a Zr–Ti–Ni–Cu–Be Bulk Metallic Glass, Appl. Phys. Lett., 1997, 71, p 476–478
Z. Bian, G.L. Chen, G. He, and X.D. Hui, Microstructure and Ductile-Brittle Transition of As-cast Zr-based Bulk Glass Alloys under Compressive Testing, Mater. Sci. Engi., 2001, A316, p 135–144
Acknowledgments
We are pleased to acknowledge research support from the National Natural Science Foundation of China through Grants 11772127.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Liu, L., Yang, J. Effect of MoSi2 Content on Dry Sliding Tribological Properties of Zr-Based Bulk Metallic Glass Composites. J. of Materi Eng and Perform 26, 6219–6225 (2017). https://doi.org/10.1007/s11665-017-3039-2
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-017-3039-2