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The Influence of Zn Content on the Corrosion and Wear Performance of Mg-Zn-Ca Alloy in Simulated Body Fluid

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Abstract

Mg-Zn-Ca alloy has been attracting increasing attention as a potential biodegradable implant material. In this paper, Mg-3Zn-0.2Ca and Mg-4Zn-0.2Ca alloys were prepared by means of vacuum melting and subsequent hot extrusion process. The influences of Zn content on the microstructure, mechanical properties, and corrosion and wear behavior of Mg-Zn-Ca alloys in simulated body fluid (SBF) were studied. The results show that with increased Zn content, the grain size and corrosion resistance were decreased, while the mechanical strength and wear resistance were increased, under both dry sliding and SBF-lubricated conditions. For the same Mg-Zn-Ca alloy, the wear loss rate under SBF lubrication was higher than dry sliding condition, indicating a strong corrosion-assisted wear effect of SBF to the Mg-Zn-Ca alloy.

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References

  1. Y.F. Zheng, X.N. Gu, and F. Witte, Biodegradable Metals, Mater. Sci. Eng. R, 2014, 77, p 1–34

    Article  Google Scholar 

  2. Yongjun Chen, Xu Zhigang, Christopher Smith, and Jag Sankar, Recent Advances on the Development of Magnesium Alloys for Biodegradable Implants, Acta Biomater., 2014, 10, p 4561–4573

    Article  Google Scholar 

  3. Andrej Atrens, Guang-Ling Song, Fuyong Cao, Zhiming Shi, and Patrick K. Bowen, Advances in Mg Corrosion and Research Suggestions, J. Magnes. Alloys, 2013, 1, p 177–200

    Article  Google Scholar 

  4. G.-L. Song and Z. Xu, Effect of Microstructure Evolution on Corrosion of Different Crystal Surfaces of AZ31 Mg Alloy in a Chloride Containing Solution, Corros. Sci., 2012, 63, p 100–112

    Article  Google Scholar 

  5. Nan Li and Yufeng Zheng, Novel Magnesium Alloys Developed for Biomedical Application: A Review, J. Mater. Sci. Technol., 2013, 29(6), p 489–502

    Article  Google Scholar 

  6. M.P. Staiger, A.M. Pietak, J. Huadmai, and G. Dias, Magnesium and Its Alloys as Orthopedic Biomaterials: A Review, Biomaterials, 2006, 27, p 1728–1734

    Article  Google Scholar 

  7. B.P. Zhang, Y. Wang, and L. Geng, Research on Mg-Zn-Ca Alloy as Degradable Biomaterial, Biomaterials—Physics and Chemistry, R. Pignatello, Ed., In Tech, Zurich, 2011, p 183–204

    Google Scholar 

  8. Shaoxiang Zhang, Xiaonong Zhang, Changli Zhao, Jianan Li, Yang Song, Chaoying Xie, Hairong Tao, Yan Zhang, Yaohua He, Yao Jiang, and Yujun Bian, Research on an Mg-Zn Alloy as a Degradable Biomaterial, Acta Biomater., 2010, 6, p 626–640

    Article  Google Scholar 

  9. X.N. Gu, Y.F. Zheng, Y. Cheng, S.P. Zhong, and T.F. Xi, In Vitro Corrosion and Biocompatibility of Binary Magnesium Alloys, Biomaterials, 2009, 30, p 484–498

    Article  Google Scholar 

  10. Zijian Li, Gu Xunan, Siquan Lou, and Yufeng Zheng, The Development of Binary Mg-Ca Alloys for Use as Biodegradable Materials Within Bone, Biomaterials, 2008, 9, p 1329–1344

    Article  Google Scholar 

  11. Du Hui, Zunjie Wei, Xinwang Liu, and Erlin Zhang, Effects of Zn on the Microstructure, Mechanical Property and Bio-corrosion Property of Mg-3Ca Alloys for Biomedical Application, Mater. Chem. Phys., 2011, 125, p 568–575

    Article  Google Scholar 

  12. Y. Sun, B. Zhang, Y. Wang, L. Geng, and X. Jiao, Preparation and Characterization of a New Biomedical Mg-Zn-Ca Alloy, Mater. Des., 2012, 34, p 58–64

    Article  Google Scholar 

  13. De-Bao Liu, Wu Bo, Xiao Wang, and Min-Fang Chen, Corrosion and Wear Behavior of an Mg-2Zn-0.2Mn Alloy in Simulated Body Fluid, Rare Met., 2015, 34(8), p 553–559

    Article  Google Scholar 

  14. American Society for Testing and Materials. ASTM-G31-72: Standard Practice for Laboratory Immersion Corrosion Testing of Metals, Annual Book of ASTM Standards. American Society for Testing and Materials, Philadelphia, 2004

  15. W.J. Huang, Q. Lin, and X. Zhang, Investigation of Tribological Properties of Magnesium Alloys Under Dry Sliding and Lubrication Condition, J. Eng. Tribol., 2011, 225(J1), p p35

    Google Scholar 

  16. Liu Debao, Liu Yichi, and Huang Yan, Effects of Solidification Cooling Rate on the Corrosion Resistance of Mg-Zn-Ca Alloy, Progr. Nat. Sci, 2014, 24(5), p 452–457

    Article  Google Scholar 

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Acknowledgments

The authors are grateful for the supports from the National Natural Science Foundation of China (No. 51271131) and key projects supported by Tianjin Science and Technology (15ZCZDSY00920)

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Correspondence to Debao Liu.

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Li, H., Liu, D., Zhao, Y. et al. The Influence of Zn Content on the Corrosion and Wear Performance of Mg-Zn-Ca Alloy in Simulated Body Fluid. J. of Materi Eng and Perform 25, 3890–3895 (2016). https://doi.org/10.1007/s11665-016-2207-0

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  • DOI: https://doi.org/10.1007/s11665-016-2207-0

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