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Metal-Organic Framework Derived MnO/Carbon Cloth Loaded by MnO Nanoparticles as a High-Performance Self-Supporting Anode for Lithium-Ion Batteries

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Abstract

In this paper, carbon cloth with pre-loaded MnO nanoparticles (the composite is denoted as MnO/CC) is synthesized by hydrothermal reaction and sintering. A flake-like Mn-MOF derivative is grown on MnO/CC (the composite is denoted as MOF derivative/MnO/CC) by subsequent solvothermal reaction and sintering. The gap between MnO nanoparticles on the surface of carbon fibers provides space for the growth of Mn-MOF, and the MnO nanoparticles fix the grown Mn-MOF, which achieves the loading of Mn-MOF and its derivative on carbon cloth. As a self-supporting anode for lithium-ion batteries, MOF derivative/MnO/CC delivers a capacity of 1292 mAh g−1, which is much higher than that of MnO/CC. The Mn-MOF derivative further increases the conductivity of the MnO nanoparticles on the surface of carbon fibers, and the MOF derivative with excellent electrochemical performance is applied to the self-supporting anode. These factors lead to the better electrochemical performance of MOF derivative/MnO/CC.

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Acknowledgment

We appreciate the financial supporting from High-energy Beam Intelligent Processing and Green Manufacturing Project of Shanghai Municipal Education Commission.

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  1. School of Materials Engineering, Shanghai University of Engineering Science, Shanghai, 201620, China

    Yanting Liang & Qi Yang

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  1. Yanting Liang
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Liang, Y., Yang, Q. Metal-Organic Framework Derived MnO/Carbon Cloth Loaded by MnO Nanoparticles as a High-Performance Self-Supporting Anode for Lithium-Ion Batteries. J. Electron. Mater. 51, 5273–5281 (2022). https://doi.org/10.1007/s11664-022-09774-6

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