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Sensing Sub-ppm Concentration of H2S Gas at Room Temperature Using Silver-Doped SnO2 Nanocrystals

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Abstract

In this work, the different weight percentages of Ag (from 0 wt.% to 12 wt.%)-doped SnO2 nanostructure layers were created by the spray pyrolysis, and their H2S gas sensing characteristics were investigated. The effect of various amounts of Ag on morphology and sensing properties to H2S such as sensitivity, selectivity, and the response was studied. The fabricated sensors showed fast responses to different concentrations (0.1–50 ppm) of H2S gas at room temperature without a heater. The findings demonstrated that doping tin oxide with Ag increased the sensing properties of the samples when compared to the pure sample. Among the manufactured samples, the one doped with 4 wt.% Ag had the best sensing properties. This sample had a 27% response for 0.1 ppm concentration of H2S gas and also had a much better selectivity than other samples. This good response is the result of a large surface-to-volume ratio and a small particle size.

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References

  1. K. Dong, J. Choi, I. Hwang, J. Lee, B. Kang, D. Ham, J. Lee, and B. Ju, Enhanced H2S sensing characteristics of Pt doped SnO2 nanofibers sensors with micro heater. Sens. Actuators B 157, 154 (2011).

    Article  CAS  Google Scholar 

  2. M. Vaishampayan, R. Deshmukh, P. Walke, and I. Mulla, Fe-doped SnO2 nano material: a low temperature hydrogen sulfide gas sensor. Mater. Chem. Phys. 109, 230 (2008).

    Article  CAS  Google Scholar 

  3. J. Gong, Q. Chen, M. Lian, N. Liu, R. Stevenson, and F. Adami, Micromachined nanocrystalline silver doped SnO2 H2S sensor. Sens. Actuators B 114, 32 (2006).

    Article  CAS  Google Scholar 

  4. G. Otulakowski, and B.P. Kavanagh, Hydrogen sulfide in lung injury: therapeutic hope from a toxic gas. Anesthesiology 113, 4 (2010).

    Article  Google Scholar 

  5. W. Zheng, X. Lu, W. Wang, Z. Li, H. Zhang, Z. Wang, X. Xu, S. Li, and C. Wang, Assembly of Pt nanoparticles on electrospun In2O3 nanofibers for H2S detection. J. Coll. Interface Sci. 338, 366 (2009).

    Article  CAS  Google Scholar 

  6. S.K. Gupta, A. Joshi, and M. Kaur, Development of gas sensors using Zn nanostructures. J. Chem. Sci. 122, 57 (2010).

    Article  CAS  Google Scholar 

  7. H. Liu, S.P. Gong, Y. Hu, J. Liu, and D. Zhou, Properties and mechanism study of SnO2 nanocrystals for H2S thick-film sensors. Sens. Actuators B 140, 190 (2009).

    Article  CAS  Google Scholar 

  8. S.W. Tsai, and JCh. Chiou, Improved crystalline structure and H2S sensing performance of CuO-Au-SnO2 thin film using SiO2 additive concentration. Sens. Actuators B 152, 176 (2011).

    Article  CAS  Google Scholar 

  9. G. Korotcenkov, B. Cho, L. Gulina, and V. Tolstoy, SnO2 thin films modified by the SnO2-Au nanocomposites: Response to reducing gases. Sens. Actuators B 141, 610 (2009).

    Article  CAS  Google Scholar 

  10. L. Patil, and D. Patil, Heterocontact type CuO-modified SnO2 sensor for the detection of a ppm level H2S gas at room temperature. Sens. Actuators B 120, 316 (2006).

    Article  CAS  Google Scholar 

  11. A. Hoel, L.F. Reyes, S. Saukko, P. Heszler, V. Lantto, and C.G. Granqvist, Gas sensing with films of nanocrystalline WO3 and Pd made by advanced reactive gas deposition. Sens. Actuators B 105, 283 (2005).

    Article  CAS  Google Scholar 

  12. G.N. Chaudhari, A.M. Bhende, S.S. Patil, and V.S. Sapkal, Structural and gas sensing properties of nanocrystalline TiO2:WO3-based hydrogen sensors. Sens. Actuators B 115, 297 (2006).

    Article  CAS  Google Scholar 

  13. R.S. Niranjan, K.R. Patil, S.R. Sainkar, and I.S. Mulla, High H2S-sensitive copper-doped tin oxide thin film. Mater. Chem. Phys. 80, 250 (2003).

    Article  CAS  Google Scholar 

  14. R. Mishra, and K. Rajanna, Metal-oxide thin film with Pt, Au and Ag nanoparticles for gas sensing applications. Sens. Mater. 17, 433 (2005).

    CAS  Google Scholar 

  15. C.H. Liu, L. Zhang, and Y. Jin He, Properties and mechanisra study of Ag doped SnO2 thin films as H2S sensors. Thin Solid Films 304, 13 (1997).

    Article  CAS  Google Scholar 

  16. R.N. Bukke, J.K. Saha, N.N. Mude, Y. Kim, S. Lee, and J. Jang, Lanthanum doping in zinc-oxide for highly reliable thin film transistor on flexible substrate by spray pyrolysis. ACS Appl. Mater. Interfaces 12, 35164 (2020).

    Article  CAS  Google Scholar 

  17. G.E. Patil, D.D. Kajale, D.N. Chavan, N.K. Pawar, P.T. Ahire, S.D. Shinde, V.B. Gaikwad, and G.H. Jain, Synthesis, characterization and gas sensing performance of SnO2 thin films prepared by spray pyrolysis. Bull. Mater. Sci. 34, 1 (2011).

    Article  CAS  Google Scholar 

  18. S.J. Helen, M. Suganthi Devadason, and T. Mahalingam. Haris, Transparent conducting Mo-doped CdO thin films by spray pyrolysis method for solar cell applications. J. Electron. Mater. 47, 2439 (2018).

    Article  CAS  Google Scholar 

  19. K. Sankarasubramanian, P. Soundarrajan, K. Sethuraman, and K. Ramamurthi, Chemical spray pyrolysis deposition of transparent and conducting Fe doped CdO thin films for ethanol sensor. Mater. Sci. Semicond. Process. 40, 879 (2015).

    Article  CAS  Google Scholar 

  20. M.H. Sayeda, E.V.C. Robert, P.J. Dale, and L. Gutaya, Cu2SnS3 based thin film solar cells from chemical spray pyrolysis. Thin Solid Films 669, 436 (2019).

    Article  Google Scholar 

  21. N.S. Ramgir, S. Ganapathi, M. Kaur, N. Datta, K.P. Muthe, D.K. Aswal, S.K. Gupta, and J.V. Yakhmi, Sub-ppm H2S sensing at room temperature using CuO thin films. Sens. Actuators B 151, 90 (2010).

    Article  CAS  Google Scholar 

  22. J.H. Sung, Y.S. Lee, J.W. Lim, Y.H. Hong, and D.D. Lee, Sensing characteristics of tin dioxide/gold sensor prepared by coprecipitation method. Sens. Actuators B 66, 149 (2000).

    Article  CAS  Google Scholar 

  23. P.S. Kolhe, A.B. Shinde, S.G. Kulkarni, N. Maiti, P.M. Koinkar, and K.M. Sonawane, Gas sensing performance of Al doped ZnO thin film for H2S detection. J. Alloys Compd. 748, 6 (2018).

    Article  CAS  Google Scholar 

  24. T.T.N. Hoa, D.T. Le, N.V. Toan, N.V. Duy, C.M. Hung, N.V. Hieu, and N.D. Hoa, Highly selective H2S gas sensor based on WO3-coated SnO2 nanowires. Mater. Today 26, 102094 (2021).

    CAS  Google Scholar 

  25. J. Fan, P. Liu, X. Chen, H. Zhou, S. Fu, and W. Wu, Carbon nanotubes-CuO/SnO2 based gas sensor for detecting H2S in low concentration. Nanotechnology 30, 475501 (2019).

    Article  CAS  Google Scholar 

  26. S. Keshtkar, A. Rashidi, M. Kooti, M. Askarieh, S. Pourhashem, E. Ghasemy, and N. Izadi, A novel highly sensitive and selective H2S gas sensor at low temperatures based on SnO2 quantum dots-C60 nanohybrid: Experimental and theory study. Talanta 188, 531 (2018).

    Article  CAS  Google Scholar 

  27. D. Zhang, J. Wu, and Y. Cao, Ultrasensitive H2S gas detection at room temperature based on copper oxide/molybdenum disulfide nanocomposite with synergistic effect. Sens. Actuators B 287, 346 (2019).

    Article  CAS  Google Scholar 

  28. K.S. Yo, S.D. Han, H.G. Moon, S.J. Yoon, and Ch.Y. Kang, Highly sensitive H2S sensor based on the metal-catalyzed SnO2 nanocolumns fabricated by glancing angle deposition. Sensors 15, 15468 (2015).

    Article  Google Scholar 

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Correspondence to Farshad Khoshnood.

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Khoshnood, F., Manouchehri, S. & Yousefi, M.H. Sensing Sub-ppm Concentration of H2S Gas at Room Temperature Using Silver-Doped SnO2 Nanocrystals. J. Electron. Mater. 51, 1804–1812 (2022). https://doi.org/10.1007/s11664-022-09447-4

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  • DOI: https://doi.org/10.1007/s11664-022-09447-4

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