Abstract
In this work, the different weight percentages of Ag (from 0 wt.% to 12 wt.%)-doped SnO2 nanostructure layers were created by the spray pyrolysis, and their H2S gas sensing characteristics were investigated. The effect of various amounts of Ag on morphology and sensing properties to H2S such as sensitivity, selectivity, and the response was studied. The fabricated sensors showed fast responses to different concentrations (0.1–50 ppm) of H2S gas at room temperature without a heater. The findings demonstrated that doping tin oxide with Ag increased the sensing properties of the samples when compared to the pure sample. Among the manufactured samples, the one doped with 4 wt.% Ag had the best sensing properties. This sample had a 27% response for 0.1 ppm concentration of H2S gas and also had a much better selectivity than other samples. This good response is the result of a large surface-to-volume ratio and a small particle size.
Similar content being viewed by others
References
K. Dong, J. Choi, I. Hwang, J. Lee, B. Kang, D. Ham, J. Lee, and B. Ju, Enhanced H2S sensing characteristics of Pt doped SnO2 nanofibers sensors with micro heater. Sens. Actuators B 157, 154 (2011).
M. Vaishampayan, R. Deshmukh, P. Walke, and I. Mulla, Fe-doped SnO2 nano material: a low temperature hydrogen sulfide gas sensor. Mater. Chem. Phys. 109, 230 (2008).
J. Gong, Q. Chen, M. Lian, N. Liu, R. Stevenson, and F. Adami, Micromachined nanocrystalline silver doped SnO2 H2S sensor. Sens. Actuators B 114, 32 (2006).
G. Otulakowski, and B.P. Kavanagh, Hydrogen sulfide in lung injury: therapeutic hope from a toxic gas. Anesthesiology 113, 4 (2010).
W. Zheng, X. Lu, W. Wang, Z. Li, H. Zhang, Z. Wang, X. Xu, S. Li, and C. Wang, Assembly of Pt nanoparticles on electrospun In2O3 nanofibers for H2S detection. J. Coll. Interface Sci. 338, 366 (2009).
S.K. Gupta, A. Joshi, and M. Kaur, Development of gas sensors using Zn nanostructures. J. Chem. Sci. 122, 57 (2010).
H. Liu, S.P. Gong, Y. Hu, J. Liu, and D. Zhou, Properties and mechanism study of SnO2 nanocrystals for H2S thick-film sensors. Sens. Actuators B 140, 190 (2009).
S.W. Tsai, and JCh. Chiou, Improved crystalline structure and H2S sensing performance of CuO-Au-SnO2 thin film using SiO2 additive concentration. Sens. Actuators B 152, 176 (2011).
G. Korotcenkov, B. Cho, L. Gulina, and V. Tolstoy, SnO2 thin films modified by the SnO2-Au nanocomposites: Response to reducing gases. Sens. Actuators B 141, 610 (2009).
L. Patil, and D. Patil, Heterocontact type CuO-modified SnO2 sensor for the detection of a ppm level H2S gas at room temperature. Sens. Actuators B 120, 316 (2006).
A. Hoel, L.F. Reyes, S. Saukko, P. Heszler, V. Lantto, and C.G. Granqvist, Gas sensing with films of nanocrystalline WO3 and Pd made by advanced reactive gas deposition. Sens. Actuators B 105, 283 (2005).
G.N. Chaudhari, A.M. Bhende, S.S. Patil, and V.S. Sapkal, Structural and gas sensing properties of nanocrystalline TiO2:WO3-based hydrogen sensors. Sens. Actuators B 115, 297 (2006).
R.S. Niranjan, K.R. Patil, S.R. Sainkar, and I.S. Mulla, High H2S-sensitive copper-doped tin oxide thin film. Mater. Chem. Phys. 80, 250 (2003).
R. Mishra, and K. Rajanna, Metal-oxide thin film with Pt, Au and Ag nanoparticles for gas sensing applications. Sens. Mater. 17, 433 (2005).
C.H. Liu, L. Zhang, and Y. Jin He, Properties and mechanisra study of Ag doped SnO2 thin films as H2S sensors. Thin Solid Films 304, 13 (1997).
R.N. Bukke, J.K. Saha, N.N. Mude, Y. Kim, S. Lee, and J. Jang, Lanthanum doping in zinc-oxide for highly reliable thin film transistor on flexible substrate by spray pyrolysis. ACS Appl. Mater. Interfaces 12, 35164 (2020).
G.E. Patil, D.D. Kajale, D.N. Chavan, N.K. Pawar, P.T. Ahire, S.D. Shinde, V.B. Gaikwad, and G.H. Jain, Synthesis, characterization and gas sensing performance of SnO2 thin films prepared by spray pyrolysis. Bull. Mater. Sci. 34, 1 (2011).
S.J. Helen, M. Suganthi Devadason, and T. Mahalingam. Haris, Transparent conducting Mo-doped CdO thin films by spray pyrolysis method for solar cell applications. J. Electron. Mater. 47, 2439 (2018).
K. Sankarasubramanian, P. Soundarrajan, K. Sethuraman, and K. Ramamurthi, Chemical spray pyrolysis deposition of transparent and conducting Fe doped CdO thin films for ethanol sensor. Mater. Sci. Semicond. Process. 40, 879 (2015).
M.H. Sayeda, E.V.C. Robert, P.J. Dale, and L. Gutaya, Cu2SnS3 based thin film solar cells from chemical spray pyrolysis. Thin Solid Films 669, 436 (2019).
N.S. Ramgir, S. Ganapathi, M. Kaur, N. Datta, K.P. Muthe, D.K. Aswal, S.K. Gupta, and J.V. Yakhmi, Sub-ppm H2S sensing at room temperature using CuO thin films. Sens. Actuators B 151, 90 (2010).
J.H. Sung, Y.S. Lee, J.W. Lim, Y.H. Hong, and D.D. Lee, Sensing characteristics of tin dioxide/gold sensor prepared by coprecipitation method. Sens. Actuators B 66, 149 (2000).
P.S. Kolhe, A.B. Shinde, S.G. Kulkarni, N. Maiti, P.M. Koinkar, and K.M. Sonawane, Gas sensing performance of Al doped ZnO thin film for H2S detection. J. Alloys Compd. 748, 6 (2018).
T.T.N. Hoa, D.T. Le, N.V. Toan, N.V. Duy, C.M. Hung, N.V. Hieu, and N.D. Hoa, Highly selective H2S gas sensor based on WO3-coated SnO2 nanowires. Mater. Today 26, 102094 (2021).
J. Fan, P. Liu, X. Chen, H. Zhou, S. Fu, and W. Wu, Carbon nanotubes-CuO/SnO2 based gas sensor for detecting H2S in low concentration. Nanotechnology 30, 475501 (2019).
S. Keshtkar, A. Rashidi, M. Kooti, M. Askarieh, S. Pourhashem, E. Ghasemy, and N. Izadi, A novel highly sensitive and selective H2S gas sensor at low temperatures based on SnO2 quantum dots-C60 nanohybrid: Experimental and theory study. Talanta 188, 531 (2018).
D. Zhang, J. Wu, and Y. Cao, Ultrasensitive H2S gas detection at room temperature based on copper oxide/molybdenum disulfide nanocomposite with synergistic effect. Sens. Actuators B 287, 346 (2019).
K.S. Yo, S.D. Han, H.G. Moon, S.J. Yoon, and Ch.Y. Kang, Highly sensitive H2S sensor based on the metal-catalyzed SnO2 nanocolumns fabricated by glancing angle deposition. Sensors 15, 15468 (2015).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Khoshnood, F., Manouchehri, S. & Yousefi, M.H. Sensing Sub-ppm Concentration of H2S Gas at Room Temperature Using Silver-Doped SnO2 Nanocrystals. J. Electron. Mater. 51, 1804–1812 (2022). https://doi.org/10.1007/s11664-022-09447-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11664-022-09447-4