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Postcomposition Preparation and Supercapacitive Properties of Polyaniline Nanotube/Graphene Oxide Composites with Interfacial Electrostatic Interaction

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Abstract

Polyaniline nanotubes (PANI-T) and graphene oxide (GO) have been compounded by a postcomposition method with the assistance of electrostatic adsorption. Using this so-called postcomposition method, both the electric double-layer capacitance of the GO and the pseudocapacitance of the conducting polymer can be utilized. PANI-T prepared by a rapid mixing method was positively charged by pretreatment with (3-aminopropyl)triethoxysilane (APTES). PANI/GO composites were obtained by mixing the positively charged PANI-T and negatively charge GO with the assistance of electrostatic attraction. Charge–discharge measurements in 1 mol L−1 H2SO4 aqueous electrolyte revealed that the specific capacitance of PANI-T/GO-10% could reach 1220 F g−1 at a current density of 0.5 A g−1, being much higher than the value of 648 F g−1 for PANI-T. After 500 cycles of charge–discharge testing, the composite retained 97% of its capacitance. These enhanced supercapacitive properties can be attributed to the two types of energy storage mechanism and the electrostatic interaction between GO and PANI-T. Preparation of such PANI-T/GO composite electrode materials by electrostatic adsorption thus provides an efficient approach for improvement of the supercapacitive properties of conducting polymers or metal oxides.

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Acknowledgments

This work was supported by Opening Project of Guangxi Key Laboratory of Calcium Carbonate Resources Comprehensive Utilization (HZXYKFKT201804), The Youth Innovation Team of Shaanxi Universities, Coal Washing & Preparation Center, Ningxia Coal Industry co., Ltd, CHN ENERGY, and Peak Plan of Xi’an University of Science and Technology. Natural Science Foundation of Shaanxi Province, China (Grant No. 2018JM5027).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Xi’an University of Science and Technology, Xi’an, 710054, People’s Republic of China

    Yong Zhang, Shanxin Xiong, Yuyun Wang, Bohua Wu, Jia Chu, Xiaoqin Wang, Runlan Zhang, Ming Gong, Zhen Li & Mengnan Qu

  2. Key Laboratory of Coal Resources Exploration and Comprehensive Utilization, Ministry of Land and Resources, Xi’an, 710021, People’s Republic of China

    Shanxin Xiong

  3. Guangxi Key Laboratory of Calcium Carbonate Resources Comprehensive Utilization, Hezhou University, Hezhou, 542899, People’s Republic of China

    Zhenming Chen

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  1. Yong Zhang
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Correspondence to Shanxin Xiong.

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Zhang, Y., Xiong, S., Wang, Y. et al. Postcomposition Preparation and Supercapacitive Properties of Polyaniline Nanotube/Graphene Oxide Composites with Interfacial Electrostatic Interaction. J. Electron. Mater. 49, 4076–4084 (2020). https://doi.org/10.1007/s11664-020-08128-4

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