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Dielectric and Magnetic Properties of Polyaniline-Blended Y-Type Ba2Ni2Fe12O22 Hexaferrite Composites

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Abstract

Polyaniline was blended to tune the magnetic properties of Ba2Ni2Fe12O22 hexaferrites. Polyaniline-blended Ba2Ni2Fe12O22 hexaferrite (weight ratios 1:1, 1:2 and 2:1) composites were prepared by the in situ polymerization method. The obtained polymer-blended ferrite composites were characterized by Fourier transform infrared spectroscopy, x-ray diffraction (XRD), scanning electron microscopy, and vibrating-sample magnetometer and low-frequency (20 Hz–2 MHz) dielectric measurements at room temperature. The presence of the hexagonal phases was detected in XRD peaks of Ba2Ni2Fe12O22 and polymer-blended hexaferrite composites. The dielectric studies showed that polyaniline-embedded hexaferrites have high values of dielectric constants compared with Y-type Ba2Ni2Fe12O22 hexaferrite. In addition, the saturation magnetization, coercivity and remanence magnetization of undoped Ba2Ni2Fe12O22 hexaferrite were decreased and tuned with the polyaniline concentration (from 43.98 emu/g to 9.32 emu/g, 611 Oe to 125 Oe, and 22.4 emu/g to 2.7 emu/g, respectively). Thus, the prepared polymer-blended hexaferrite composites showed promising magnetic and dielectric properties.

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Packiaraj, G., Sakthipandi, K., Jotania, R.B. et al. Dielectric and Magnetic Properties of Polyaniline-Blended Y-Type Ba2Ni2Fe12O22 Hexaferrite Composites. J. Electron. Mater. 49, 3317–3324 (2020). https://doi.org/10.1007/s11664-020-08051-8

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