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Carbon Fibers Loaded Composites for Microwave Absorbing Application: Effect of Fiber Length and Dispersion Process on Dielectric Properties

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Abstract

In this work, a new composite for microwave absorption applications, especially for anechoic chambers, is studied. We propose to substitute carbon black loaded polyurethane foam, currently used in commercial absorbers, by epoxy foam filled with carbon fibers. The purpose of the present paper is to study the influence of three dispersion methods (spatula, shear mixer and ultrasound probe) and four fiber lengths (1 mm, 3 mm, 6 mm and 12 mm) on the homogeneity and dielectric properties (permittivity ε′ and dielectric losses tanδ) of achieved composites. Long fibers dispersed with spatula have shown higher dielectric properties than short fibers. However, such a soft dispersion method was revealed to be inefficient to disperse properly the long fibers. Although a homogenous dispersion was obtained with the shear mixer (mechanical dispersion), we noticed an important degradation of the fibers which lead to a decrease of the dielectric properties. Dispersion with ultrasounds appears to be a good compromise between homogeneity and dielectric properties of composites. Finally, electromagnetic simulation predicted a high absorption performance for pyramidal absorber made with the 12 mm-carbon fibers loaded composite with reflection loss lower than − 50 dB for frequencies ranging between 8 GHz and 18 GHz.

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References

  1. J. Huo, L. Wang, and H. Yu, J. Mater. Sci. 44, 3917 (2009).

    Article  CAS  Google Scholar 

  2. C.P. Neo and V.K. Varadan, IEEE Trans. Electromagn. Compat. 46, 102 (2004).

    Article  Google Scholar 

  3. P. Bollen, N. Quievy, I. Huynen, C. Bailly, C. Detrembleur, J.M. Thomassin, and T. Pardoen, Scr. Mater. 68, 50 (2013).

    Article  CAS  Google Scholar 

  4. W. Emerson, IEEE Trans. Electromagn. Compat. 21, 484 (1973).

    Google Scholar 

  5. C.L. Holloway, R.R. DeLyser, R.F. German, P. McKenna, and M. Kanda, IEEE Trans. Electromagn. Compat. 39, 33 (1997).

    Article  Google Scholar 

  6. R. Kaur, G.D. Aul, and V. Chawla, Prog. Electromagn. Res. M 43, 157 (2015).

    Article  Google Scholar 

  7. I.S. Seo, W.S. Chin, and D.G. Lee, Compos. Struct. 66, 533 (2004).

    Article  Google Scholar 

  8. S.E. Lee, J.H. Kang, and C.G. Kim, Compos. Struct. 76, 397 (2006).

    Article  Google Scholar 

  9. W.S. Chin and D.G. Lee, Compos. Struct. 77, 457 (2007).

    Article  Google Scholar 

  10. W.H. Choi, H.K. Jang, J.H. Shin, T.H. Song, J.B. Kim, W.J. Lee, Y.S. Joo, and C.G. Kim, Electron. Lett. 49, 620 (2013).

    Article  CAS  Google Scholar 

  11. D.R. Smith, W.J. Padilla, D.C. Vier, S.C. Nemat-Nasser, and S. Schultz, Phys. Rev. Lett. 84, 4184 (2000). https://doi.org/10.1103/PhysRevLett.84.4184.

    Article  CAS  Google Scholar 

  12. F. Ding, Y. Cui, X. Ge, Y. Jin, and S. He, Appl. Phys. Lett. 100, 103506 (2012). https://doi.org/10.1063/1.3692178.

    Article  CAS  Google Scholar 

  13. Y. He, R. Gong, H. Cao, X. Wang, and Y. Zheng, Smart Mater. Struct. 16, 1501 (2007).

    Article  CAS  Google Scholar 

  14. S. Yoshida, M. Sato, E. Sugawara, and Y. Shimada, J. Appl. Phys. 85, 4636 (1999).

    Article  CAS  Google Scholar 

  15. S. Yoshida, S. Ando, Y. Shimada, K. Suzuki, K. Nomura, and K. Fukamichi, J. Appl. Phys. 93, 6659 (2003).

    Article  CAS  Google Scholar 

  16. H.K. Choudhary, R. Kumar, S.P. Pawar, A.V. Anupama, S. Bose, and B. Sahoo, Chem. Select 3, 2120 (2018).

    CAS  Google Scholar 

  17. T. Kasagi, T. Tsutaoka, and K. Hatakeyama, J. Phys.: Conf. Ser. 200, 082012 (2010). https://doi.org/10.1088/1742-6596/200/8/082012.

    Article  CAS  Google Scholar 

  18. E.H. Min, M.S. Kim, and J.G. Koh, J. Kor. Phys. Soc. 52, 1850 (2008).

    Article  CAS  Google Scholar 

  19. A. Berthault, D. Rousselle, and G. Zerah, J Magn Magn Mater. 112, 477 (1992). https://doi.org/10.1016/0304-8853(92)91236-M

  20. M.A. Popov, I.V. Zavislyak, A.S. Tatarenko, G. Srinivasan, and A.M. Balbashov, IEEE Trans. Magn. 45, 2053 (2009). https://doi.org/10.1109/TMAG.2008.2008414.

    Article  CAS  Google Scholar 

  21. S.M. Abbas, A.K. Dixit, R. Chatterjee, and T.C. Goel, J. Magn. Magn. Mater. 309, 20 (2007). https://doi.org/10.1016/j.jmmm.2006.06.006.

    Article  CAS  Google Scholar 

  22. H.K. Choudhary, R. Kumar, S.P. Pawar, U. Sundararaj, and B. Sahoo, Phys. Chem. Chem. Phys. 21, 15595 (2019). https://doi.org/10.1039/c9cp03305j.

    Article  CAS  Google Scholar 

  23. R. Kumar, H.K. Choudhary, A.V. Anupama, A.V. Menon, S.P. Pawar, S. Bose, and B. Sahoo, New J. Chem. 43, 5568 (2019).

    Article  CAS  Google Scholar 

  24. R. Kumar, H.K. Choudhary, S.P. Pawar, S. Bose, and B. Sahoo, Phys. Chem. Chem. Phys. 19, 23268 (2017).

    Article  CAS  Google Scholar 

  25. R. Moucka, A.V. Lopati, and N.E. Kazantseva, J. Mater. Sci. 42, 9480 (2007).

    Article  CAS  Google Scholar 

  26. H.K. Choudhary, S.P. Pawar, R. Kumar, A.V. Anupama, S. Bose, and B. Sahoo, Chem. Select 2, 830 (2017).

    Google Scholar 

  27. V.T. Truong, S.Z. Riddell, and R.F. Muscat, J. Mater. Sci. 33, 4971 (1998). https://doi.org/10.1023/A:1004498705776.

    Article  CAS  Google Scholar 

  28. M. Wan, J. Li, and S. Li, Polym. Adv. Technol. 12, 651 (2001).

    Article  CAS  Google Scholar 

  29. P. Chandrasekhar and K. Naishadham, Synth. Met. 105, 115 (1999). https://doi.org/10.1016/S0379-6779(99)00085-5.

    Article  CAS  Google Scholar 

  30. H.K. Choudhary, R. Kumar, S.P. Pawar, S. Bose, and B. Sahoo, J. Electron. Mater. (2019). https://doi.org/10.1007/s11664-019-07478-y.

    Article  Google Scholar 

  31. Z. Liu, G. Bai, Y. Huang, F. Li, Y. Ma, T. Guo, X. He, X. Lin, H. Gao, and Y. Chen, J. Phys. Chem. C 111, 13696 (2007).

    Article  CAS  Google Scholar 

  32. Z. Fan, G. Luo, Z. Zhang, L. Zhou, and F. Wei, Mater. Sci. Eng. B 132, 85 (2006).

    Article  CAS  Google Scholar 

  33. A. Saib, L. Bednarz, R. Daussin, C. Bailly, X. Lou, J.M. Thomassin, C. Pagnoulle, C. Detrembleur, R. Jerome, and I. Huynen, IEEE Trans. Microw. Theory Technol. 54, 2745 (2006).

    Article  CAS  Google Scholar 

  34. H. Zhao, X. Han, Z. Li, D. Liu, Y. Wang, Y. Wang, W. Zhou, and Y. Du, J. Colloid Interface Sci. 528, 174 (2018).

    Article  CAS  Google Scholar 

  35. H.B. Zhang, Q. Yan, W.G. Zheng, Z. He, and Z.Z. Yu, ACS Appl. Mater. Interfaces 3, 918 (2011).

    Article  CAS  Google Scholar 

  36. S.K. Kwon, J.M. Ahn, G.H. Kim, C.H. Chun, J.S. Hwang, and J.H. Lee, Polym. Eng. Sci. 42, 2165 (2002).

    Article  CAS  Google Scholar 

  37. J.H. Oh, K.S. Oh, C.G. Kim, and C.S. Hong, Compos. Part B Eng. 35, 49 (2004).

    Article  CAS  Google Scholar 

  38. H. Zhu, Indian J. Fibre Text. Res. 32, 391 (2007).

    CAS  Google Scholar 

  39. N. Zhao, T. Zou, C. Shi, J. Li, and W. Guo, Mater. Sci. Eng. B 127, 207 (2006).

    Article  CAS  Google Scholar 

  40. F. Nanni, P. Travaglia, and M. Valentini, Compos. Sci. Technol. 69, 485 (2009).

    Article  CAS  Google Scholar 

  41. G. Li, T. Xie, S. Yang, J. Jin, and J. Jiang, J. Phys. Chem. C 116, 9196 (2012).

    Article  CAS  Google Scholar 

  42. F. Qin and C. Brosseau, J. Appl. Phys. 111, 6 (2012).

    Google Scholar 

  43. X.F. Zhang, X.L. Dong, H. Huang, B. Lv, J.P. Lei, and C.J. Choi, J. Phys. D Appl. Phys. 40, 5383 (2007).

    Article  CAS  Google Scholar 

  44. N.C. Das, D. Khastgir, T.K. Chaki, and A. Chakraborty, Compos. Part A Appl. Sci. 31, 1069 (2000).

    Article  Google Scholar 

  45. M.S. Cao, W.L. Song, Z.L. Hou, B. Wen, and J. Yuan, Carbon 48, 788 (2010).

    Article  CAS  Google Scholar 

  46. S.H. Kim, Y.G. Park, and S.S. Kim, Phys. Status Solidi (C) 4, 4602 (2007). https://doi.org/10.1002/pssc.200777374.

    Article  CAS  Google Scholar 

  47. J. Keyte, K. Pancholi, and J. Njuguna, Front. Mater. (2019). https://doi.org/10.3389/fmats.2019.00224.

    Article  Google Scholar 

  48. B.G. Choa, S.H. Hwangb, M. Parkc, J.K. Parkc, Y.B. Parka, and H.G. Chaeb, Compos. Part B Eng. 160, 436 (2019). https://doi.org/10.1016/j.compositesb.2018.12.062.

    Article  CAS  Google Scholar 

  49. L. Chen, X. Yin, X. Fan, M. Chen, X. Ma, L. Cheng, and L. Zhang, Carbon 95, 10 (2015). https://doi.org/10.1016/j.carbon.2015.08.011.

    Article  CAS  Google Scholar 

  50. G. Shen, M. Xu, and Z. Xu, Mater. Chem. Phys. 105, 268 (2007). https://doi.org/10.1016/j.matchemphys.2007.04.056.

    Article  CAS  Google Scholar 

  51. Y. Liu, Z. Zhang, S. Xiao, C. Qiang, L. Tian, and J. Xu, Appl. Surf. Sci. 257, 7678 (2011). https://doi.org/10.1016/j.apsusc.2011.04.007.

    Article  CAS  Google Scholar 

  52. Y. Yang, B. Zhang, W. Xu, Y. Shi, Z. Jiang, N. Zhou, B. Gu, and H. Lu, J. Magn. Magn. Mater. 256, 129 (2003). https://doi.org/10.1016/S0304-8853(02)00436-5.

    Article  CAS  Google Scholar 

  53. C. Qiang, J. Xu, Z. Zhang, L. Tian, S. Xiao, Y. Liu, and P. Xu, J. Alloys Compd. 506, 93 (2010). https://doi.org/10.1016/j.jallcom.2010.06.193.

    Article  CAS  Google Scholar 

  54. SIEPEL. APM Microwave pyramidal absorber (2015). http://www.siepel.com/en/siepel-international/product/pyramidal-foam-apm-apx-0. Accessed 17 July 2019.

  55. E.J. Highwood and R.P. Kinnersley, Environ. Int. 32, 560 (2006).

    Article  CAS  Google Scholar 

  56. G. Oberdorster, A. Maynard, K. Donaldson, V. Castranova, J. Fitzpatrick, K. Ausman, J. Carter, B. Karn, W. Kreyling, D. Lai, S. Olin, N. Monteiro-Riviere, D. Warheit, and H. Yang, Part Fiber Toxicol. 2, 1 (2005).

    Article  CAS  Google Scholar 

  57. L. Pometcu, A. Sharaiha, R. Benzerga, and P. Pouliguen, Loughborough Antennas and Propagation Conference LAPC 2014, IEEE (2014), pp. 633–636. https://doi.org/10.1109/lapc.2014.6996472.

  58. Standard epoxy foaming 170 to 600 Kg/m3. http://sicomin.com/composite-datasheets-and-downloads. Accessed 17 July 2019.

  59. J. Zhang, N. Hori, and A. Takemura, Ind. Crops Prod. 138, 111455 (2019).

    Article  CAS  Google Scholar 

  60. Protective polyurethane foam liners. https://www.rajapack. co.uk/protective-packaging/foam-packaging/protective-polyu rethane-foam-liners_PDT00710.html?SearchCat=suggested&SearchQuery=Protective+polyurethane+foam+wrap+liners%2C+400x300mm%2C+pack+of+128. Accessed 17 July 2019.

  61. S.B. Jones and S.P. Friedman, Water Resour. Res. 36, 2821 (2000).

    Article  Google Scholar 

  62. J. Li, P.C. Ma, W.S. Chow, C.K. To, B.Z. Tang, and J.K. Kim, Adv. Funct. Mater. 17, 3207 (2007). https://doi.org/10.1002/adfm.200700065.

    Article  CAS  Google Scholar 

  63. C. Méjean, L. Pometcu, R. Benzerga, A. Sharaiha, C. Le Paven-Thivet, M. Badard, and P. Pouliguen, Mater. Sci. Eng. B 220, 59 (2017).

    Article  CAS  Google Scholar 

  64. J.Z. Liang and Q.Q. Yang, Compos. Part B 114, 457 (2017).

    Article  CAS  Google Scholar 

  65. L. Shen, F.Q. Wang, H. Yang, and Q.R. Meng, Polym. Test. 30, 442 (2011).

    Article  CAS  Google Scholar 

  66. L. Pometcu, Innovative materials and forms for attenuation at Hyper Frequencies (2016). https://tel.archives-ouvertes.fr/tel-01428908. Accessed 17 July 2019.

  67. S. Ramo, J.R. Whinnery, and T. Van Duzer, Fields and Waves in Communications Electronics (Hoboken: Wiley, 1994).

    Google Scholar 

  68. W. H. Hayt, Jr. and J. A. Buck, Engineering Electromagnetics, 6th edn. (2001), pp. 400–407.

  69. W. Duan, X. Yin, Q. Li, L. Schlier, P. Greil, N. Travitzky, and J. Eur, Ceram. Soc. 36, 3681 (2016).

    Article  CAS  Google Scholar 

  70. E.T. Thostenson and T.-W. Chou, Compos. Part A 30, 1055 (1999).

    Article  Google Scholar 

  71. P. Saville, Review of Radar Absorbing Materials (Hoboken: DTIC Document, 2005).

    Google Scholar 

  72. Y. Zhang, Y. Huang, T. Zhang, H. Chang, P. Xiao, H. Chen, Z. Huang, and Y. Chen, Adv. Mater. 27, 2049 (2015).

    Article  CAS  Google Scholar 

  73. H. Duana, H. Zhua, J. Yanga, J. Gaoc, Y. Yanga, L. Xub, G. Zhaoa, and Y. Liua, Compos. Part A Appl. 118, 41 (2019).

    Article  CAS  Google Scholar 

  74. W. Hong, P. Xiao, H. Luo, and Z. Li, Sci. Rep. 5, 14927 (2015). https://doi.org/10.1038/srep14927.

  75. L. Kong, X. Yin, X. Yuan, Y. Zhang, X. Liu, L. Cheng, and L. Zhang, Carbon 73, 185 (2014).

    Article  CAS  Google Scholar 

  76. Z.F. Zhang, G.H. Luo, Z.J. Fan, R. Xiang, L. Zhou, and F. Wei, Acta Phys. Chim. Sin. 22, 03 (2006).

    Google Scholar 

  77. F. Yang, X. Zhang, J. Han, and S. Du, Mater. Des. 29, 1817 (2008).

    Article  CAS  Google Scholar 

  78. B.K. Chung and H.T. Chuah, Prog. Electromagn. Res. 43, 273 (2003).

    Article  Google Scholar 

  79. V. Shaayegan, A. Ameli, S. Wang, and C.B. Park, Compos. Part A 88, 67 (2016).

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by the European Union through the European Regional Development Fund (ERDF), the Ministry of Higher Education and Research, the Région Bretagne, the Département des Côtes d’Armor and Saint-Brieuc Armor Agglomération, through the CPER Projects 2015-2020 MATECOM and SOPHIE/STIC & Ondes.

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Benzerga, R., Badard, M., Méjean, C. et al. Carbon Fibers Loaded Composites for Microwave Absorbing Application: Effect of Fiber Length and Dispersion Process on Dielectric Properties. J. Electron. Mater. 49, 2999–3008 (2020). https://doi.org/10.1007/s11664-020-07998-y

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