Skip to main content
Log in

Optical, Electrical, and Crystal Properties of TiO2 Thin Films Grown by Atomic Layer Deposition on Silicon and Glass Substrates

  • Topical Collection: Electronic Materials for Renewable Energy Applications
  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

TiO2 thin films have been deposited on glass and Si(100) by atomic layer deposition (ALD) technique using tetrakis(diethylamido)titanium(IV) and water vapor as reactants. Thorough investigation of the properties of the TiO2/glass and TiO2/Si thin films was carried out, varying the deposition temperature in the range from 100°C to 250°C while keeping the number of reaction cycles fixed at 1000. Physical and material property analyses were performed to investigate optical and electrical properties, composition, structure, and morphology. TiO2 films grown by ALD may represent promising materials for future applications in optoelectronic devices.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. W. Chiappim, G.E. Testoni, R.S. Moraes, R.S. Pessoa, J.C. Sagas, F.D. Origo, L. Vieira, and H.S. Maciel, Vacuum 123, 91 (2016).

    Article  Google Scholar 

  2. C.S. Kovash Jr., J.D. Hoefelmeyer, and B.A. Logue, Electrochim. Acta 67, 18 (2012).

    Article  Google Scholar 

  3. P.J. Cameron and L.M. Peter, J. Phys. Chem. B 109, 7392 (2005).

    Article  Google Scholar 

  4. T.W. Hamann, A.B.F. Martinson, J.W. Elam, M.J. Pellin, and J.T. Hupp, J. Phys. Chem. C 112, 10303 (2008).

    Article  Google Scholar 

  5. D.H. Kim, M. Woodroof, K. Lee, and G.N. Parsons, ChemSusChem 6, 1014 (2013).

    Article  Google Scholar 

  6. D.M. King, X. Liang, Y. Zhou, C.S. Carney, L.F. Hakim, P. Li, and A.W. Weimer, Powder Technol. 183, 356 (2008).

    Article  Google Scholar 

  7. S.M. George, Chem. Rev. 110, 111 (2010).

    Article  Google Scholar 

  8. M. Ritala and J. Niinistö, ECS Trans. 25, 641 (2009).

    Article  Google Scholar 

  9. C.-T. Wang and H.-L. Siao, Surf. Coat. Technol. 244, 63 (2014).

    Article  Google Scholar 

  10. T.-T. Duong, Y.-J. Kim, J.-H. Eom, J.-S. Choi, A.-T. Le, and S.-G. Yoon, RSC Adv. 5, 33515 (2015).

    Article  Google Scholar 

  11. E. Marin, A. Lanzutti, M. Lekka, L. Guzman, W. Ensinger, and L. Fedrizzi, Surf. Coat. Technol. 211, 84 (2012).

    Article  Google Scholar 

  12. H. Yaghoubi, N. Taghavinia, and E.K. Alamdari, Surf. Coat. Technol. 204, 1562 (2010).

    Article  Google Scholar 

  13. A. Ghobadi, T.G. Ulusoy, R. Garifullin, M.O. Guler, and A.K. Okyay, Sci. Rep. 6, 30587 (2016).

    Article  Google Scholar 

  14. W.S. Law, S.W. Lam, W.Y. Gan, J. Scott, and R. Amal, Thin Solid Films 517, 5425 (2009).

    Article  Google Scholar 

  15. S. Zhuiykov, M.K. Akbari, Z. Hai, C. Xue, H. Xu, and H. Lachlan, Mater. Des. 120, 99 (2017).

    Article  Google Scholar 

  16. Y. Xiong, M. Lai, J. Li, H. Yong, H. Qian, C. Xu, K. Zhong, and S. Xiao, Surf. Coat. Technol. 265, 78 (2015).

    Article  Google Scholar 

  17. C.C. Trapalis, P. Keivanidis, G. Kordas, M. Zaharescu, M. Crisan, A. Szatvanyi, and M. Gartner, Thin Solid Films 433, 186 (2003).

    Article  Google Scholar 

  18. G. Kosarsoy, E.H. Sen, N. Aksoz, S. Ide, and H. Aksoy, Appl. Surf. Sci. 318, 269 (2014).

    Article  Google Scholar 

  19. X. Wang, J. Zhang, W. Sun, W. Yang, J. Cao, Q. Li, Y. Peng, and J.K. Shang, Chem. Eng. J. 264, 437 (2015).

    Article  Google Scholar 

  20. J. Lyytinen, X. Liu, O.M.E. Ylivaara, S. Sintonen, A. Iyer, S. Ali, J. Julin, H. Lipsanen, T. Sajavaara, R.L. Puurunen, and J. Koskinen, Wear 342–343, 270 (2015).

    Article  Google Scholar 

  21. R.C. Suciu, E. Indrea, T.D. Silipas, S. Dreve, M.C. Rosu, V. Popescu, G. Popescu, and H.I. Nascu, J. Phys: Conf. Ser. 182, 012080 (2009).

    Google Scholar 

  22. J. Musil, D. Heřman, J. Šícha, J. Vac. Sci. Technol. A Vac. Surf. Films 24, 521 (2006).

  23. M. Ghaffari, B. Cosar, H.I. Yavuz, M. Ozenbas, and A.K. Okyay, Electrochim. Acta 76, 446 (2012).

    Article  Google Scholar 

  24. H. Karaagac, L.E. Aygun, M. Parlak, M. Ghaffari, N. Biyikli, and A.K. Okyay, Phys. Status Solidi Rapid Res. Lett. 6, 442 (2012).

    Article  Google Scholar 

  25. J. Aarik, A. Aidla, T. Uustare, K. Kukli, V. Sammelselg, M. Ritala, and M. Leskela, Appl. Surf. Sci. 193, 277 (2002).

    Article  Google Scholar 

  26. R. Garifullin, H. Eren, T.G. Ulusoy, A.K. Okyay, N. Biyikli, and M.O. Guler, Phys. Status Solidi A 213, 3238 (2016).

    Article  Google Scholar 

  27. A. Haider, H. Cansizoglu, M.F. Cansizoglu, N. Biyikli, A.K. Okyay, and T. Karabacak, J. Vac. Sci. Technol. A Vac. Surf. Films 33, 01A110 (2015).

    Article  Google Scholar 

  28. R. Hussin, K.L. Choy, and X.H. Hou, Adv. Mater. Res. 1133, 352 (2016).

    Article  Google Scholar 

  29. C. Jin, B. Liu, Z. Lei, and J. Sun, Nanoscale Res. Lett. 10, 95 (2015).

    Article  Google Scholar 

  30. Y.J. Shi, R.J. Zhang, H. Zheng, D.H. Li, W. Wei, X. Chen, Y. Sun, Y.F. Wei, H.L. Lu, N. Dai, and L.Y. Chen, Nanoscale Res. Lett. 12, 243 (2017).

    Article  Google Scholar 

  31. Z.P. Yang, H.E. Cheng, I. Chang, and I.S. Yu, Appl. Sci. J. 6, 8 (2016).

    Article  Google Scholar 

  32. L.B. McCusker, R.B. Von Dreele, D.E. Cox, D. Louer, and P. Scardi, J. Appl. Crystallogr. 32, 36 (1999).

    Article  Google Scholar 

  33. V.P. Zakaznova-Herzog, H.W. Nesbitt, G.M. Bancroft, and J.S. Tse, Surf. Sci. 600, 3175 (2006).

    Article  Google Scholar 

  34. D.A. Shirley, Phys. Rev. B 5, 4709 (1972).

    Article  Google Scholar 

  35. J. Chastain, Handbook of x-ray Photoelectron Spectroscopy (Waltham: Perkin-Elmer, 1992).

    Google Scholar 

  36. V. Young and T. Otagawa, Appl. Surf. Sci. 20, 228 (1985).

    Article  Google Scholar 

  37. D. Briggs and M.P. Seah, eds., Surface and Interface Analysis (Chichester: Wiley, 1983), p. xiv + 533.

  38. C. Wagner, D. Zatko, and R. Raymond, Anal. Chem. 52, 1445 (1980).

    Article  Google Scholar 

  39. S.J. Xiao, M. Textor, N.D. Spencer, and H. Sigrist, Langmuir 14, 5507 (1998).

    Article  Google Scholar 

  40. C. Viornery, Y. Chevolot, D. Leonard, B.O. Aronsson, P. Pechy, H.J. Mathieu, P. Descouts, and M. Gratzel, Langmuir 18, 2582 (2002).

    Article  Google Scholar 

  41. N.A. Smith, G.G. Antoun, A.B. Ellis, and W.C. Crone, Compos. A Appl. Sci. Manuf. 35, 1307 (2004).

    Article  Google Scholar 

  42. A.K. Okyay, F.B. Oruç, F. Cimen, and L.E. Aygün, Proc. SPIE Int. Soc. Opt. Eng. 8626, 16 (2013).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to H. Ates.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kupa, I., Unal, Y., Cetin, S.S. et al. Optical, Electrical, and Crystal Properties of TiO2 Thin Films Grown by Atomic Layer Deposition on Silicon and Glass Substrates. J. Electron. Mater. 47, 4502–4507 (2018). https://doi.org/10.1007/s11664-018-6370-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11664-018-6370-y

Keywords

Navigation