Abstract
Dye sensitized solar cells (DSSC) were fabricated from a coumarin NKX-2700 dye-sensitized core–shell photoanode and a quasi-solid-state electrolyte, sandwiched together, with a cobalt sulfide-coated counter electrode. The core–shell photoanode consisted of a composite mixture of 90% TiO2 nanoparticles and 10% TiO2 nanowires (TNPW) as core layer and MgO nanoparticles (MNP) as shell layer. Hafnium oxide (HfO2) was applied to the core–shell photoanode film as a blocking layer. TiO2 nanoparticles, TiO2 nanowires, and TNPW/MNP were characterized by x-ray diffractometry, scanning electron microscopy, and transmission electron microscopy. It was apparent from the UV–visible spectrum of the sensitizing dye coumarin NKX-2700 that its absorption was maximum at 525 nm. Power conversion efficiency (PCE) was greater for DSSC-1, fabricated with a core–shell TNPW/MNP/HfO2 photoanode, than for the other DSSC; its photovoltaic properties were: short circuit photocurrent J sc = 19 mA/cm2, open circuit voltage (V oc) = 720 mV, fill factor (FF) = 66%, and PCE (η) = 9.02%. The charge-transport and charge-recombination behavior of the DSSC were investigated by electrochemical impedance spectroscopy; the results showed that the composite core–shell film resulted in the lowest charge-transfer resistance (R CE) and the longest electron lifetime (τ eff). Hence, the improved performance of DSSC-1 could be ascribed to the core–shell photoanode with blocking layer, which increased electron transport and suppressed recombination of charge carriers at the photoanode/dye/electrolyte interface.
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References
B.O. Regan and M. Grätzel, Nature 353, 737 (1991).
M. Grätzel, Nature 414, 338 (2001).
B. Tan and Y. Wu, J. Phys. Chem. B 110, 15932 (2006).
M.K. Nazeeruddin, F. de Angelis, and S. Fantacci, et al., J. Am. Chem. Soc. 127, 16835 (2005).
M. Wei, Y. Konishi, H. Zhou, M. Yanagida, H. Sugihara, and H. Arakawa, J. Mater. Chem. 16, 1287 (2006).
J. Nelson, Phys. Rev. B 59, 15374 (1999).
J.H. Heo, S.H. Im, J.H. Noh, T.N. Mandal, C.-S. Lim, J.A. Chang, Y.H. Lee, H.-J. Kim, A. Sarkar, Md.K Nazeeruddin, M. Gratzel, and S. Seok II, Nature Photonics 80, 1 (2013). doi:10.1038/NPHOTON.2013.80.
N. Koide, A. Islam, Y. Chiba, and L. Han, J. Photochem. Photobiol. A 182, 296 (2006).
S. Chappel, S.G. Chen, and A. Zaban, Langmuir 18, 3336 (2002).
S.G. Diamant, O. Chen, A. Melamed, and A. Zaban, J. Phys. Chem. B 107, 1977 (2003).
Y. Diamant, S. Chappel, S.G. Chen, O. Melamed, and A. Zaban, Coordination. Chem. Rev. 248, 1271 (2004).
S.G. Chen, S. Chappel, Y. Diamant, and A. Zaban, Chem. Mater. 13, 4629 (2001).
R. Katoh, A. Furube, and T. Yoshihara, et al., J. Phys. Chem. B 108, 4818 (2004).
E. Palomares, J.N. Clifford, S.A. Haque, T. Lutz, and J.R. Durrant, JACS 125, 475 (2003).
Bihui Li, Gang Lü, Lijuan Luo, and Yiwen Tang, J. Nat. Sci. 15, 325 (2010).
P. Basyach and A. Choudhury, Int. J. Innovat. Res. Develop. 1, 175 (2012).
P. Ramasamy, M.-S. Kang, H.-J. Cha, and J. Kim, Mater. Res. Bull. 48, 79 (2012).
K. Hara, Z.-S. Wang, T. Sato, A. Furube, R. Katoh, H. Sugihara, Y. D, C. Kasada, A. Shinpo, and S. Suga, J. Phys. Chem. B 109, 15476 (2005).
Z.S. Wang, Y. Cui, K. Hara, Y. Dan-oh, C. Kasada, and A. Shinpo, Adv. Mater. 19, 1138 (2007).
E. Stathatos and P. Lianos, a. Chem. Mater. 15, 1825 (2003).
W. Kubo, S. Kambe, S. Nakade, T. Kitamura, K. Hanabusa, Y. Wada, and S. Yanagida, J. Phys. Chem. B 107, 4374 (2003).
J.H. Wu, Z. Lan, J.M. Lin, M.L. Huang, S.C. Hao, T. Sato, and S. Yin, Adv. Mater. 19, 4006 (2006).
P. Wang, S.M. Zakeeruddin, J.E. Moser, M.K. Nazeeruddin, T. Sekiguchi, and M. Grätzel, Nat. Mater. 2, 402 (2003).
C.H. Lee, S.W. Rhee, and H.W. Choi, Nanoscale Res. Lett. 7, 48 (2012).
X. Feng, K. Shankar, O.K. Varghese, M. Paulose, T.J. LaTempa, and C.A. Grimes, Nano Lett. 8, 3781 (2008).
K. Hara, T. Sato, R. Katoh, A. Furube, Y. Ohga, A. Shinpo, S. Suga, K. Sayama, H. Sugihara, and H. Arakawa, J. Phys. Chem. B 107, 597 (2003).
K. Hara, Y. Tachibana, Y. Ohga, A. Shinpo, S. Suga, K. Sayama, and Hideki Sugihara Hironori Arakawa, Sol. Energy Mater. Sol. Cells 77, 89 (2003).
J.Y. Kim, S.W. Lee, J.H. Noh, H.S. Jung, and K.S. Hong, J. Electroceram. 23, 422 (2009).
Q. Zheng, H. Kang, J. Yun, J. Lee, J.H. Park, and S. Baik, ACS Nano 5, 5088 (2011).
G. Schlichthorl, S.Y. Huang, J. Sprague, and A.J. Frank, J. Phys. Chem. B 101, 8141 (1997).
G. Schlichthorl, N.G. Park, and A.J. Frank, J. Phys. Chem. B 103, 782 (1999).
R. Kern, R. Sastrawan, J. Ferber, R. Stangl, and J. Luther, Electrochim. Acta 47, 4213 (2002).
N.G. Park, M.G. Kang, K.M. Kim, K.S. Ryu, S.H. Chang, D.K. Kim, J. van de Lagemaat, K.D. Benkstein, and A.J. Frank, Langmuir 20, 4246 (2004).
J. Bisquert, J. Phys. Chem. B 106, 325 (2002).
M. Adachi, M. Sakamoto, J. Jiu, Y. Ogata, and S. Isoda, J. Phys. Chem. B 110, 13872 (2006).
B. Tan and Y. Wu, J. Phys. Chem. B 110, 2087 (2006).
J.J. Wu, G.R. Chen, C.C. Lu, W.T. Wu, and J.S. Chen, Nanotechnology 19, 105702 (2008).
J. Nelson and R.E. Chandler, Coord. Chem. Rev. 248, 1181 (2004).
C.H. Lee, S.W. Rhee, and H.W. Choi, Nanoscale Res. Lett. 7, 48 (2012).
S. Wu, H. Han, Q. Tai, J. Zhang, S. Xu, C. Zhou, Y. Yang, H. Hu, B.L. Chen, B. Sebo, and X.-Z. Zhao, Nanotechnology 19, 215704 (2008).
H.S. Jung, J.K. Lee, M. Nastasi, S.W. Lee, J.Y. Kim, J.S. Park, K.S. Hong, and H. Shin, Langmuir 21, 10332 (2005).
Mariyappan Shanmugam and Mahdi Farrokh, Thin Solid Films 518, 2678 (2010).
J. van de Lagemaat, N.G. Park, and A.J. Frank, J. Phys. Chem. B 104, 2044 (2008).
Acknowledgement
We thank Bharathiar University, Coimbatore and Annamalai University, Chidambaram, for allowing us to perform this work in their laboratory.
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Maheswari, D., Venkatachalam, P. Improved Performance of Dye-Sensitized Solar Cells Fabricated from a Coumarin NKX-2700 Dye-Sensitized TiO2/MgO Core–Shell Photoanode with an HfO2 Blocking Layer and a Quasi-Solid-State Electrolyte. J. Electron. Mater. 44, 967–976 (2015). https://doi.org/10.1007/s11664-014-3595-2
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DOI: https://doi.org/10.1007/s11664-014-3595-2