PbTe/Ag composite powders were synthesized by a chemical plating method and then compacted by spark plasma sintering (SPS) at 573 K to 673 K and 50 MPa. The effects of the sintering temperature on the thermoelectric properties of PbTe and the PbTe/Ag composites were investigated. The thermoelectric properties of PbTe and PbTe/Ag bulk samples were measured in the temperature range from 300 K to 700 K. PbTe/Ag bulk samples changed electrical transport behavior from p-type to n-type at room temperature. The SPS temperature not only changed the lattice parameter but also affected the conduction behavior of PbTe/Ag composites. The variation in the carrier concentration was determined by the role of the Ag dopant for different SPS temperatures. Moreover, the conduction of the PbTe/Ag samples changed from metallic to semiconducting in the measured temperature range from 300 K to 700 K as the sintering temperature increased. For the PbTe/Ag bulk materials subjected to SPS at 573 K and 673 K, the values of the power factor were 0.38 mW/m K2 and 1.31 mW/m K2 at 700 K, respectively.
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Sie, F.R., Hwang, C.S., Tang, Y.H. et al. Effect of Sintering Temperature on Thermoelectric Properties of PbTe/Ag Composites Fabricated by Chemical Plating and Spark Plasma Sintering. J. Electron. Mater. 44, 1450–1455 (2015). https://doi.org/10.1007/s11664-014-3411-z
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DOI: https://doi.org/10.1007/s11664-014-3411-z