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Enthalpy of Mixing of Liquid Cu-Fe-Zr Alloys at 1873 K (1600 °C)

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Abstract

The enthalpies of mixing of liquid Cu-Fe-Zr alloys were determined at 1873 K (1600 °C) by using a high-temperature isoperibolic calorimeter. The measurements were performed along sections x Cu/x Fe = 3/1, 1/1, 1/3 in the composition range x Zr = 0 to 0.55. The limiting partial enthalpies of mixing of undercooled liquid zirconium in liquid Cu-Fe alloys are (–91.8 ± 8.4) kJ mol−1 (section x Cu/x Fe = 3/1), (–94.1 ± 12.8) kJ mol−1 (section x Cu/x Fe = 1/1), and (–107.3 ± 15.6) kJ mol−1 (section x Cu/x Fe = 1/3). The integral mixing enthalpies are sign changing over the investigated composition range. The Redlich–Kister–Muggianu polynomial was used for the least square fit of the experimental results in order to obtain an analytical expression for the integral mixing enthalpy.

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Acknowledgments

This work was supported by the Ministry of Education and Science of Ukraine under the Grant 0112U001245.

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Authors and Affiliations

  1. Metallurgical Department, Donbass State Engineering Academy, Shkadinova Street 72, Kramatorsk, 84313, Ukraine

    Liya A. Dreval (Post Doctoral), Pavel G. Agraval (Docent) & Mikhail A. Turchanin (Professor)

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  1. Liya A. Dreval
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  2. Pavel G. Agraval
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  3. Mikhail A. Turchanin
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Correspondence to Liya A. Dreval.

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Manuscript submitted December 6, 2013.

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Dreval, L.A., Agraval, P.G. & Turchanin, M.A. Enthalpy of Mixing of Liquid Cu-Fe-Zr Alloys at 1873 K (1600 °C). Metall Mater Trans B 46, 2234–2245 (2015). https://doi.org/10.1007/s11663-015-0383-1

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