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Effect of Cryogenic Thermal Cycling on Tribocorrosion Performance of Fe-Based Bulk Amorphous Alloy in 3.5 Pct NaCl Solution

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Abstract

The effects of cryogenic thermal cycling on the tribocorrosion behavior of Fe41Co7Cr15Mo14C15B6Y2 bulk amorphous alloy were studied in 3.5 pct NaCl solution. The relaxation enthalpy and fracture toughness increased by the cryogenic thermal cycling treatment while the hardness decreased. Moreover, the corrosion resistance enhanced with the formation of more stable passive film. Accordingly, when sliding against ZrO2 ball under 10 N load in 3.5 pct NaCl solution, the corrosive wear rates of Fe-based bulk amorphous alloys generally decreased with the increase of the number of cryogenic thermal cycles. After 60-cycle treatment, the wear rate decreased by 36.4 pct, which is about 3.3 times lower than that of 316L SS. Meanwhile, cryogenic thermal cycling is beneficial to reduce the coefficient of friction (COF). The dominant wear mechanism is the abrasive wear combined with corrosive wear. The improved toughness and passivation ability due to the cryogenic thermal cycling are responsible for the decline of ΔVW, so as to enhance the tribocorrosion resistance. Therefore, cryogenic thermal cycling could be an effective way to improve the tribocorrosion performance of amorphous alloys and coatings in marine environment.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (51875169) and STU Scientific Research Foundation for Talents (NTF21011).

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The authors declare that they have no conflict of interest.

CRediT Authorship Contribution

Juan Jin: Methodology, Investigation, Data curation, and Writing—original draft. Xiulin Ji: Methodology, Investigation, Data curation, Writing—original draft, Writing—review & editing, Resources, and Supervision. Sheng Cao: Methodology, Data curation, and Visualization. Weiwei Zhu: Methodology, Conceptualization, and Resources.

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  1. College of Mechanical & Electrical Engineering, Hohai University, Changzhou, 213022, P.R. China

    Juan Jin & Xiulin Ji

  2. Department of Mechatronics Engineering, Shantou University, Shantou, 515063, P.R. China

    Xiulin Ji, Sheng Cao & Weiwei Zhu

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  1. Juan Jin
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Jin, J., Ji, X., Cao, S. et al. Effect of Cryogenic Thermal Cycling on Tribocorrosion Performance of Fe-Based Bulk Amorphous Alloy in 3.5 Pct NaCl Solution. Metall Mater Trans A 53, 3404–3417 (2022). https://doi.org/10.1007/s11661-022-06756-5

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