Abstract
Three organic compounds containing azole rings 1-benzyl-4-phenyl-1H-1,2,3-triazole (I1), 5-phenyl-3-propylisoxazole (I2), and 3,5-diphenylisoxazole (I3) were synthesized and characterized as corrosion inhibitors on galvanized steel and copper-nickel (Cu-Ni, 90/10) substrates. The three tested azole inhibitors acted as corrosion inhibitors on galvanized steel in the presence of real cooling water used as electrolyte. Electrochemical performance indicated that the presence of heteroatoms, such as N and O, with free pair electrons, the chain length, and the aromatic ring plays an important role in the capacity to inhibit corrosion of galvanized steel. 3,5-diphenylisoxazole (I3) has the best inhibition activity with jcorr of 2.04 × 10−7 (5 ppm), 7.57 × 10−8 (10 ppm), and 1.73 × 10−8 (20 ppm) A cm−2, followed by compounds I1 and I2. The synthesized compounds are comparable or even higher than the electrochemical performance of commercial inhibitor tolyltriazole (TTA, jcorr = 3.06 × 10−8 A cm−2). Conversely, for Cu-Ni (90/10) substrates, commercial TTA with 20 ppm displayed the lowest corrosion current densities (jcorr = 3.20 × 10−8 A cm−2) through a characteristic anodic pseudo-passivation; however, pits were observed after ~550 mVAg/AgCl. In contrast, the synthesized compounds tended to suppress anodic copper dissolution at positive potentials but, in the best case, displayed greater corrosion rates I3 (1.463 mils per year (MPY)), I2 (1.515 MPY), and I1 (0.677 MPY) in comparison with TTA (0.091 MPY). The low inhibition efficiency (IE) of synthesized compounds is correlated to the weak absorption on the copper surface.
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Acknowledgments
One of the authors (DEO-DLT) is grateful for her postgraduate fellowship to Consejo Nacional de Ciencia y Tecnología (CONACYT), México; Comisión de Operación y Fomento de Actividades Académicas del IPN (COFAA), México; and Secretaría de Investigación y Posgrado (SIP) del Instituto Politécnico Nacional (IPN), México. The authors are also grateful for the financial support provided by the Instituto Politécnico Nacional through the SIP2019-6650, SIP2019-6670, and SIP2019-6718 projects; CONACyT CB2015-252181 and C-2014-1905 projects; as well as SNI-CONACyT.
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Domínguez-Crespo, M.A., Zepeda-Vallejo, L.G., Torres-Huerta, A.M. et al. New Triazole and Isoxazole Compounds as Corrosion Inhibitors for Cu-Ni (90/10) Alloy and Galvanized Steel Substrates. Metall Mater Trans A 51, 1822–1845 (2020). https://doi.org/10.1007/s11661-019-05615-0
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DOI: https://doi.org/10.1007/s11661-019-05615-0