Abstract
The industrial significance of microalloyed martensitic steels manufactured via cold rolling, reaustenitization, and quenching has been typically recognized as low. However, it is currently believed that microalloying can improve the in-service properties of ultra-high-strength press hardening steels. In this work, five 34MnB5-based steels were designed to address the role of Ti and V when combined with Cr or Mo. Microstructure-property relationships were analyzed after die quenching and additional bake hardening (BH) heat treatment using advanced methods of microscopy, glow discharge optical emission spectroscopy, quasi-static tensile tests, and three-point bending tests. Results indicate that both Ti and V can provide grain size refinement through the formation of stabile nanosized precipitates. The BH treatment improved postuniform elongation values, indicating a trend of improved ductility. However, the expected improvements in bendability were clearly confirmed only for two V-microalloyed steels with the alloying concepts of 0.3Cr-0.15V-0.03Al-0.02Ti-0.0020B and 0.3Mo-0.15V-0.0060N (without Al-Ti-B additions) (wt pct). Thus, it was discovered that microalloying with V, when combined with either Cr or Mo, provides a promising combination of mechanical properties as far as the austenitization parameters are appropriately controlled.
Similar content being viewed by others
Notes
JEOL is a trademark of Japan Electron Optics Ltd., Tokyo.
References
K. Mori, P.F. Bariani, B.-A. Behrens, A. Brosius, S. Bruschi, T. Maeno, M. Merklein, and J. Yanagimoto: CIRP Ann.-Manuf. Techn., 2017, vol. 66 (2), pp. 755–77.
T. Gerber, I. Heckelmann, N. Vives Diaz, and F.-J. Lenze: Proc. 4th Int. Conf. on Hot Sheet Metal Forming of High-Performance Steel, Luleå, 2013, M. Oldenburg, P. Prakash, and K. Steinhoff, eds., 2013, pp. 145–52.
G. Krauss: Mater. Sci. Eng. A, 1999, vols. 273–275, pp. 40–57.
M. Naderi: Doctoral Thesis, University of Aachen, Aachen, 2007.
H. Mohrbacher: Proc. 6th Int. Conf. on Hot Sheet Metal Forming of High-Performance Steel, Atlanta, GA, 2017, M. Oldenburg, P. Prakash, and K. Steinhoff, eds., 2017, pp. 213–20.
A. Tokizawa, K. Yamamoto, Y. Takemoto, and T. Senuma: Proc. 4th Int. Conf. on Hot Sheet Metal Forming of High-Performance Steel, Luleå, 2013, M. Oldenburg, P. Prakash, and K. Steinhoff, eds., 2013, pp. 473–79.
P. Larour, H. Pauli, T. Kurz, and T. Hebesberger: Proc. Ann. Conf. Int. Deep Drawing Research Group (IDDRG 2010), Graz, 2010.
J. Bian, L. Wang, H. Mohrbacher, H.Z. Lu, and W.J. Wang: Adv. Mater. Res., 2015, vol. 1063, pp. 7–20.
T. Kurz, P. Larour, J. Lackner, T. Steck, and G. Jesner: Proc. Ann. Conf. Int. Deep Drawing Research Group (IDDRG 2016), Linz, 2016, E. Till et al., eds., 2016, pp. 414–27.
D. Fan, H. Kim, and B. De Cooman: Steel Res. Int., 2009, vol. 80 (3), pp. 241–48.
H. Järvinen, M. Honkanen, M. Järvenpää, and P. Peura: J. Mater. Process. Technol., 2018, vol. 252, pp. 90–104.
P. Dietsch, K. Tihay, S. Cobo, S. Sarkar, D. Hasenpouth, and D. Cornette: Proc. 6th Int. Conf. on Hot Sheet Metal Forming of High-Performance Steel, Atlanta, GA, 2017, M. Oldenburg, P. Prakash, and K. Steinhoff, eds., 2017, pp. 629–38.
J. Bian, H. Lu, W. Wang, and A. Guo: Proc. 6th Int. Conf. on Hot Sheet Metal Forming of High-Performance Steel, Atlanta, GA 2017, M. Oldenburg, P. Prakash, and K. Steinhoff, eds., 2017, pp. 600–09.
J. Wang, Y. Liu, Q. Lu, J. Pang, Z. Wang, C.M. Enloe, J.P. Singh, and C.D. Horvath: Proc. 6th Int. Conf. on Hot Sheet Metal Forming of High-Performance Steel, Atlanta, GA, 2017, M. Oldenburg, P. Prakash, and K. Steinhoff, eds., pp. 717–27.
W.S. Choi and B.C. De Cooman: Steel Res. Int., 2014, vol. 85 (5), pp. 824–35.
J. Bian and H. Mohrbacher: Proc. AIST Int. Symp. of New Developments of Advanced High Strength Sheet Steels, CO, p. 251.
K. Hikida, T. Nishibata, H. Kikuchi, T. Suzuki, and N. Nakayama: Proc. 5th Int. Conf. on Hot Sheet Metal Forming of High-Performance Steel, Toronto, 2015, K. Steinhoff, M. Oldenburg, and P. Prakash, eds., 2015, pp. 127–34.
M. Maikranz-Valentin: Proc. 6th Int. Conf. on Hot Sheet Metal Forming of High-Performance Steel, Atlanta, GA, 2017, M. Oldenburg, P. Prakash, and K. Steinhoff, eds., 2017, pp. 317–24.
S. Otani, M. Kozuka, T. Murakami, J. Naito, A. Pichler, and T. Kurz: Proc. 5th Int. Conf. on Hot Sheet Metal Forming of High-Performance Steel, Toronto, 2015, K. Steinhoff, M. Oldenburg, and P. Prakash, eds., 2015, pp. 411–16.
B. Hutchinson, D. Martin, O. Karlsson, F. Lindberg, H. Thoors, R.K.W. Marceau, and A.S. Taylor: Mater. Sci. Technol., 2017, vol. 33 (4), pp. 497–506.
M. Matsumoto, Y. Takemoto, and T. Senuma: Proc. 5th Int. Conf. on Hot Sheet Metal Forming of High-Performance Steel, Toronto, 2015, K. Steinhoff, M. Oldenburg, and P. Prakash, 2015, pp. 55–63.
T. Kishimoto, Y. Takemoto, and T. Senuma: Proc. 6th Int. Conf. on Hot Sheet Metal Forming of High-Performance Steel, Atlanta, GA, 2017, M. Oldenburg, P. Prakash, and K. Steinhoff, eds., 2017, pp. 187–94.
H. Asahi: ISIJ Int., 2002, vol. 42 (10), pp. 1150–55.
F. Han, B. Hwang, D. Suh, Z. Wang, D.L. Lee, and S. Kim: Met. Mater. Int., 2008, vol. 14 (6), p. 667–72.
W.T. Geng, A.J. Freeman, and G.B. Olson: Phys. Rev. B, 2001, vol. 63, art. no. 165415.
H. Kitahara, R. Ueji, N. Tsuji, and Y. Minamino: Acta Mater., 2006, vol. 54 (5), pp. 1279–88.
T.N. Baker: Ironmak. Steelmak., 2016, vol. 43 (4), pp. 264–307.
D.K. Matlock and J.G. Speer: Mater. Sci. Technol., 2009, vol. 25 (9), pp. 1118–25.
S.-C. Wang and P.-W. Kao: J. Mater. Sci., 1993, vol. 28 (19), pp. 5169–75.
D. Glisic, N. Radovic, A. Koprivica, A. Fadel, and D. Drobnjak: ISIJ Int., 2010, vol. 50, pp. 601–06.
H. Järvinen, M. Isakov, T. Nyyssönen, M. Järvenpää, and P. Peura: Mater. Sci. Eng. A, 2016, vol. 676, pp. 109–20.
O.G. Kasatkin, B.B. Vinokur, and V.L. Pilyushenko: Met. Sci. Heat Treat., 1984, vol. 26 (1), pp. 27–31.
“Steel. Determination of Yield Strength Increase by the Effect of Heat Treatment (Bake-Hardening-Index),” EN 10325:2006, BSI, 2006.
T. Nyyssönen, M. Isakov, P. Peura, and V.-T. Kuokkala: Metall. Mater. Trans. A, 2016, vol. 47A, pp. 2587–90.
ImageJ (Image Processing and Analysis in Java), https://imagej.nih.gov/ij/index.html, accessed 24 May 2018.
VDA 238-100 test specification draft: Plate Bending Test for Metallic Materials. Accessed 12 2010.
T. Nishibata and N. Kojima: J. Alloy Compd., 2013, vol. 577 (0), pp. 549–54.
G. Krauss: ISIJ Int., 1995, vol. 35 (4), pp. 349–59.
W.S. Choi, J. Lee, and B.C. De Cooman: Mater. Sci. Eng. A, 2015, vol. 639, pp. 439–47.
R. Soto, W. Saikaly, X. Bano, C. Issartel, G. Rigaut, and A. Charai: Acta Mater., 1999, vol. 47 (12), pp. 3475–81.
Y. Han, J. Shi, L. Xu, W.Q. Cao, and H. Dong: Mater. Des., 2012, vol. 34, pp. 427–34.
S. Aminorroaya and R. Dippenaar: J. Microsc.-Oxford, 2008, vol. 232, pp. 123–29.
T. Gladman: The Physical Metallurgy of Microalloyed Steels, The Institute of Materials, London, 1997, pp. 81–211.
R. Lagneborg, T. Siwecki, S. Zajac, and B. Hutchinson, Scand. J. Metall., 1999, vol. 28, pp. 186–241.
Y. Funakawa, T. Shiozaki, K. Tomita, T. Yamamoto, and E. Maeda, ISIJ Int., 2004, vol. 44 (11), pp. 1945–51.
S. Zajac, T. Siwecki, W.B. Hutchinson, and R. Lagneborg: ISIJ Int., 1998, vol. 38 (10), pp. 1130–39.
S.-I. Tabata, K. Hikida, and K. Kusumi: Proc. 6th Int. Conf. on Hot Sheet Metal Forming of High-Performance Steel, Atlanta, GA, 2017, M. Oldenburg, P. Prakash, and K. Steinhoff, 2017, pp. 299–307.
E.I. Galindo-Nava and P.E.J. Rivera-Díaz-del-Castillo: Acta Mater., 2015, vol. 98, pp. 81–93.
B. Ju, H. Wu, D. Tang, and N. Dang: J. Iron Steel Res. Int., 2016, vol. 23 (5), pp. 495–500.
E.I. Galindo-Nava and P.E.J. Rivera-Díaz-del-Castillo: Scripta Mater., 2016, vol. 110, pp. 96–100.
M. Maikranz-Valentin, U. Weidig, U. Schoof, H.-H. Becker, and K. Steinhoff: Steel Res. Int., 2008, vol. 79 (2), pp. 92–97.
M. Saeglitz and G. Krauss: Metall. Mater. Trans. A, 1997, vol. 28A, pp. 377–87.
S.C. Kennett, G. Krauss, and K.O. Findley: Scripta Mater., 2015, vol. 107, pp. 123–26.
A.G. Kostryzhev, A. Al Shahrani, C. Zhu, J.M. Cairney, S.P. Ringer, C.R. Killmore, and E.V. Pereloma: Mater. Sci. Eng. A, 2014, vol. 607A, pp. 226–35.
W.C. Leslie and R. Sober: ASM Trans. Q., 1967, vol. 60 (1), pp. 99–111.
D.H. Sulistiyo, L. Cho, E.J. Seo, and B.C. De Cooman: Mater. Sci. Technol., 2016, pp. 1–14.
A. Saastamoinen, A. Kaijalainen, D. Porter, and P. Suikkanen: Mater. Charact., 2017, vol. 134, pp. 172–81.
A.J. Kaijalainen, P.P. Suikkanen, L.P. Karjalainen, and D.A. Porter: Mater. Sci. Eng. A, 2016, vol. 654, pp. 151–60.
J. Steninger and A. Melander: Scand. J. Metall., 1982, vol. 11 (2), pp. 55–71.
Acknowledgments
We thank Johan Lönnqvist and Christer Eggertson (Swerea KIMAB) for carrying out laboratory melts, Jussi Paavola (University of Oulu) for performing laboratory rolling of experimental steels, and Sanna Järn (SSAB Europe Oy) for implementing GDOES analysis. This study was financially supported by the Finnish Funding Agency for Technology and Innovation (Tekes) in the Breakthrough Steels and Applications Program of the Finnish Metals and Engineering Competence Cluster (FIMECC Ltd), which is gratefully acknowledged. The author thanks the Tampere University of Technology (TUT’s Graduate School), Emil Aaltonen Foundation, and Finnish Foundation for Technology Promotion for financial support.
Author information
Authors and Affiliations
Corresponding author
Additional information
Manuscript submitted July 10, 2018.
Rights and permissions
About this article
Cite this article
Järvinen, H., Honkanen, M., Oja, O. et al. Microstructure-Property Relationships of Novel Ultra-High-Strength Press Hardening Steels. Metall Mater Trans A 50, 816–836 (2019). https://doi.org/10.1007/s11661-018-4967-7
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11661-018-4967-7