Synthesis and Thermal Characterization of Solar Salt-Based Phase Change Composites with Graphene Nanoplatelets

Abstract

Thermal energy storage (TES) systems use solar energy despite its irregular availability and day-night temperature difference. Current work reports the thermal characterizations of solar salt-based phase change composites in the presence of graphene nanoplatelets (GNP). Solar salt (60:40 of NaNO₃:KNO₃) possessing phase transition temperature and melting enthalpy of 221.01°C and 134.58 kJ/kg is proposed as a phase change material (PCM) for high-temperature solar-based energy storage applications. Thermal conductivity must be improved to make them suitable for widespread applications and to close the gap between the system needs where they are employed. GNP is added at weight concentrations of 0.1%, 0.3%, and 0.5% with solar salt using the ball milling method to boost its thermal conductivity. Morphological studies indicated the formation of a uniform surface of GNP on solar salt. FTIR spectrum peaks identified the physical interaction between salt and GNP. Thermal characterization of the composites, such as thermal conductivity, DSC and TGA was carried out for the samples earlier and later 300 thermal cycles. 0.5% of GNP has improved the thermal conductivity of salt by 129.67% and after thermal cycling, the enhancement reduced to 125.21% indicating that thermal cycling has a minor impact on thermal conductivity. Phase change temperature decreased by around 2.32% in the presence of 0.5% GNP and the latent heat reduced by 4.34% after thermal cycling. TGA thermograms depicted the composites initiated the weight loss at around 550°C after which it was rapid. After thermal cycling, the weight loss initiated at ∼40°C lower compared to pure salt, which was found to be a minor change. Thermal characterization of solar salt and GNP-based solar salt composites revealed that the composites can be used for enhanced heat transfer in high-temperature solar-based heat transfer and energy storage applications.