Skip to main content
Log in

Effect of High Content Limestone Powder on Microstructure and Mechanical Properties of Cement-based Materials

  • Cementitious Materials
  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

Compared with the control sample without limestone powder (LP), the mechanical properties of the sample with 30% LP can be significantly improved by using a small amount of water reducer to reduce the water-cement ratio, without significantly affecting the fluidity of the fresh mixture and increasing the economic cost. In addition, compared with the sole addition of limestone powder, dual addition of metakaolin and limestone powder can effectively improve the strengths. The reason of this phenomenon was investigated by means of XRD, TG-DTG, SEM, LF-NMR and isothermal calorimetry, etc. The reactive aluminum-rich phases in metakaolin react with limestone powder in the hydration process, and the formed calcium carboaluminate reduces the porosity and makes the hardened paste denser. The addition of ground granulated blast furnace slag can also improve the strength of the specimen added with limestone powder, whereas, the effect is inferior to that of metakaolin, for the ground granulated blast furnace slag contains less reactive aluminate phases, and accordingly, the amount of calcium carboaluminate generated is lower than that of metakaolin.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Ali M B, Saidur R, Hossain M S. A Review on Emission Analysis in Cement Industries[J]. Renewable and Sustainable Energy Reviews, 2011, 15(5): 2252–2261

    Article  CAS  Google Scholar 

  2. Damtoft J S, Lukasik J, Herfort D, et al. Sustainable Development and Climate Change Initiatives[J]. Cement and Concrete Research, 2008, 38(2): 115–127

    Article  CAS  Google Scholar 

  3. Lothenbach B, Scrivener K, Hooton R D. Supplementary Cementitious Materials[J]. Cement and Concrete Research, 2011, 41(12): 1244–1256

    Article  CAS  Google Scholar 

  4. Khan K, Amin M N. Influence of Fineness of Volcanic Ash and Its Blends with Quarry Dust and Slag on Compressive Strength of Mortar under Different Curing Temperatures[J]. Construction and Building Materials, 2017, 154: 514–528

    Article  Google Scholar 

  5. Xu S, Wang J, Jiang Q, et al. Study of Natural Hydraulic Lime-based Mortars Prepared with Masonry Waste Powder as Aggregate and Diatomite/Fly Ash as Mineral Admixtures[J]. Journal of Cleaner Production, 2016, 119: 118–127

    Article  CAS  Google Scholar 

  6. Li X, Liu Z, Lv Y, et al. Utilization of Municipal Solid Waste Incineration Bottom Ash in Autoclaved Aerated Concrete[J]. Construction and Building Materials, 2018, 178: 175–182

    Article  CAS  Google Scholar 

  7. Bizzozero J, Scrivener K L. Limestone Reaction in Calcium Aluminate Cement-calcium Sulfate Systems[J]. Cement and Concrete Research, 2015, 76: 159–169

    Article  CAS  Google Scholar 

  8. Matschei T, Lothenbach B, Glasser F P. The Role of Calcium Carbonate in Cement Hydration[J]. Cement and Concrete Research, 2007, 37(4): 551–558

    Article  CAS  Google Scholar 

  9. Deschner F, Winnefeld F, Lothenbach B, et al. Hydration of Portland Cement with High Replacement by Siliceous Fly Ash[J]. Cement and Concrete Research, 2012, 42(10): 1389–1400

    Article  CAS  Google Scholar 

  10. Briki Y, Zajac M, Haha M B, et al. Impact of Limestone Fineness on Cement Hydration at Early Age[J]. Cement and Concrete Research, 2021, 147: 106 515

    Article  CAS  Google Scholar 

  11. Drissi S, Shi C, Li N, et al. Relationship Between the Composition and Hydration-microstructure-mechanical Properties of Cement-metakaolin-limestone Ternary System[J]. Construction and Building Materials, 2021, 302: 124 175

    Article  CAS  Google Scholar 

  12. Wang D, Shi C, Farzadnia N, et al. A Review on Use of Limestone Powder in Cement-based Materials: Mechanism, Hydration and Microstructures[J]. Construction and Building Materials, 2018, 181: 659–672

    Article  CAS  Google Scholar 

  13. Ghrici M, Kenai S, Said-Mansour M. Mechanical Properties and Durability of Mortar and Concrete Containing Natural Pozzolana and Limestone Blended Cements[J]. Cement and Concrete Composites, 2007, 29(7): 542–549

    Article  CAS  Google Scholar 

  14. Barrett T J, Sun H, Nantung T, et al. Performance of Portland Limestone Cements[J]. Transportation Research Record: Journal of the Transportation Research Board, 2014, 2441(1): 112–120

    Article  Google Scholar 

  15. Liu S, Yan P. Effect of Limestone Powder on Microstructure of Concrete[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2010, 25(2): 328–331

    Article  CAS  Google Scholar 

  16. Lothenbach B, Matschei T, Möschner G, et al. Thermodynamic Modelling of the Effect of Temperature on the Hydration and Porosity of Portland Cement[J]. Cement and Concrete Research, 2008, 38(1): 1–18

    Article  CAS  Google Scholar 

  17. Mo Z, Wang R, Gao X. Hydration and Mechanical Properties of UHPC Matrix Containing Limestone and Different Levels of Metakaolin[J]. Construction and Building Materials, 2020, 256: 119 454

    Article  CAS  Google Scholar 

  18. Wang D, Shi C, Farzadnia N, et al. A Review on Effects of Limestone Powder on the Properties of Concrete[J]. Construction and Building Materials, 2018, 192: 153–166

    Article  CAS  Google Scholar 

  19. Lothenbach B, Le Saout G, Gallucci E, et al. Influence of Limestone on the Hydration of Portland Cements[J]. Cement and Concrete Research, 2008, 38(6): 848–860

    Article  CAS  Google Scholar 

  20. Martin L H J, Winnefeld F, Müller C J, et al. Contribution of Limestone to the Hydration of Calcium Sulfoaluminate Cement[J]. Cement and Concrete Composites, 2015, 62: 204–211

    Article  CAS  Google Scholar 

  21. Antoni M, Rossen J, Martirena F, et al. Cement Substitution by a Combination of Metakaolin and Limestone[J]. Cement and Concrete Research, 2012, 42(12): 1579–1589

    Article  CAS  Google Scholar 

  22. De Weerdt K, Haha M B, Le Saout G, et al. Hydration Mechanisms of Ternary Portland Cements Containing Limestone Powder and Fly Ash[J]. Cement and Concrete Research, 2011, 41(3): 279–291

    Article  CAS  Google Scholar 

  23. Puerta-Falla G, Balonis M, Le Saout G, et al. The Influence of Metakaolin on Limestone Reactivity in Cementitious Materials[C]. Proceedings of the 1st International Conference on Calcined Clays for Sustainable Concrete, Switzerland, 2015

  24. Shi Z, Geiker M R, De Weerdt K, et al. Role of Calcium on Chloride Binding in Hydrated Portland Cement-metakaolin-limestone Blends[J]. Cement and Concrete Research, 2017, 95: 205–216

    Article  CAS  Google Scholar 

  25. Zunino F, Scrivener K. Microstructural Developments of Limestone Calcined Clay Cement (LC3) Pastes after Long-term (3 years) Hydration[J]. Cement and Concrete Research, 2022, 153: 106 693

    Article  CAS  Google Scholar 

  26. Moon G D, Oh S, Jung S H, et al. Effects of the Fineness of Limestone Powder and Cement on the Hydration and Strength Development of PLC Concrete[J]. Construction and Building Materials, 2017, 135: 129–136

    Article  CAS  Google Scholar 

  27. Liu L, He Z, Cai X, et al. Application of Low-field NMR to the Pore Structure of Concrete[J]. Applied Magnetic Resonance, 2020, 52(1): 15–31

    Article  Google Scholar 

  28. Berodier E, Scrivener K, Scherer G. Understanding the Filler Effect on the Nucleation and Growth of C-S-H[J]. Journal of the American Ceramic Society, 2014, 97(12): 3764–3773

    Article  CAS  Google Scholar 

  29. Liu K, Wang S, Quan X, et al. Effect of Iron Ore Tailings Industrial By-product as Eco-friendly Aggregate on Mechanical Properties, Pore Structure, and Sulfate Attack and Dry-wet Cycles Resistance of Concrete[J]. Case Studies in Construction Materials, 2022, 17: e01 472

    Article  Google Scholar 

  30. Wang Y, Yang W, Ge Y, et al. Analysis of Freeze-thaw Damage and Pore Structure Deterioration of Mortar by Low-field NMR[J]. Construction and Building Materials, 2022, 319: 126 097

    Article  Google Scholar 

  31. Xue S, Meng F, Zhang P, et al. Influence of Water Re-curing on Microstructure of Heat-damaged Cement Mortar Characterized by Low-field NMR and MIP[J]. Construction and Building Materials, 2020, 262: 120 532

    Article  CAS  Google Scholar 

  32. Zhao H, Qin X, Liu J, et al. Pore Structure Characterization of Early-age Cement Pastes Blended with High-volume Fly Ash[J]. Construction and Building Materials, 2018, 189: 934–946

    Article  Google Scholar 

  33. Wang Y, Yuan Q, Deng D, et al. Measuring the Pore Structure of Cement Asphalt Mortar by Nuclear Magnetic Resonance[J]. Construction and Building Materials, 2017, 137: 450–458

    Article  Google Scholar 

  34. Deng G, He Y, Lu L, et al. Pore Structure Evolution and Sulfate Attack of High-volume Slag Blended Mortars Under Standard Curing and Steam Curing[J]. Construction and Building Materials, 2023, 363: 129 878

    Article  CAS  Google Scholar 

  35. Yang J, Su Y, He X, et al. Pore Structure Evaluation of Cementing Composites Blended with Coal By-products: Calcined Coal Gangue and Coal Fly Ash[J]. Fuel Processing Technology, 2018, 181: 75–90

    Article  CAS  Google Scholar 

  36. Yu Z, Ye G. The Pore Structure of Cement Paste Blended with Fly Ash[J]. Construction and Building Materials, 2013, 45: 30–35

    Article  CAS  Google Scholar 

  37. Ramezanianpour A M, Hooton R D. A Study on Hydration, Compressive Strength, and Porosity of Portland-limestone Cement Mixes Containing SCMs[J]. Cement and Concrete Composites, 2014, 51: 1–13

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Yongjia He  (何永佳) or Linnü Lü  (吕林女).

Additional information

Conflict of interest

All authors declare that there are no competing interests.

Funded by the National Natural Science Foundation of China (Nos.51972249, 52172026, 51772226)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chen, M., He, Y., Lü, L. et al. Effect of High Content Limestone Powder on Microstructure and Mechanical Properties of Cement-based Materials. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 38, 557–566 (2023). https://doi.org/10.1007/s11595-023-2731-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-023-2731-3

Key words

Navigation