Abstract
Carbide slag was used as an activator to improve the activity of anhydrous phosphogypsum. Carbide slag could greatly improve the mechanical strength of anhydrous phosphogypsum than K2SO4. The compressive strength of 11 wt% carbide slag and 1 wt% K2SO4 activated anhydrous phosphogypsum increased greatly to 8.6 MPa at 3 d, and 11.9 MPa at 7 d, and 16.0 MPa at 28 d, respectively. The rate of hydration heat was accelerated and the total hydration heat was increased, and more calcium sulfate dihydrate was formed and cross-linked with other parts which improved the compressive strength of anhydrous phosphogypsum under the effects of different activators. It was indicated that carbide slag was a highly effective and cost-efficient activator. The result provides a highly effective and low-cost method which results in a novel and high value-added method for the utilization of phosphogypsum in the future.
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References
Pérez-López R, Álvarez-Valero A M, Nieto J M. Changes in Mobility of Toxic Elements during the Production of Phosphoric Acid in the Fertilizer Industry of Huelva (SW Spain) and Environmental Impact of Phosphogypsum Wastes[J]. J. Hazard Mater., 2007, 148: 745–750
Pérez-López R, Carrero S, Cruz-Hernández P, et al. Sulfate Reduction Processes in Salt Marshes Affected by Phosphogypsum: Geochemical Influences on Contaminant Mobility[J]. J. Hazard Mater., 2018, 350: 154–161
Carlos R C, Francisco M, Rafael P L, et al. Valorization of Wastes from the Fertilizer Industry: Current Status and Future Trends[J]. J. Clean. Prod., 2018, 174: 678–690
Mohammed F, Biswas W K, Yao H, et al. Sustainability Assessment of Symbiotic Processes for the Reuse of Phosphogypsum[J]. J. Clean. Prod., 2018, 188: 497–507
Yang J K, Liu W C, Zhang L L, et al. Preparation of Load-bearing Building Materials from Autoclaved Phosphogypsum[J]. Constr. Build. Mater., 2009, 23(2): 687–693
Zhou J, Sheng Z M, Li T T, et al. Preparation of Hardened Tiles from Waste Phosphogypsum by A New Dintermittent Pressing Hydration[J]. Ceram. Int., 2016, 42(6): 7237–7245
Rashad A M. Phosphogypsum as A Construction Material[J]. J. Clean. Prod., 2017, 166: 732–743
Chen Q S, Zhang Q L, Fourie A, et al. Utilization of Phosphogypsum and Phosphate Tailings for Cemented Paste Backfill[J]. J. Environ. Manage., 2017, 201: 19–27
Li X, Du J, Gao L, et al. Immobilization of Phosphogypsum for Cemented Paste Backfill and Its Environmental Effect[J]. J. Clean. Prod., 2017, 156: 137–146
Wang Q, Jia R Q. A Novel Gypsum-Based Self-Leveling Mortar Produced by Phosphorus Building Gypsum[J]. Constr. Build. Mater., 2019, 226: 11–20
Aminul H M, Chen B, Liu Y T, et al. Improvement of Physico-mechanical and Microstructural Properties of Magnesium Phosphate Cement Composites Comprising with Phosphogypsum[J]. J. Clean. Prod., 2020, 261: 121–268
Contreras M, Pérez-López R, Gázquez M J, et al. Fractionation and Fluxes of Metals and Radionuclides During the Recycling Process of Phosphogypsum Wastes Applied to Mineral CO2 Sequestration[J]. Waste Manage., 2015, 45: 412–419
Lu W D, Ma B G, Su Y, et al. Preparation of Alpha-hemihydrate Gypsum from Phosphogypsum in Recycling CaCl2 Solution[J]. Constr. Build. Mater., 2019, 214: 399–412
Zhang Y H, Wang F, Huang H W, et al. Gypsum Blocks Produced from TiO2 Production By-Products[J]. Environ. Technol., 2016, 37(9): 1094–1100
Ma B G, Jin Z H, Su Y, et al. Utilization of Hemihydrate Phosphogypsum for the Preparation of Porous Sound Absorbing Material[J]. Constr. Build. Mater., 2020, 234: 117–346
Chen Q S, Zhang Q L, Qi C C, et al. Recycling Phosphogypsum and Construction Demolition Waste for Cemented Paste Backfill and Its Environmental Impact[J]. J. Clean. Prod., 2018, 186: 418–429
Geraldo R H, Costa A R D, Kanai J, et al. Calcination Parameters on Phosphogypsum Waste Recycling[J]. Constr. Build. Mater., 2020, 256: 119–406
Yang M, Qian J S, Pan L, et al. Hydration of Activated Anhydrate Phosphogypsum[J]. J. Wuhan University of Technology-Mater. Sci. Ed., 2013, 28(03): 535–537
Singh M, Garg M. Activation of Gypsum Anhydrite-Slag Mixtures[J]. Cem. Concr. Res., 1995, 25(2): 332–338
Yang M, Qian J S. Activation of Anhydrate Phosphogypsum by K2SO4 and Hemihydrate Gypsum[J]. J. Wuhan University of Technology-Mater. Sci. Ed., 2011, 26(6): 1103–1107
Wang Y L, Dong S J, Liu L L, et al. Using Calcium Carbide Slag as One of Calcium-Containing Raw Materials to Produce Cement Clinker[J]. Materials Sci. Forum., 2013, 743–744: 171–174
Singh N B. The Activation Effect of K2SO4 on the Hydration of Gypsum Anhydrite, CaSO4(II)[J]. J. Am. Ceram. Soc., 2005, 88(1): 196–201
Tan H B, Zhang X, He X Y, et al. Utilization of Lithium Slag by Wet-grinding Process to Improve the Early Strength of Sulphoaluminate Cement Paste[J]. J. Clean. Prod., 2018, 205: 536–551
He X, Ma M, Su Y, et al. The Effect of Ultrahigh Volume Ultrafine Blast Furnace Slag on the Properties of Cement Pastes[J]. Constr. Build. Mater., 2018, 189: 438–447
Allahverdi A, Mahinroosta M. Mechanical Activation of Chemically Activated High Phosphorous Slag Content Cement[J]. Powder Technol., 2013, 245: 182–188
Fernández-Jiménez A, Puertas F. Setting of Alkali-activated Slag Cement. Influence of Activator Nature[J]. Adv. Cem. Res., 2001, 13(3): 115–121
Yang L C, Guan B H, Wu Z B, et al. Solubility and Phase Transitions of Calcium Sulfate in KCl Solutions Between 85 and 100 °C[J]. Ind. Eng. Chem. Res., 2009, 48(16): 7773–7779
Jin Z H, Ma B G, Su Y, et al. Effect of Calcium Sulphoaluminate Cement on Mechanical Strength and Waterproof Properties of Beta-Hemihydrate Phosphogypsum[J]. Constr. Build. Mater., 2020, 242: 118–198
Li W T, Yi Y L. Use of Carbide Slag from Acetylene Industry for Activation of Ground Granulated Blast-furnace Slag[J]. Constr. Build. Mater., 2020, 238: 117–713
Gameiro A, Silva S A, Faria P, et al. Physical and Chemical Assessment of Lime-metakaolin Mortars: Influence of Binder: Aggregate Ratio[J]. Cem. Concr. Compos., 2014, 45: 264–271
Cody A M, Cody R D. Evidence for Micro-biological Induction of 101 Montmartre Twinning of Gypsum (CaSO4•2H2O)[J]. J. Cryst. Growth., 1989, 98(4): 721–30
Li H, Zhang H, Li L, et al. Utilization of Low-Quality Desulfurized Ash from Semi-dry Flue Gas Desulfurization by Mixing with Hemihydrate Gypsum[J]. Fuel, 2019, 255: 115–783
Hajjouji A E, Murat M. Strength Development and Hydrate Formation Rate. Investigation on Anhydrite Binders[J]. Cem. Concr. Res.,1987, 17(5): 814–820
Yang L, Zhang Y S, Yan Y. Utilization of Original Phosphogypsum as Raw Material for the Preparation of Self-Leveling Mortar[J]. J. Clean. Prod., 2016, 127: 204–213
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Funded by Innovation Group Fund Project of Hubei Province (No.2020CFA039) and the Key Research and Development Program of Hubei Province(No.2020BCA077)
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Chen, S., Xiong, G., Su, Y. et al. Laboratory Evaluation for Utilization of Phosphogypsum through Carbide Slag Highly-Effective Activating Anhydrous Phosphogypsum. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 36, 392–399 (2021). https://doi.org/10.1007/s11595-021-2422-x
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DOI: https://doi.org/10.1007/s11595-021-2422-x