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Theoretical Study of Electron Paramagnetic Resonance Spectra and Local Lattice Distortion for Mn2+ in Zn(ClO4)2·6(H2O)Mg(ClO4)2·6(H2O)

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Abstract

The electron paramagnetic resonance (EPR) spectra of trigonal Mn2+ centers in Zn(ClO4)2·6(H2O) and Mg(ClO4)2·6(H2O) crystals were studied on the basis of the complete energy matrices for a d5 configuration ion in a trigonal ligand field. It was demonstrated that the local lattice structure around a trigonal Mn2+ center has an compressed distortion along the crystalline c3 axis, and when Mn2+ is doped in the Zn(ClO4)2·6(H2O) and Mg(ClO4)2·6(H2O) crystals, there is a similar local distortion. From the EPR calculation, the local lattice structure parameters R=2.183 2 Å, for Zn(ClO4)2·6(H2O), R=2.130 2 Å, for Mg(ClO4)2·6(H2O) have been determined.

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References

  1. Tiway C S, Skarkar R, Kumbhakar P. Synthesis and Optical Characterization of Monodispersed Mn2+ Doped CdS Nanoparticles[J]. Phys. Lett.A, 2008, 372(36): 5825–5830

    Article  Google Scholar 

  2. Zajac M, Gosk J, Grzanka E, et al. Ammonothermal Synthesis of GaN Doped with Transition Metal Ions (Mn, Fe, Cr)[J]. J.Alloy Compd., 2008, 456(1-2): 324–338

    Article  Google Scholar 

  3. Acikgoz M, Kazan S, Mikailov FA, et al. Structural Phase Transitions in Fe3+-Doped Ferroelectric TiGaSe2 Crystal[J]. Solid State Commun., 2008,145(11-12): 539–544

    Article  Google Scholar 

  4. García-Lastra JM, Barriuso MT, Aramburu JA, et al. Anisotropic Relaxation of Mn2+ and Ni2+ Impurities in K2MgF4[J]. Chem. Phys. Lett., 2009, 473(1-3): 88–91

    Article  Google Scholar 

  5. Ram Kripal, Manju Maurya. Characterization of Mn2+ Doped Tetramethyl Ammonium Tetra Chlorozincate Single Crystal Using EPR and Optical Absorption[J]. Mater. Chem. Phys., 2008, 108(2-3): 257–262

    Article  Google Scholar 

  6. Ram Kripal, Ashutosh Kumar Shukla. ESR and Optical Study of Mn2+ Doped Ammonium Selenate Single Crystals[J]. Spectrochim. Acta. Part.A, 2007, 66(2): 453–456

    Article  Google Scholar 

  7. Ram Kripal, Har Govind, Gupta SK, et al. EPR and Optical Absorption Study of Mn2+-Doped Zinc Ammonium Phosphate Hexahydrate Single Crystals[J]. Phys. B, 2007, 392(1-2): 92–98

    Article  Google Scholar 

  8. Dayal R, Ramachandra D Rao, and Putcha Venkateswarlu. Electron Paramagentic Resonance and Phase Transitions in Mn2+ Doped Cd(-ClO4)2·6H2O[J]. J.Chem.Phys., 1979, 70(9): 2487–2490

    Article  Google Scholar 

  9. LECH J, SLEZAK A. EPR of Mn2+ in [Co(H2O)6](ClO4)2 Single Crystals: Estimation of Co2+ Spin-Lattice Relaxation Time[J]. J.Phys.Chem. Solid, 1991, 52(5): 685–689

    Article  Google Scholar 

  10. Prokhorov AA, Neilo GN, Prokhorov AD. EPR Studies of Phase Transitions in Perchlorates [M2+(ClO4)2·6H2O] At High Pressures[J]. Phys. Solid. State, 2006 48(2): 340–347

    Article  Google Scholar 

  11. Akhilesh Kumar Jain and Upreti GC. EPR Observation of A High Temperature Phase Transition in Zn(ClO4)2·6H2O:Mn2+[J]. Solid State Commun., 1978, 28(7): 571–574

    Article  Google Scholar 

  12. DAYAL R, Ramachandar Rao D. EPR Study of Phase Transitions In Single Crystals of Cd (ClO4)2·6H2O And Cd (ClO4)2·6 D2O[J]. Phys. Status Solidi A, 1980, 58: 155–158

    Article  Google Scholar 

  13. Jain K and Upreti G C, EPR Study of A New Low-temperature Phase Transition in Zn(ClO4)2·6H2O[J]. J. Phys. Chem. Solids, 1982, 43(6): 563–569

    Article  Google Scholar 

  14. White A and Falk M. Phase Transitions in M(ClO4)2·6H2O (M=Mg, Zn) Investigations by Adiabatic Calorimetry and Infrared Spectroscopy[J]. J. Chem. Phys., 1986, 84(6): 3484–3490

    Article  Google Scholar 

  15. White A and Falk M. A Study of Phase Transitions In Cd(ClO4)2·6H2O by Adiabatic Calorimetry and Infrared Spectroscopy[J]. J. Chem. Phys., 1985, 83(5): 2467–2474

    Article  Google Scholar 

  16. Patel V. Temperature Evolution of The Infrared Spectrum Of Ni(-ClO4)2·6H2O[J]. Solid State Commun., 1985, 53(4): 431–435

    Article  Google Scholar 

  17. Bleaney B, Trenam RS. The Dispersion of Matter in Turbulent Flow Through A Pipe[J]. Proc. R. Soc. London, Ser. A, 1954, 223: 1–14

    Article  Google Scholar 

  18. Kuang XY. Analysis of the Electron Paramagnetic Resonance Zero-Field Splitting for Fe3+ in Sapphire[J]. Phys. Rev. B, 1987, 36(1): 712–714

    Article  Google Scholar 

  19. Newman DJ, Urban W. Interpretation of S-State Ion E.P.R. Spectra[J]. Adv. Phys., 1975, 24: 793–796

    Article  Google Scholar 

  20. Van Vleck J H. Theory of the Variations in Paramagnetic Anisotropy Among Different Salts of the Iron Group[J]. Phys. Rev., 1932, 1: 208–210

    Article  Google Scholar 

  21. Zhao MG, Bai GR, Jin HC. D-orbital Theory For Mn2+-Complex Ions in Crystals[J]. J. Phys.C, 1982, 15: 5959–5964

    Article  Google Scholar 

  22. Lohr Jr LL. Optical Spectra of Divalent Manganese Salts. I. Energy Levels for Cubic and Lower-Symmetry Complexes[J]. J. Chem. Phys., 1966, 45(10): 3611–3622

    Google Scholar 

  23. Zheng W C. Local Trigonal Distortions of Some Paramagnetic Impurity Centers in ZnSiF6·6H2O Crystal[J]. Radiat. Eff. Defect Solids, 1996, 140: 329–334

    Google Scholar 

  24. Curie D, Barthon C, Canny B. Covalent Bonding of Mn2+ Ions in Octahedral and Tetrahedral Coordination[J]. J. Chem. Phys., 1974, 61(8): 3048–3063

    Article  Google Scholar 

  25. Kuang XY, Zhang W. Analysis of Temperature-Dependent Electron-Paramagnetic-Rresonance Spectra for S-State Ions in MgO[J]. Phys. Rev. B, 1992, 45: 8104–8107

    Article  Google Scholar 

  26. Jain VK. Superposition Model Analysis for The Zero-Field Splitting of Mn2+ in Some Crystals[J]. Modern Physics Letters B, 2006, 20: 1917–1922

    Article  Google Scholar 

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Authors and Affiliations

  1. School of Science, Southwest Petroleum University, Chengdu, 610065, China

    Jufen Li  (李菊芬), Jianli Huo & Xinhui Wu

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  1. Jufen Li  (李菊芬)
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  2. Jianli Huo
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  3. Xinhui Wu
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Correspondence to Jufen Li  (李菊芬).

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Funded in Part by the National Natural Science Foundation of China (No.61601384)

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Li, J., Huo, J. & Wu, X. Theoretical Study of Electron Paramagnetic Resonance Spectra and Local Lattice Distortion for Mn2+ in Zn(ClO4)2·6(H2O)Mg(ClO4)2·6(H2O). J. Wuhan Univ. Technol.-Mat. Sci. Edit. 33, 571–574 (2018). https://doi.org/10.1007/s11595-018-1862-4

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  • DOI: https://doi.org/10.1007/s11595-018-1862-4

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