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Preparation and surface properties of silicon-containing waterborne polyurethane functionalized with fluorine-containing acrylate and micro-nano silica

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Abstract

In order to prepare hydrophobic waterborne polyurethane coatings with better performances, the silicon-containing waterborne polyurethane (SiWPU) with functional chain extender hydroxyethyl acrylate (HEA) was prepared first, and then a series of silicon&fluorine-containing polyurethane/acrylate (FSiPUA) emulsions were obtained with flourine containing acrylic monomer by seed emulsion polymerization, introducing micro-nano SiO2 into FSiPUA emulsion to make the final hybrid emulsion. The properties of SiWPU, FSiPUA and SiO2/FSiPUA were investigated by fourier transform infrared spectra (FTIR), transmission electron microscope (TEM), Scanning Electron Microscope (SEM) and some other analytical methods. The results revealed that FSiPUA emulsion particles possessed composite core-shell structure and FSiPUA films with suitable ratio performed better than SiWPU films in hardness, water resistance and solvent resistance. The SiO2/FSiPUA films with micro-nano dual roughness structure showed a water contact angle of 136° with good resistance to acid and alkali.

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References

  1. Karl Ludwing Noble. Waterborne Polyurethane[J]. Progress in Organnic Coatings, 1997, (32): 131–136

    Article  Google Scholar 

  2. Chattopadhyay D K, Raju K V S N. Structural Engineering of Polyurethane Coatings for High Performance Applications[J]. Prog.Polym.Sci, 2007, (32): 352–418

    Article  Google Scholar 

  3. Rahman Mohammad Mizanur, Chun Ho-Hwan, Park Hyun. Preparation and Properties of Waterborne Polyurethane-Silicane: a Promising Antiflouling Coating[J]. Macromolecular Research, 2011, 19(1): 8–13

    Article  Google Scholar 

  4. Qiang Xiaohu, Feng Libang, Wang Anping, et al. Effect of Silica Nanoparticles on Properties of Waterborne Polyurethanes[J]. Chinese Journal of Polymer Science, 2012, 30(6): 845–852

    Article  Google Scholar 

  5. Jeon Ho Tak, Jang Moon Kyoung, Kim Byung Kyu, et al. Synthesis and Characterization of Waterborne Polyurethane-Silica Hybrids Using Sol-Gel Process[J]. Colloids and Surfaces A:Physicochem.Eng.Aspects, 2007, (302): 559–567

    Article  Google Scholar 

  6. Krol Piotr, Krol Bozena, Pielichowska Kinga, et al. Comparison of Phase Structures and Surface Free Energy Values for the Coatings Synthesised from Linear Polyurethanes and From Waterborne Polyurethane Cationomers[J]. Colloid Polym. Sci., 2011(289): 1757–1767

    Article  Google Scholar 

  7. Krol Piotr, Krol Bozena, Stagraczynski Ryszard, et al. Waterborne Catinomer Polyurethane Coatings with Improved Hydrophobic Properties[J]. Appl. Polym. Sci., 2013: 2508–2519

    Google Scholar 

  8. Gite V V, Mahulikar P P, Hundiwale D G. Preparation and Properties of Polyurethane Coatings Based on Acrylic Polyols and Trimer of Isophorone Diisocyanate[J]. Progress in Organic Coatings, 2010(68): 307–312

    Article  Google Scholar 

  9. Sardon H, Irusta L, Gonzalez A, et al. Waterborne Hybrid Polyurethane Coatings Functionalized with (3-Aminopropyl) Triethoxysilanne: Adhesion Properties[J]. Progress in Organic Coatings, 2013, (76): 1230–1235

    Article  Google Scholar 

  10. Contraires Elise Degrandi, Lopez Aitziber, Reyes Yuri, et al. High-Shear-Strength Waterborne Polyurethane/Acrylic Soft Adhesives[J]. Macromolecular Materials and Engineering, 2013(298): 612–623

    Article  Google Scholar 

  11. Fu Heqing, Huang Hong, Wang Qi, et al. Properties of Aqueous Polyurethane Dispersion Modified by Epoxide Resin and Their Use as Adhesives[J]. Dispersion Science and Technology, 2009(30): 634–638

    Article  Google Scholar 

  12. Lim Chul Hwan, Choi Hee Sung, Noh Si Tae. Surface Modification with Waterborne Fluorinated Anionic Polyurethane Dispersions[J]. Applied Polymer Science, 2002, 86: 3322–3330

    Article  Google Scholar 

  13. Lai Xiaojuan, Shen Yiding, Wang Lei. Preparation and Properties of Self-Crosslinkable Polyurethane/Silane Hybrid Emulsion[J]. Polym. Res., 2011(18): 2425–2433

    Article  Google Scholar 

  14. Chen Jing-Jing, Zhu Chuan-Fang, Deng Hong-Tao. Preparation and Characterization of the Waterborne Polyurethane Modified with Nanosilica[J]. Polym. Res., 2009(16): 375–380

    Article  Google Scholar 

  15. Zhou Shuxue, Wu Limin, Sun Jian, et al. The Change of the Properties of Acrylic-Based Polyurethane via Addition of Nano-Silica[J]. Progress in Organic Coatings, 2002(45): 33–42

    Article  Google Scholar 

  16. Yang Chien Hsin, Liu Feng Jiin, Liu Yun Peng, et al. Hybrids of Col-loidal Silica and Waterborne Polyurethane[J]. Journal of Colloid and Interface Science, 2006(302): 123–132

    Article  Google Scholar 

  17. Ana M Torro-Palau, Juan C Fernandez Garcia, A Cesar Orgiles Barcelo, et al. Characterization of Polyurethanes Containing Different Silicas[J]. International Journal of Adhesion&Adhesives, 2001(21): 1–9

    Article  Google Scholar 

  18. Li Kechen, Peng Jiangen, Zhang Meizhou, et al. Comparative Study of the Effects of Anatase and Rutile Titanium Dioxide Nanoparticles on the Structure and Properties of Waterborne Polyurethane[J]. Colloids and Surface A: Physicochem. Eng. Aspects, 2015(470): 92–99

    Article  Google Scholar 

  19. Pan Hongxia, Chen Dajun. Preparation and Characterization of Waterborne Polyurethane/Attapulgite Nanocomposites[J]. European Polymer Journal, 2007(43): 3766–3772

    Article  Google Scholar 

  20. Kim Byung Kyu, Seo Jang Won, Jeong Han Mo. Morphology and Properties of Waterborne Polyurethane/Clay Nanocomposites[J]. European Polymer Journal, 2003(39): 85–91

    Article  Google Scholar 

  21. Raghu Anjanapura V, Lee Yu Rok, Jeong Han Mo, et al. Preparation and Physical Properties of Waterborne Polyurethane/Functionalized Graphene Sheet Nanocomposites[J]. Macromol. Chem. Phys., 2008(209): 2487–2493

    Article  Google Scholar 

  22. Xiong Jiawen, Zheng Zhen, Qin Xiumin, et al. The Thermal and Mechanical Properties of a Polyurethane/Multi-walled Carbon Nanotube Composite[J]. Carbon, 2006(44): 2701–2707

    Article  Google Scholar 

  23. Kuan Hsu Chiang, Ma Chen Chi M, Chang Wei Ping, et al. Synthesis, Thermal, Mechanical and Rheological Properties of Multiwall Carbon Nanotube/Waterborne Polyurethane Nanocomposite[J]. Composites Science and Technology, 2005(65): 1703–1710

    Article  Google Scholar 

  24. Luo Xiaomin, Zhang Peng, Ren Jing, et al. Preparation and Properties of Functionalized Graphene/Waterborne Polyurethane Composites with Highly Hydrophobic[J]. Appl.Polym. Sci, 2015:1–8

    Google Scholar 

  25. Senthikumar Rengasamy, Vijay Mannari. Hydrophobic and Oil-Resistant Coatings Based on Advanced Green Polyurethane Dispersions[J]. Appl.Polym. Sci, 2013: 3874–3884

    Google Scholar 

  26. Jeong Ho Young, Lee Min Hee, Kim Byung Kyu. Surface Modification of Waterborne Polyurethane[J]. Colloids and Surfaces A: Physicochem. Eng.Aspects, 2006, (290): 178–185

    Article  Google Scholar 

  27. Xin Hua, Shen Yiding, Li Xiaorui. Novel Cationic Polyurethane-Fluorinated Acrylic Hybrid Latexes: Synthesis, Characterization and Properties[J]. Colloids and Surfaces A: Physicochem. Eng.Aspects, 2011(384): 205–211

    Article  Google Scholar 

  28. Wang Chen, Li Xiaorui, Du Biao, et al. Preparation and Properties of a Novel Waterborne Fluorinated Polyurethane-Acrylate Hybrid Emulsion[J]. Colloid Polym. Sci., 2014(292): 579–587

    Article  Google Scholar 

  29. Wang Yingying, Qiu Fengxian, Xu Binbin, et al. Preparation,Mechanical Properties and Surface Morphologies of Waterborne Fluorinated Polyurethane-acrylate[J]. Progress in Organic Coatings, 2013(76): 876–883

    Article  Google Scholar 

  30. Shin MinSeung, Lee YoungHee, Rahman MohammadMizanur, et al. Synthesis and Properties of Waterborne Fluorinated Polyurethane-Acrylate Using a Solvent-/Emulsifier-Free Method[J]. Polymer, 2013(54): 4873–4882

    Article  Google Scholar 

  31. Rabea A Mohammad, Mohseni M, Mirabedini S M, et al. Surface Analysis and Anti-Graffti Behavior of a Weathered Polyurethane-Based Coating Embedded with Hydrophobic Nano Silica[J]. Applied Surface Science, 2012(258): 4391–4396

    Article  Google Scholar 

  32. Jiang Lei, Zhao Yong, Zhai Jin. A Lotus-Leaf-Like Superhydrophobic Surface:a Porous Microsphere/ Nanofiber Composite Film Prepared by Electrohydrodynamics[J]. Angew.Chem., 2004(116): 4438–4441

    Article  Google Scholar 

  33. Shirtcliffe Neil J, Mchale Glen, Atherton Shaun, et al. An Introduction to Superhydrophobicity[J]. Advances in Colloid and Interface Science, 2010(161): 124–138

    Article  Google Scholar 

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Authors and Affiliations

  1. School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, 430070, China

    Qi Cai  (蔡棋), Jiemin Huang, Rui Weng  (翁睿) & Shichen Liu

Authors
  1. Qi Cai  (蔡棋)
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  2. Jiemin Huang
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  3. Rui Weng  (翁睿)
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  4. Shichen Liu
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Corresponding author

Correspondence to Rui Weng  (翁睿).

Additional information

Funded by the National High Technology Research and Development Program ("863"Program) (No.2003AA305071)

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Cai, Q., Huang, J., Weng, R. et al. Preparation and surface properties of silicon-containing waterborne polyurethane functionalized with fluorine-containing acrylate and micro-nano silica. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 33, 233–241 (2018). https://doi.org/10.1007/s11595-018-1811-2

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  • DOI: https://doi.org/10.1007/s11595-018-1811-2

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