Skip to main content
SpringerLink
Log in

Preparation and characterization of high infrared emissivity Mn-doped NCO spinel composites

  • Advanced materials
  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

NiCr2O4 (NCO) spinel composites with different Mn/Ni atomic ratios (Mn/Ni = 0.05, 0.10, 0.15, and 0.20) were synthesized via solid state reaction method. Phase compositions and microstructure of samples were characterized by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The TG-DSC curves showed that the appropriate baking temperature for Mn-doped NCO spinel preparation was approximately 1 320 °C. X-ray diffraction patterns exhibited the formation of NCO spinel with Fd-3m space group. Valence state of the Mn ions was determined from 2p and 3s X-ray photoelectron spectra. Manganese ions were mostly in divalent and trivalent states, and the ratio of Mn2+/Mn3+ was 0.78-0.98. Fourier transform infrared spectroscopy (FTIR) was used to analyze the spectral emissivity of Mn doped NCO spinel. It was revealed that the infrared emissivity of Mn-doped NCO spinel in 1.8-5 μm could be significantly enhanced with increasing content of Mn2+, reaching as high as 0.9398. Mn-doped NCO spinel showed excellent radiation performance and good prospect in high emissivity applications in the temperature range of 800-1 200 °C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Lu L, Fan XA, Zhang J, et al. Evolution of Structure and Infrared Radiation Properties for Ferrite-based Amorphous Coating[J]. Applied Surface Science, 2014, 316: 82–87

    Article  Google Scholar 

  2. Tian H, Wang YM, Liu Y, et al. Dependence of Infrared Radiation on Microstructure of Polymer Derived Ceramic Coating on Steel[J]. Current Applied Physics. 2013, 13(1): 1–6

    Article  Google Scholar 

  3. Rousseau B, Chabin M, Echegut P, et al. High Emissivity of a Rough Pr2NiO4 Coating[J]. Applied Physics Letters, 2001, 79(22): 3 633–3 635

    Article  Google Scholar 

  4. Švantner M, Honnerová P, Veselý Z. The Influence of Furnace Wall Emissvity on Steel Charge Heating[J]. Infrared Physics & Technology, 2016, 74: 63–71

    Article  Google Scholar 

  5. Li Z, Yang L, Ge D, et al. Magnetron Sputtering SiC Films on Nickel Photonic Crystals with High Emissivity for High Temperature Applications[J]. Applied Surface Science, 2012, 259: 811–815

    Article  Google Scholar 

  6. Li Y, Zhou W, Xiao P, et al. The Anti-oxidation Behavior and Infrared Emissivity Property of SiC-SiO4-SiO2 Coating[J]. Journal Of Materials Science, 2014, 25: 5 433–5 440

    Google Scholar 

  7. Shabel’skaya NP, Ivanov VV, Talanov VM, et al. Synthesis and Phase Formation in the System NiO-Fe2O3-Cr2O3[J]. Glass And Ceramics, 2014, 71(3): 18–22

    Article  Google Scholar 

  8. Zhang J, Fan XA, Lu L, et al. Ferrites Based Infrared Radiation Coatings with High Emissivity and High Thermal Shock Resistance and Their Application on Energy-saving Kettle[J]. Applied Surface Science, 2015, (344): 223–229

    Article  Google Scholar 

  9. Wu X, Yu H, Dong H, et al. Enhanced Infrared Radiation Properties of CoFe2O4 by Single Ce3+-doping with Energy-efficient Preparation[J]. Ceramics International, 2014, 40(4): 5 905–5 911

    Article  Google Scholar 

  10. Słoczyński J, Ziółkowski J, Grzybowska B. Oxidative Dehydrogenation of Propane on NixMg1-xAl2O4 and NiCr2O4 Spinels[J]. Journal Of Catalysis, 1999, (187): 410–418

    Article  Google Scholar 

  11. Bakar SA, Soltani N, Yunus WMM, et al. Structural and Paramagnetic Behavior of Spinel NiCr2O4 Nanoparticles Synthesized by Thermal Treatment Method: Effect of Calcination Temperature[J]. Solid State Communications, 2014, 192: 15–19

    Article  Google Scholar 

  12. Barman J, Ravi S. Study of Exchange Bias Behavior in Ni(Cr1-xFex)2O4[J]. Solid State Communications, 2015, 201: 59–63

    Article  Google Scholar 

  13. Li T, Ma Z, Liu L, et al. Thermal Properties of Sm2Zr2O7-NiCr2O4 Composites[J]. Ceramics International, 2014, 40(7): 11 423–11 426

    Article  Google Scholar 

  14. Zhu Z, Cheng X, Ye W, et al. Synthesis of NiCr2O4 Spinel Coatings with High Emissivity by Plasma Spraying[J]. Inernational Journal of Minerals, Metallurgy and Materials, 2012, 19(3): 266–270

    Article  Google Scholar 

  15. Izumi K, Miyazaki S, Yoshida S, et al. Optical Properties of 3d Transition-metal-doped MgAl2O4 Spinels[J]. Physical Review B, 2007, 76(7): 075111

    Article  Google Scholar 

  16. Speight JG. lange's Handbook of Chemistry[M]. The McGraw-Hill company, 1934

    Google Scholar 

  17. Ptak M, Maczka M, Gągor A, et al. Temperature-dependent XRD, IR, Magnetic, SEM and TEM Studies of Jahn-Teller Distorted NiCr2O4 Powders[J]. Journal of Solid State Chemistry, 2013, 201: 270–279

    Article  Google Scholar 

  18. Ptak M, Mączka M, Pikul A, et al. Magnetic and Low Temperature Phonon Studies of CoCr2O4 Powders Doped with Fe(III) and Ni(II) Ions[J]. Journal Of Solid State Chemistry, 2014, 212: 218–226

    Article  Google Scholar 

  19. Shati AKA, Blakey SG, Beck SBM. The Effect of Surface Roughness and Emissivity on Radiator Output[J]. Energy And Buildings, 2011, 43(2-3): 400–406

    Article  Google Scholar 

  20. Grosvenor AP, Bellhouse EM, Korinek A, et al. XPS and EELS Characterization of Mn2SiO4 MnSiO3 and MnAl2O4[J]. Applied Surface Science, 2016, 379: 242–248

    Article  Google Scholar 

  21. Sai Q, Xia C, Rao H, et al. Mn, Cr-co-doped MgAl2O4 Phosphors for White LEDs[J]. Journal Of Luminescence, 2011, 131(11): 2 359–2 364

    Article  Google Scholar 

  22. He X, Li Y, Wang L, et al. High Emissivity Coatings for High Temperature Application: Progress and Prospect[J]. Thin Solid Films, 2009, 517(17): 5 120–5 129

    Article  Google Scholar 

  23. Sova RM, Linevsky MJ, Thomas ME, et al. High-temperature Infrared Properties of Sapphire, AlON, Fused Silica, Yttria, and Spine[J]. Infrared Physics & Technology. 1998, 39: 251–261

    Article  Google Scholar 

  24. Zhang Y, Wen DJ. Relationship between Infrared Radiation and Crystal Structure in Fe-Mn-Co-Cu-O Spinels[J]. Acta Metallurgica Sinica (English Letters), 2008, 21(1): 15–20

    Article  Google Scholar 

  25. Zhang SY, Cao QX, Yao YH. Synthesis and Infrared Emissivities of Mn-doped ZnO:Co Powders[J]. Infrared Physics & Technology, 2013, 61: 1–4

    Article  Google Scholar 

  26. Tsai M-T, Chang Y-S, Huang I-B, et al. Luminescent and Structural Properties of Manganese-doped Zinc Aluminate Spinel Nanocrystals[J]. Ceramics International, 2013, 39(4): 3 691–3 697

    Article  Google Scholar 

  27. Lenglet M, Lefez B. Infrared Optical Properties of Cobalt(II) Spinels[J]. Solid State Communications, 1996, 98(8): 689–694

    Article  Google Scholar 

  28. Huang J, Fan C, Song G, et al. Enhanced Infrared Emissivity of CeO2 Coating by La Doping[J]. Applied Surface Science, 2013, (280): 605–609

    Article  Google Scholar 

  29. Manara J, Arduini-Schuster M, Keller M. Infrared-optical Characteristics of Ceramics at elevated Temperatures[J]. Infrared Physics & Technology, 2011, 54(5): 395–402

    Article  Google Scholar 

  30. Wang QP, Guo XX, Zhang JS, et al. Study on Transitional Metal Oxides Energy-Saving Materials with High-Emissivity[J]. Advanced Materials Research, 2011, 335–336: 732–735

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China

    Jun Zou  (邹隽), Shurong Dong & Xudong Cheng  (程旭东)

  2. College of Mechanical and Power Engineering, China Three Gorges University, Yichang, 443002, China

    Jun Zou  (邹隽)

  3. School of Mechanical Engineering, North University of China, Taiyuan, 030051, China

    Junhua Gao & Hongfu Wang

Authors
  1. Jun Zou  (邹隽)
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shurong Dong
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Junhua Gao
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Hongfu Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Xudong Cheng  (程旭东)
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xudong Cheng  (程旭东).

Additional information

Funded by the Scientific and Technological Research Projects for Education Department of Hubei Province(Q20161407)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zou, J., Dong, S., Gao, J. et al. Preparation and characterization of high infrared emissivity Mn-doped NCO spinel composites. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 32, 1265–1270 (2017). https://doi.org/10.1007/s11595-017-1740-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-017-1740-5

Key words

Search

Navigation