Skip to main content
Log in

Road performances of mesoporous nano-silica modified asphalt binders

  • Cementitious materials
  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

The objective of this paper was to find new modifier to improve the aging resistance and low temperature cracking resistance of asphalt. To investigate the aging resistance of modified asphalt binders, mesoporous nano-silica (doping Ti4+) was used as a asphalt modifier. Some physical properties including penetration, ductility, and softening point of asphalt were analyzed with RTFO (Rotating thin film oven) aging and ultraviolet aging. Moreover, the performances of high and low temperature of modified asphalt binders with pressure aging were tested by dynamic shear rheometer (DSR) test and bending beam rheometer (BBR) test. These results showed that the penetration decreased, low temperature ductility, and softening point increased when adding mesoporous nano-silica to base asphalt. After ultraviolet radiation aging, the penetration loss and ductility loss of modified asphalt decreased than that of original asphalt, the increase of softening point was also significantly reduced than that of base asphalt. Furthermore, The test results of DSR and BBR showed that the G*sinδ and creep modulus‘s’ of pressure aged asphalt decreased, but the creep rate ‘m’ increased. It can be concluded that the aging resistance and cracking resistance of modified asphalt are improved by adding mesoporous nano-silica, especially the doping of Ti4+ could improve the aging resistance obviously.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Fang C, Yu R, Liu S, et al. Nano-materials Applied in Asphalt Modification[J]. Mater. Sci. Technol., 2013, 29(7): 589–594

    Article  Google Scholar 

  2. Sarsam SI. Effect of Nano-materials on Asphalt Cement Properties[J]. Sci.Res. Knowledge 1, 2013, 10: 422–426

    Google Scholar 

  3. Sun SS, Wang YM. Study on Anti-photooxidstion Aging Property of TiO2 Modified Asphalt[J]. Journal of Shandong Jiaotong University, 2011, 19(2): 46–49 (in Chinese)

    Google Scholar 

  4. Ye C, Chen HX. Study on Road Performance of Nano-SiO2 and Nano-TiO2 Modified Asphalt[J]. New Build. Mater., 2009, 6: 82–87

    Google Scholar 

  5. Yang Q, Ye Q, Liu L. Dispersion and Re-aging properties of Asphalt Modified with TiO2[J]. Journal of Tongji University (Natural Science), 2011, 39(2): 263–265, 281 (in Chinese)

    Google Scholar 

  6. Zhang JS, Gao YB, Li MT. The Influence of Nano-Fe3O4 Particles on the Conventional Bitumen Test[J]. Journal of Shandong Jiaotong University, 2004, 12(4):10–14 (in Chinese)

    Google Scholar 

  7. Zhang XY, Tan YQ, Wang ZR. Study on Performance of Silica Modified Asphalt and Its Mixture[J]. Journal of Highway and Transportation Research and Development, 2005, 22(7): 23–25, 40 (in Chinese)

    Google Scholar 

  8. Liu H, Zhang H, Hao P. The Effect of Surface Modifiers on Ultraviolet Aging Properties of Nano-zinc Oxide Modified Bitumen[J]. Petroleum Science and Technology, 2015, 33: 72–78

    Article  Google Scholar 

  9. Ahmed Rehab, Nehal Salahuddin. Nanocomposite Materials Based on Polyurethane Intercalated into Montmorillonite Clay[J]. Materials Science and Engineering A, 2005, 399: 368–376

    Article  Google Scholar 

  10. Sun L, Xin XT, Yu P. Pavement Performance of Nano-SiO2 Modified Asphalt Mixture[J]. Journal of Highway and Transportation Research and Development, 2013, 30(8): 1–5 (in Chinese)

    Google Scholar 

  11. Sun L, Xin XT, Ren JL. Pavement Performance of Nanomaterial Modified Asphalt Mixture[J]. Journal of Southeast University(Natural Science Edition), 2013, 43(4): 873–876 (in Chinese)

    Google Scholar 

  12. Zhang H, Yu J, Wu S. Effect of Montmorillonite Organic Modification on Ultraviolet Aging Properties of SBS Modified Bitumen[J]. Constr. Build.Mater., 2012, 27: 553–559

    Article  Google Scholar 

  13. Zhang JP, Liu GQ, Du H. Rheological Properties of Warm Mix Asphalt Binder by DSR Test at Medium Temperature[J]. Journal of Southeast University(English Edition), 2015, 31(3): 384–388

    Google Scholar 

  14. Zhu JH, Shen W, Xu HL. Direct Synthesis of Titanium Substituted SBA-15 under Conventional Hydrothermal Conditions and Their Catalysis Characterization[J]. Acta Chimica Sinica, 2003, 61(2): 202–207 (in Chinese)

    Google Scholar 

  15. Zhang ZZ, Wang BT. Preparation and Water Retention Properties of Clay-based Sand-fixing and Grass-planting Materials[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2013, 4: 325–328

    Article  Google Scholar 

  16. Gao Y, Gu F, Zhao YL. Thermal Oxidative Aging Characterization of SBS Modified Asphalt[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2013, 28(1): 88–91

    Article  Google Scholar 

  17. Sun L, Xin XT, Wang HY, Performance of Nanomaterial Modified Asphalt as Paving Materials[J]. Journal of The Chinese Ceramic Society, 2012, 40(8): 1095–1101(in Chinese)

    Google Scholar 

  18. Xue Y, Wu S, Cai J, et al. Effects of Two Biomass Ashes on Asphalt Binder: Dynamic Shear Rheological Characteristic Analysis[J]. Constr. Build. Mater., 2014, 15(56): 7–15

    Article  Google Scholar 

  19. Gu XY, Xu TT, NI FJ. Rheological Behavior of Basalt Fiber Reinforced Asphalt Mastic[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2014, 29(5): 950–955

    Article  Google Scholar 

  20. Wang L, Chang CQ. Rheological Evaluation of Polymer Modified Asphalt Binders[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2015, 8: 695–702

    Article  Google Scholar 

  21. Sun CJ, Tang N, Pan P, Wu SP. Rheological Properties of Conductive Asphalt Binders Containing Graphite and Carbon Fiber before and after Aging[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2013, 6: 557–559

    Article  Google Scholar 

  22. Xiong P, Hao PW, Gao CM. Pavement Performance of SBS Modified Asphalt[J]. Journal of Chang’an University(Natural Science Edition), 2005, 25(1): 10–14, 19 (in Chinese)

    Google Scholar 

  23. Cong P, Zhang Y, Liu N. Investigation of the Properties of Asphalt Mixtures Incorporating Reclaimed SBS Modified Asphalt Pavement[J]. Constr. Build. Mater., 2016, 113: 334–340

    Article  Google Scholar 

  24. Wu MM, Li R, Zhang YZ. Study of High and Low Temperature Performance of Fiber-asphalt Mortar[J]. Journal of China University of Oetroleum (Natural Science), 2015, 39(1): 169–175(in Chinese)

    Google Scholar 

  25. Zhang HL, Su MM, Zhao SF. High and Low Temperature Properties of Nano-particles/polymer Modified Asphalt[J]. Constr. Build. Mater., 2016, 114: 323–332

    Article  Google Scholar 

  26. Wang SJ, Tai DC. Evaluating Indices for Low-temperature Performance of SBR Modified Asphalt Binder[J]. Journal of Chang’an University (Natural Science Edition), 2007, 27(3): 25–30 (in Chinese)

    Google Scholar 

  27. JTG E20-2011. Code for Highway Engineering Asphalt and Asphalt Mixture[S].

  28. ASTM-D2872. Standard Test Method for Effect of Heat and Air on a Moving Film of Asphalt (Rolling Thin-Film Oven Test)[S]. American Society for Testing and Materials, West Conshohocken, USA, 2004

    Google Scholar 

  29. ASTM-D1754. Standard Test Method for Effects of Heat and Air on Asphalt Materials (Thin-Film Oven Test)[S]. ASTM, Philadelphia (PA), 2009

    Google Scholar 

  30. ASTM-D4402. Standard Test Method for Viscosity Determination of Asphalt at Elevated Temperatures Using a Rotational Viscometer[S]. ASTM, Philadelphia (PA), 2006

    Google Scholar 

  31. ASTM-D6648. Standard Test Method for Determining the Flexural Creep Stiffness of Asphalt Binder Using the Bending Beam Rheometer[S]. ASTM, Philadelphia (PA), 2001

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Xiaoming Liu  (刘小明).

Additional information

Funded by the China Scholarship Council (201506375019)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, X., Cao, F., Wang, L. et al. Road performances of mesoporous nano-silica modified asphalt binders. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 32, 845–853 (2017). https://doi.org/10.1007/s11595-017-1678-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-017-1678-7

Key words

Navigation