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Effects of carbon nanotubes on mechanical and 2D-3D microstructure properties of cement mortar

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Abstract

To study the influence of multi-wall carbon nanotubes (MWCNTs) on the mechanical and microstructural properties of cementitious composites, 0.00, 0.02, 0.08, 0.10, and 0.20 wt% of multi-wall carbon nanotubes were added into cement mortar, in which the cement-sand ratio was 1:1.5. The flexural and compressive strengths of cement mortar at the age of 3, 7, 28 and 90 d and the fracture performance at the age of 28 d were determined, its 2D micrograph was tested by means of SEM, and the 3D defects distribution was firstly determined with or without CNTs by means of XCT (X-ray computerized tomography). The results showed that 0.08 wt% of CNTs improved the compressive strength and flexural strength by 18% and 19%, respectively, and a significant improvement of its fracture property was observed. Moreover lower addition of carbon nanotubes to cement mortars can improve its microstructure and decrease the defects significantly compared to the cement mortar without CNTs. With the increase of the content of CNTs, the mechanical properties of cement mortars presented to be declined largely due to the agglomeration of CNTs.

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References

  1. Iijima S. Helical Microtubes of Graphitic Carbon[J]. Nature, 1991, 354: 56–58

    Article  Google Scholar 

  2. Xun Yu, Eil Kwon. A Carbon Canotube/Cement Composite with Piezoresistive Properties [J]. Smart Mater. Struct., 2009, 18: 1–5

    Google Scholar 

  3. Geng Ying Li, Pei Ming Wang, Xiaohua Zhao. Mechanical Behavior and Microstructure of Cement Composites Incorporating Surface-Treated Multi-Walled Carbon Nanotube [J]. Carbon, 2005, 43: 1 239–1 245

    Article  Google Scholar 

  4. Ando Y. The Preparation of Carbon Nanotubes[J]. Fuel Sci. Technol., 1994, 2(2): 173–180

    Article  Google Scholar 

  5. J P Salvetat, J M Bonard, N H Thomson, et al. Mechanical Properties of Carbon Nanotubes [J]. Appl. Phys., 1999, A 69(3): 255–260

    Article  Google Scholar 

  6. Maser W K, Benito A M, Martinez M T. Production of Carbon Nanotubes the Light Approach [J]. Carbon, 2002, 40(10):1 685–1 695

    Article  Google Scholar 

  7. Maria S Konsta-Gdoutos, Zoi S Metaxa, Surendra P Shah. Highly Dispersed Carbon Nanotube Reinforced Cement Based Materials[J]. Cem. Concr. Res., 2010, 40: 1 052–1 059

    Article  Google Scholar 

  8. T Belytschko, S P Xiao, G C Schatz, et al. Atomistic Simulations of Nanotube Fracture [J]. Phys. Rev., 2002, B 65(23): 235 430–235 437

    Article  Google Scholar 

  9. K T Lau, D Hui. The Revolutionary Creation of New Advanced Materials-Carbon Nanotube [J]. Compos., 2002, B 33: 263–277

    Article  Google Scholar 

  10. T Wei, Z Fan, G Luo, et al. A New Structure for Multi-Walled Carbon Nanotubes Reinforced Alumina Nanocomposite with High Strength and Toughness [J]. Mater. Lett., 2008, 62: 641–644

    Article  Google Scholar 

  11. Y F Zhu, L Shi, J Liang, et al. Synthesis of Zirconia Nanoparticles on Carbon Nanotubes and Their Potential for Enhancing the Fracture Toughness of Alumina Ceramics[J]. Compos., 2008, B 39: 1 136–1 141

    Article  Google Scholar 

  12. H Lee, S Mall, P He, et al. Characterization of Carbon Nanotube/Nanofiber-Reinforced Polymer Composites Using an Instrumented Indentation Technique [J]. Compos., 2007, B 38: 58–65

    Article  Google Scholar 

  13. A M K Esawia, K Morsi, A Sayed, et al. Fabrication and Properties of Dispersed Carbon Nanotube-Aluminum Composites [J]. Mater. Sci. Eng., 2009, A508:167–173

    Article  Google Scholar 

  14. Makar J M, Beaudoin J J. Carbon Nanotubes and their Applications in the Construction Industry [C]. In: Proceedings of the First International Symposium on Nanotechnology in Construction, Paisley, Scotland, 2003

    Google Scholar 

  15. Chong K P, Garboczi E J. Smart and Designer Structural Material Systems [J]. Prog. Struct. Mater. Eng., 2002, 4: 417–30

    Article  Google Scholar 

  16. F Sanchez, K Sobolev. Nanotechnology in Concrete-A review [J]. Construction and Building Materials, 2010, 24: 2 060–2 071

    Article  Google Scholar 

  17. Makar J M, Margeson J, Luh J. Carbon Nanotube/Cement Composites-Early Results and Potential Applications [C]. In: Proceedings of 3rd International Conference on Construction Materials: Performance, Innovations and Structural Implications, Vancouver, 2005

    Google Scholar 

  18. Li G Y, Wang P M, Zhao X. Pressure-Sensitive Properties and Microstructure of Carbon Nanotube Reinforced Cement Composites [J]. Cem. Concr. Compos., 2007; 29(5): 377–82

    Article  Google Scholar 

  19. Konsta-Gdoutos M S, Metaxa Z S, Shah S P. Multi-Scale Mechanical and Fracture Characteristics and Early-Age Strain Capacity of High Performance Carbon Nanotube/Cement Nanocomposites [J]. Cem. Concr. Compos., 2010, 32(2):110–115

    Article  Google Scholar 

  20. Chong K P, Garboczi E J. Smart and Designer Structural Material Systems [J]. Prog. Struct. Mater. Eng., 2002, 4:417–430

    Article  Google Scholar 

  21. A Chaipanich, T Nochaiya, W Wongkeo, et al. Compressive Strength and Microstructure of Carbon Nanotubes-Fly Ash Cement Composites [J]. Mater. Sci. Eng., 2010, A 527:1 063–1 067

    Article  Google Scholar 

  22. T Nochaiya, P Tolkidtikul, P Singjai, A Chaipanich. Microstructure and Characterizations of Portland-Carbon Nanotubes Pastes [J]. Adv. Mater. Res., 2008, 55:549–552

    Article  Google Scholar 

  23. P Torkittikul. A Chaipanich. Bioactivity Properties of White Portland Cement Paste with Carbon Nanotubes [C]. In: Proceedings of INEC 2010 3rd International Nanoelectronics Conference, Hong Kong, 2010

    Google Scholar 

  24. Cwirzen A, Habermehl-Cwirzen K, Nasibulin A, et al. SEM/AFM Studies of Cementitious Binder Modified by MWCNT and Nano-Sized Fe Needles [J]. Mater. Char., 2008, 60: 753–760

    Google Scholar 

  25. Shah S P, Konsta-Gdoutos M S, Metaxa Z S, et al. Nanoscale Modification of Cementitious Materials [C]. In: Nanotechnology in Construction: Proceedings of the NICOM 3 (3rd International Symposium on Nanotechnology in Construction), Prague, Czech Republic; 2009

    Google Scholar 

  26. Cwirzen A, Habermehl-Cwirzen K, Penttala V. Surface Decoration of Carbon Nanotubes and Mechanical Properties of Cement/Carbon Nanotube Composites [J]. Adv. Cem. Res., 2008, 20(2):65–73

    Article  Google Scholar 

  27. Saez de Ibarra Y, Gaitero J J, Erkizia E, et al. Atomic Force Microscopy and Nanoindentation of Cement Pastes with Nanotube Dispersions [J]. Phys. Status. Solidi., 2006, 203(6):1 076–1 081

    Article  Google Scholar 

  28. Y Junrong, N Grossiord, C E Koning, et al. Controlling the Dispersion of Multi-Wall Carbon Nanotubes in Aqueous Surfactant Solution [J]. Carbon, 2007, 45(3); 618–623

    Article  Google Scholar 

  29. T Hielscher. Ultrasonic Production of Nano-Size Dispersions and Emulsions [C]. Proceedings of 1st Workshop on NanoTechnology Transfer in Europe, Grenoble, France, 2006

    Google Scholar 

  30. Han Jiande, Sun Wei, Pan Ganghua, et al. Application of X-ray Computed Tomography in Characterization Microstructure Changes of Cement Pastes in Carbonation Process[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2012, 27(2): 358–363

    Article  Google Scholar 

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Correspondence to Qiaoling Liu  (刘巧玲).

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Funded by the National Basic Research Program of China (No. 2009CB623200), the Program for Changjiang Scholars and Innovative Research Team in University of China (No. IRT13075)

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Liu, Q., Sun, W., Jiang, H. et al. Effects of carbon nanotubes on mechanical and 2D-3D microstructure properties of cement mortar. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 29, 513–517 (2014). https://doi.org/10.1007/s11595-014-0950-3

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  • DOI: https://doi.org/10.1007/s11595-014-0950-3

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