Abstract
This work reports on the synthesis of FeCo2Se4 from FeCo2O4 by varying the duration of the selenization process. The structure and crystallinity of the products were characterized using X-ray diffraction (XRD). Energy dispersive X-ray spectroscopy (EDX) analyzed the compositions of the products. The FeCo2O4 presents a thinner and smoother nanosheets structure whereas the FeCo2Se4 forms a thicker and rougher nanosheets structure. The electrocatalytic effects of FeCo2Se4 and FeCo2O4 in comparison to Pt were examined by cyclic voltammetry (CV) and further supported by Tafel polarization. Electrochemical impedance spectroscopy (EIS) was employed to study the internal resistance and charge transfer kinetics. The FeCo2Se4 obtained after 12 h selenization treatment (FeCo2Se4) exhibits the highest electrocatalytic activity and the lowest charge transfer resistance, followed by Pt and FeCo2O4. The poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP)/ propylene carbonate (PC)/ 1,2-dimethoxyethane (DME)/ 1-methyl-3-propyl imidazolium iodide (MPII)/ sodium iodide (NaI)/ iodine (I2) gel polymer electrolytes were assembled into dye-sensitized solar cells (DSSCs) with titanium oxide (TiO2) photoanode and the respective counter electrode. The respective counter electrode was FeCo2Se4, FeCo2O4, or platinum (Pt). The efficiencies attained for FeCo2Se4, FeCo2O4, and Pt counter electrodes are 8.71, 6.04, and 6.11%, respectively. Superior cell efficiency with FeCo2Se4 counter electrode can be attributed to the higher porosity, larger specific surface area, lower electron transfer resistance, and higher I3− reduction rate of FeCo2Se4.
Similar content being viewed by others
Data availability
The raw and processed data required to reproduce the above findings cannot be shared at this time as the data also forms part of an ongoing study.
References
Bhushan I, Kumar V, Durgesh S, Tripathi K (2020) Nanotechnology in the Life Sciences Nanomaterials and Environmental Biotechnology. Cham:Springer 342
Green MA (2009) The path to 25% silicon solar cell efficiency: history of silicon cell evolution. Progr Photovoltaics: Res Appl 17(3):183–189
Zhang A, Guo Z (2016) Efficient light trapping in tapered silicon nanohole arrays. Optik (Stuttg) 127:2861–2865
Li G, Lu Y, Xuan Q et al (2020) Performance analysis on a crystalline silicon photovoltaic cell under non-uniform illumination distribution with a high electrical efficiency. Sol Energy 203:275–283
Kakiage K, Aoyama Y, Yano T et al (2015) Highly-efficient dye-sensitized solar cells with collaborative sensitization by silyl-anchor and carboxy-anchor dyes. Chem Commun 51:15894–15897
Razamin NAY, Muhammad FH, Subban RHY, Winie T (2019) Stability improvement by incorporating poly(ε-caprolactone) in dimethylformamide-potassium iodide liquid electrolyte for dye-sensitized solar cell. J Solid State Electrochem 23:2411–2421
Singh R, Janakiraman S, Agrawal A et al (2020) An amorphous poly(vinylidene fluoride-co-hexafluoropropylene) based gel polymer electrolyte for magnesium ion battery. J Electroanalytical Chem 858:113788
Saaid FI, Tseng TY, Winie T (2018) PVdF-HFP quasi-solid-state electrolyte for application in dye-sensitized solar cells. Int J Technol 9:1187–1195
Wang P, Zakeeruddin SM, Moser JE et al (2003) A stable quasi-solid-state dye-sensitized solar cell with an amphiphilic ruthenium sensitizer and polymer gel electrolyte. Nat Mater 2:402–440
Zhang S, Jin J, Li D et al (2019) Increased power conversion efficiency of dye-sensitized solar cells with counter electrodes based on carbon materials. RSC Adv 9:22092–22100
Shaikh JS, Shaikh NS, Mali SS et al (2018) Nanoarchitectures in dye-sensitized solar cells: metal oxides, oxide perovskites and carbon-based materials. Nanoscale 10:4987–5034
Marchini E, Caramori S, Bignozzi CA, Carli S (2021) On the use of pedot as a catalytic counter electrode material in dye-sensitized solar cells. Appl Sci (Switzerland) 11(9):3795
Maiaugree W, Pimparue P, Jarernboon W et al (2017) NiS(NPs)-PEDOT-PSS composite counter electrode for a high efficiency dye sensitized solar cell. Mater Sci Eng B Solid State Mater Adv Technol 220:66–72
Gao C, Han Q, Wu M (2018) Review on transition metal compounds based counter electrode for dye-sensitized solar cells. J Energy Chem 27:703–712
Duan Y, Tang Q, Liu J et al (2014) Transparent metal selenide alloy counter electrodes for high- efficiency bifacial dye-sensitized solar cells. Angewandte Chemie - International Edition 53:14569–14574
Narudin N, Ekanayake P, Soon YW et al (2021) Enhanced properties of low-cost carbon black-graphite counter electrode in DSSC by incorporating binders. Sol Energy 225:237–244
Yun S, Hagfeldt A, Ma T (2014) Pt-free counter electrode for dye-sensitized solar cells with high efficiency. Adv Mater 26:6210–6237
Lei H, Zhou J, Zhao R et al (2020) Design and assembly of a novel asymmetric supercapacitor based on all-metal selenides electrodes. Electrochim Acta 363:137206
Mohamed AM, Allam NK (2022) Transition metal selenide (TMSe) electrodes for electrochemical capacitor devices: a critical review. J Energy Storage 47:103565
Liu WW, Jiang W, Liu YC et al (2020) Platinum-free ternary metallic selenides as nanostructured counter electrode for high-efficiency dye-sensitized solar cell by interface engineering. ACS Appl Energy Mater 3:3704–3713
Subalakshmi K, Kumar KA, Paul OP et al (2019) Platinum-free metal sulfide counter electrodes for DSSC applications: structural, electrochemical and power conversion efficiency analyses. Sol Energy 193:507–518
Baptayev B, Mustazheb D, Balanay MP (2020) Binary transition metal sulfides as an economical Pt-free counter electrodes for dye-sensitized solar cells. Mater Today Proc 25:24–27
Dao V-D, Quang DV, Vu NH et al (2019) Transition metal oxides as Pt-free counter electrodes for liquid-junction photovoltaic devices. Vietnam J Chem 57:784–791
Chen YL, Huang YJ, Yeh MH et al (2022) Nanoflower-like P-doped nickel oxide as a catalytic counter electrode for dye-sensitized solar cells. Nanomater 12(22):4036
Low WH, Khiew PS, Lim SS et al (2019) Recent development of mixed transition metal oxide and graphene/mixed transition metal oxide based hybrid nanostructures for advanced supercapacitors. J Alloys Compd 775:1324–1356
Kate RS, Khalate SA, Deokate RJ (2018) Overview of nanostructured metal oxides and pure nickel oxide (NiO) electrodes for supercapacitors: a review. J Alloys Compd 734:89–111
Ge P, Zhang C, Hou H et al (2018) Anions induced evolution of Co3X4 (X = O, S, Se) as sodium-ion anodes: the influences of electronic structure, morphology, electrochemical property. Nano Energy 48:617–629
Yousaf M, Naseer U, Ali I et al (2022) Role of binary metal chalcogenides in extending the limits of energy storage systems: challenges and possible solutions. Sci China Mater 65:559–592
Zheng J, Guo Z, Zhou W et al (2018) Synergistic effect of Ni and Fe in Fe-doped NiS2 counter electrode for dye-sensitized solar cells: experimental and DFT studies. Electrochim Acta 284:24–29
Zakaria PNM, Noor ISM, Winie T (2023) Caulerpa lentillifera seaweed extract as natural sensitizer for dye-sensitized solar cell. Macromol Symp 407(1):2100359
Najihah MZ, Noor IM, Winie T (2022) Long-run performance of dye-sensitized solar cell using natural dye extracted from Costus woodsonii leaves. Opt Mater (Amst) 123:111915
Rajkumar S, Elanthamilan E, Princy Merlin J, Sathiyan A (2021) Enhanced electrochemical behaviour of FeCo2O4/PANI electrode material for supercapacitors. J Alloys Compd 874:159876
Yadav AA, Hunge YM, Kulkarni SB (2019) Synthesis of multifunctional FeCo2O4 electrode using ultrasonic treatment for photocatalysis and energy storage applications. Ultrason Sonochem 58:104663
Xu G, Zhang Z, Qi X et al (2018) Hydrothermally synthesized FeCo2O4 nanostructures: structural manipulation for high-performance all solid-state supercapacitors. Ceram Int 44:120–127
Kadam HK, Tilve SG (2015) Advancement in methodologies for reduction of nitroarenes. RSC Adv 5:83391–83407
Du J, You S, Li X et al (2020) In situ crystallization of active NiOOH/CoOOH heterostructures with hydroxide ion adsorption sites on velutipes-like CoSe/NiSe nanorods as catalysts for oxygen evolution and cocatalysts for methanol oxidation. ACS Appl Mater Interfaces 12:686–697
Ding G, Li Y, Gao Y et al (2020) Uniform coating of Se on selenophilic surfaces of nickel-rich layered oxide cathode materials for high performance Li-Ion batteries. ACS Sustain Chem Eng 8:9632–9640
Upadhyay S, Pandey OP (2021) Synthesis of layered 2H–MoSe2 nanosheets for the high-performance supercapacitor electrode material. J Alloys Compd 857:157522
Wang H, Xu Y, Yu X et al (2013) Structure and morphology control in thin films of conjugated polymers for an improved charge transport. Polymers (Basel) 5:1272–1324
Vijaya S, Landi G, Wu JJ, Anandan S (2019) MoS2 nanosheets based counter electrodes: an alternative for Pt-free dye-sensitized solar cells. Electrochim Acta 294:134–141
Ji Y, Cao J, Jiang L et al (2014) G-C3N4/BiVO4 composites with enhanced and stable visible light photocatalytic activity. J Alloys Compd 590:9–14
Cho JS, Park JS, Kang YC (2016) Preparation of hollow Fe2O3 nanorods and nanospheres by nanoscale Kirkendall diffusion, and their electrochemical properties for use in lithium-ion batteries. Sci Rep 6(1):38933
Duan Y, Tang Q, He B et al (2015) Bifacial dye-sensitized solar cells with transparent cobalt selenide alloy counter electrodes. J Power Sources 284:349–354
Guan G, Wu J, Huang J, Qian X (2022) Polynary metal selenide CoSe2/NiSe2/MoSe2 porous nanospheres as efficient electrocatalytic materials for high-efficiency dye-sensitized solar cells. J Electroanal Chem 924:116888
Bu C, Liu Y, Yu Z et al (2013) Highly transparent carbon counter electrode prepared via an in situ carbonization method for bifacial dye-sensitized solar cells. ACS Appl Mater Interfaces 5:7432–7438
Wang Z, Xu H, Zhang Z et al (2014) High-performance cobalt selenide and nickel selenide nanocomposite counter electrode for both iodide/triiodide and cobalt(II/III) redox couples in dye-sensitized solar cells. Chin J Chem 32:491–497
Pang B, Lin S, Shi Y et al (2019) Synthesis of CoFe2O4/graphene composite as a novel counter electrode for high performance dye-sensitized solar cells. Electrochim Acta 297:70–76
Kumar R, Nemala SS, Mallick S, Bhargava P (2017) High efficiency dye sensitized solar cell made by carbon derived from sucrose. Opt Mater (Amst) 64:401–405
Jia J, Wu J, Dong J et al (2015) Cobalt selenide/tin selenide hybrid used as a high efficient counter electrode for dye-sensitized solar cells. J Mater Sci: Mater Electron 26:10102–10108
Murugadoss V, Panneerselvam P, Yan C et al (2019) A simple one-step hydrothermal synthesis of cobalt[sbnd]nickel selenide/graphene nanohybrid as an advanced platinum free counter electrode for dye sensitized solar cell. Electrochim Acta 312:157–167
Huang S, He Q, Chen W et al (2015) 3D hierarchical FeSe2 microspheres: controlled synthesis and applications in dye-sensitized solar cells. Nano Energy 15:205–215. https://doi.org/10.1016/j.nanoen.2015.04.027
Jiang T, Yin N, Bai Z et al (2018) Wet chemical synthesis of S doped Co 3 O 4 nanosheets/reduced graphene oxide and their application in dye sensitized solar cells. Appl Surf Sci 450:219–227. https://doi.org/10.1016/j.apsusc.2018.04.148
Qian X, Li H, Shao L et al (2016) Morphology-tuned synthesis of nickel cobalt selenides as highly efficient Pt-free counter electrode catalysts for dye-sensitized solar cells. ACS Appl Mater Interfaces 8:29486–29495
Jiang Q, Pan K, Lee CS et al (2017) Cobalt-nickel based ternary selenides as high-efficiency counter electrode materials for dye-sensitized solar cells. Electrochim Acta 235:672–679
Huang S, He Q, Liu M et al (2020) Controlled synthesis of porous nanosheets-assembled peony-like cobalt nickel selenides for triiodide reduction in dye-sensitized solar cells. J Alloys Compd 818:152817
Jin Z, Zhao G, Wang ZS (2018) Controllable growth of Ni:XCoySe films and the influence of composition on the photovoltaic performance of quasi-solid-state dye-sensitized solar cells. J Mater Chem C Mater 6:3901–3909
Wang H, Huang S, Wang S et al (2019) Colloid synthesis of CuFeSe2 nanocubes as efficient electrocatalysts for dye-sensitized solar cells. J Electroanalytical Chem 834:26–32
Li P, Tang Q (2016) Highly transparent metal selenide counter electrodes for bifacial dye-sensitized solar cells. J Power Sources 317:43–48
Zhao Y, Duan J, Duan Y et al (2018) 9.07%-Efficiency dye-sensitized solar cell from Pt-free RuCoSe ternary alloy counter electrode. Mater Lett 218:76–79
Wei P, Li J, Hao Z et al (2019) In situ synthesis of ternary nickel iron selenides with high performance applied in dye-sensitized solar cells. Appl Surf Sci 492:520–526
Yang P, Tang Q (2016) A branching NiCuPt alloy counter electrode for high-efficiency dye-sensitized solar cell. Appl Surf Sci 362:28–34
Acknowledgements
M. Z. Najihah wishes to thank the Ministry of Education Malaysia for the MyBrainSc scholarship award.
Author information
Authors and Affiliations
Contributions
M. Z. Najihah — methodology, investigation, data curation, formal analysis, original draft writing; Farish Irfal Saaid — methodology, investigation, data curation, formal analysis; I. M. Noor — conceptualization, supervision, formal analysis; H. J. Woo — resources, formal analysis; Tan Winie — conceptualization, resources, supervision, project administration, writing (review and editing).
Corresponding author
Ethics declarations
Ethics approval
Not applicable.
Competing interests
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Najihah, M.Z., Saaid, F.I., Noor, I.M. et al. Iron cobalt selenide counter electrode for application in dye-sensitized solar cell: synthesis parameter, structural, electrochemical, and efficiency studies. Ionics 30, 2939–2955 (2024). https://doi.org/10.1007/s11581-024-05462-z
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11581-024-05462-z