Abstract
Membrane (ion membrane) electrolysis technology has gained a lot of attention and development because of its function and advantage of making full use of the two-stage reaction and separating the products of the two poles. In particular, the membrane electrolysis industry has a great potential to grow in the context of the transformation from “carbon-driven” to “electrically driven.” There are many systems that require membrane or ion membrane electrolysis. Typical ones are electrolytic water to hydrogen, chlor-alkali, electrodialysis, electrometallurgy, etc. In this paper, several typical membrane (ion membrane) electrolysis scenarios are selected and analyzed in detail with respect to their principles, development history, characteristics, problems faced, and development prospects. A theoretical basis is laid for the development and application of efficient industrialized membrane electrolysis technology, which will be beneficial to the technological progress in this field.
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Abbreviations
- IEMs:
-
Ion exchange membranes
- CEMs:
-
Cation exchange membranes
- AWE:
-
Alkaline water electrolysis
- PEM:
-
Proton exchange membrane electrolysis
- AEM:
-
Alkaline ion membrane electrolysis
- SOE:
-
Solid oxide electrolytic
- SOEC:
-
Solid oxide electrolytic cell
- AEMWE:
-
Anion exchange membrane water electrolysis
- YSZ:
-
Y2O3-stabilized ZrO2
- ScSZ:
-
Scandium-stabilized zirconium oxide
- LSM:
-
La1-xSrxMnO3
- HP:
-
Hydrogen production
- PFSA:
-
Perfluorosulfonic acid membrane
- PFCA:
-
Perfluoro carboxylic acid membrane
- PTFE:
-
Polytetrafluoroethylene
- ED:
-
Electrodialysis
- SCT-SAPs:
-
Side chain sulfonated aromatic polymers
- R s :
-
Measured internal resistance of the membrane [Ω]
- A :
-
Area of the electrode [cm2]
- R :
-
R = 8.314 J/(mol·K) is the universal gas constant
- T :
-
Reaction temperature [K]
- F :
-
Faraday’s constant [C·mol−1]
- φ m :
-
Membrane potential
- φ s :
-
Solution potential
- σ :
-
Porosity
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Funding
The National Natural Science Foundation of China (No. 51504231), State Key Laboratory of Multiphase Complex Systems (No. MPCS-2022-A-02), Yunnan Ten Thousand Talents Plan Young & Elite Talents Project (YNWR-QNBJ-2018-327), and Innovation Academy for Green Manufacture Institute, Chinese Academy of Sciences (No. IAGM2022D08).
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HS: wrote the original draft, revised the manuscript, and conducted investigation. HY (corresponding author): conceptualization, project administration, and framework of the manuscript. XY: provided some ideas and discussions. XW: provided some ideas and discussions. HJ: provided some ideas and discussions. YT: provided some ideas and discussions. JH: provided some ideas and discussions. All authors have reviewed the manuscript and agreed to publish it.
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Song, H., Yang, H., Yu, X. et al. Research progress of industrial application of membrane electrolysis technology. Ionics 30, 1223–1243 (2024). https://doi.org/10.1007/s11581-024-05395-7
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DOI: https://doi.org/10.1007/s11581-024-05395-7