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Steady-state interface construction of high-voltage nickel-rich lithium-ion battery cathodes by low-content LixCoO2 surface modification engineering

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Abstract

The nickel-rich layered ternary cathode material has gained widespread interest for its high theoretical specific capacity. However, the inferior charge/discharge cycle, because of increased side reactions at high cut-off voltages, severely limits its application in industrial applications. Improving the electrochemical performance of LiNi0.8Co0.1Mn0.1O2 by forming a protective layer without changing the structural characteristics of the electrode material itself is considered to be the most effective method. In this work, we constructed a LixCoO2 crystalline cladding layer through an extremely effortless and very easy-to-industrialize method. These coating materials significantly improved the cycling stability of NCM811 at 4.8 V ultra-high cut-off voltage. Results of characterization showed that after 100 cycles at 1 C (2.8–4.8 V), the 1.0 wt% modified NCM811 and pristine NCM811 show a retention of 77% and 53%, respectively. This is attributable to the fact that the coating material can effectively mitigate the interfacial side reactions to protect the active electrode material, further enhance the kinetic transport properties of Li+ across the interface, and reduce the degradation of the bulk structure. Based on these results, we think that the LixCoO2 crystalline cladding layer is a useful way to very significantly elevate the properties of nickel-rich lithium metal oxide electrode materials.

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Funding

This study was supported by the National Natural Science Foundation of China General Project (52272089, 51578448), National Natural Science Youth Fund Project (51308447), Shaanxi Province Outstanding Youth Science Foundation (2021JC-43), and Scientific Research Program Funded by Shaanxi Provincial Education Department (Grant/Award Number: 20JY042).

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  1. College of Materials Science and Engineering, Xi’an University of Architecture and Technology, Xi’an, 710055, Shaanxi, China

    Xiaolin Ye, Jian Wei, Xinyu Qiao, Yuxuan Ji & Bing Chen

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  1. Xiaolin Ye
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Xiaolin Ye and Jian Wei wrote the main manuscript text. Xinyu Qiao, Yuxuan Ji, and Bing Chen reviewed the manuscript.

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Ye, X., Wei, J., Qiao, X. et al. Steady-state interface construction of high-voltage nickel-rich lithium-ion battery cathodes by low-content LixCoO2 surface modification engineering. Ionics 29, 3039–3053 (2023). https://doi.org/10.1007/s11581-023-05056-1

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