Abstract
Compared with Li-ion batteries, dual-graphite batteries (DGBs) have low cost, easy handling, and renewable advantages. However, DGBs with pure ionic liquid as the electrolyte (LEDGBs) suffer from high self-discharge rate (SDR). Here, a gel polymer electrolyte (ILGPE) was prepared using polyvinylidene fluoride as the polymer matrix and 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide as the electrolyte and assembled into a gel polymer double-graphite battery (IGDGB). The results show that the IGDGB has an initial discharge capacity of 34.9 mAh g-1, and SDR is only 3.63%/h lower than the LEDGB (25.07%/h) after resting for 3 h. Notably, even after resting for 10 h, the IGDGB still has a discharge capacity of 27.5 mAh g-1. Meanwhile, the electrochemical impedance spectroscopy analysis results indicate that the low SDR of IGDGB is due to the limiting effect of ILGPE on the carrier strength. This result provides an idea of self-discharge reduction strategy for other electrochemical energy storage systems with intercalation storage mechanism.
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References
Li J, Fleetwood J, Hawley WB, Kays W (2022) From materials to cell: state-of-the-art and prospective technologies for lithium-ion battery electrode processing. Chem Rev 122(1):903–956. https://doi.org/10.1021/acs.chemrev.1c00565
Armand M, Tarascon JM (2008) Building better batteries. Nature 451(7179):652–657. https://doi.org/10.1038/451652a
Kang B, Ceder G (2009) Battery materials for ultrafast charging and discharging. Nature 458(7235):190–193. https://doi.org/10.1038/nature07853
Etacheri V, Marom R, Elazari R, Salitra G, Aurbach D (2011) Challenges in the development of advanced Li-ion batteries: a review. Energ Environ Sci 4(9):3243–3262. https://doi.org/10.1039/c1ee01598b
Dai H, Zhang G, Rawach D, Fu C, Wang C, Liu X, Dubois M, Lai C, Sun S (2021) Polymer gel electrolytes for flexible supercapacitors: recent progress, challenges, and perspectives. Energy Storage Mater 34:320–355. https://doi.org/10.1016/j.ensm.2020.09.018
Luo P, Zheng C, He J, Tu X, Sun W, Pan H, Zhou Y, Rui X, Zhang B, Huang K (2022) Structural engineering in graphite-based metal-ion batteries. Adv Funct Mater 32(9):2107277. https://doi.org/10.1002/adfm.202107277
Rothermel S, Meister P, Schmuelling G, Fromm O, Meyer HW, Nowak S, Winter M, Placke T (2014) Dual-graphite cells based on the reversible intercalation of bis(trifluoromethanesulfonyl)imide anions from an ionic liquid electrolyte. Energ Environ Sci 7(10):3412–3423. https://doi.org/10.1039/c4ee01873g
Yang QW, Zhang ZQ, Sun XG, Hu YS, Xing HB, Dai S (2018) Ionic liquids and derived materials for lithium and sodium batteries. Chem Soc Rev 47(6):2020–2064. https://doi.org/10.1039/c7cs00464h
Pan S, Yao M, Zhang J, Li B, Xing C, Song X, Su P, Zhang H (2020) Recognition of ionic liquids as high-voltage electrolytes for supercapacitors. Front Chem 8. https://doi.org/10.3389/fchem.2020.00261
Fan JX, Zhang ZX, Liu YH, Wang AY, Li L, Yuan WH (2017) An excellent rechargeable PP14TFSI ionic liquid dual-ion battery. Chem Commun 53(51):6891–6894. https://doi.org/10.1039/c7cc02534c
Huang Y, Xiao RG, Ma ZM, Zhu WC (2019) Developing dual-graphite batteries with pure 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ionic liquid as the electrolyte. Chemelectrochem 6(17):4681–4688. https://doi.org/10.1002/celc.201901171
Wang AY, Yuan WH, Fan JX, Li L (2018) A dual-graphite battery with pure 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl) imide as the electrolyte. Energ Technol 6(11):2172–2178. https://doi.org/10.1002/ente.201800269
Vranes M, Dozic S, Djeric V, Gadzuric S (2012) Physicochemical characterization of 1-butyl-3-methylimidazolium and 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide. J Chem Eng Data 57(4):1072–1077. https://doi.org/10.1021/je2010837
Fang Y-B, Zheng W, Li L, Yuan W-H (2020) An ultrahigh rate ionic liquid dual-ion battery based on a poly(anthraquinonyl sulfide) anode. Acs Appl Energ Mater 3(12):12276–12283. https://doi.org/10.1021/acsaem.0c02335
Zhu W, Xiao R, Cai Z, Huang Y, Chen J (2021) Electrochemically active layer on the surface of poly(anthraquinonyl sulfide) anode in dual-ion batteries. Polym 212:123167. https://doi.org/10.1016/j.polymer.2020.123167
Jiang B, Zhu W, Cai Z, Zeng Y, Xiao R (2022) Graphene-based conductive networks to enhance the performance of polyimide anode materials for dual-ion batteries. Chemistryselect 7(9):e202200092. https://doi.org/10.1002/slct.202200092
Zhu W, Huang Y, Jiang B, Xiao R (2021) A metal-free ionic liquid dual-ion battery based on the reversible interaction of 1-butyl-1-methylpyrrolidinium cations with 1,4,5,8-naphthalenetetracarboxylic dianhydride. J Mol Liq 339:116789. https://doi.org/10.1016/j.molliq.2021.116789
Liu H, Zhu W, Zhou H, Wang J (2022) Research of dual-ion polymer batteries based on N-butyl-N-methylpiperidinium bis(trifluoromethylsulfonyl)imide ionic liquid electrolyte. Ionics. https://doi.org/10.1007/s11581-022-04652-x
Kim J, Kim Y, Yoo J, Kwon G, Ko Y, Kang K (2022) Organic batteries for a greener rechargeable world. Nat Rev Mater. https://doi.org/10.1038/s41578-022-00478-1
Li W, Pang Y, Zhu T, Wang Y, Xia Y (2018) A gel polymer electrolyte based lithium-sulfur battery with low self-discharge. Solid State Ion 318:82–87. https://doi.org/10.1016/j.ssi.2017.08.018
Zhao C, Sun X, Li W, Shi M, Ren K, Lu X (2021) Reduced self-discharge of supercapacitors using piezoelectric separators. Acs Appl Energ Mater 4(8):8070–8075. https://doi.org/10.1021/acsaem.1c01373
Obeidat AM, Rastogi AC (2016) Graphene and poly (3,4-ethylenedioxythiophene) (PEDOT) based hybrid supercapacitors with ionic liquid gel electrolyte in solid state design and their electrochemical performance in storage of solar photovoltaic generated electricity. MRS Adv 1(53):3565–3571. https://doi.org/10.1557/adv.2016.322
Kasprzak D, Galiński M (2022) Biopolymer-based gel electrolytes with an ionic liquid for high-voltage electrochemical capacitors. Electrochem Commun 138:107282. https://doi.org/10.1016/j.elecom.2022.107282
Dong X, Chen L, Su X, Wang Y, Xia Y (2016) Flexible aqueous lithium-ion battery with high safety and large volumetric energy density. Angew Chem Int Ed 55(26):7474–7477. https://doi.org/10.1002/anie.201602766
Choudhury S, Saha T, Naskar K, Stamm M, Heinrich G, Das A (2017) A highly stretchable gel-polymer electrolyte for lithium-sulfur batteries. Polym 112:447–456. https://doi.org/10.1016/j.polymer.2017.02.021
Zhou D, Shanmukaraj D, Tkacheva A, Armand M, Wang G (2019) Polymer electrolytes for lithium-based batteries: advances and prospects. Chem-Us 5(9):2326–2352. https://doi.org/10.1016/j.chempr.2019.05.009
Yan J, Li S, Lan B, Wu Y, Lee PS (2020) Rational design of nanostructured electrode materials toward multifunctional supercapacitors. Adv Funct Mater 30(2):1902564. https://doi.org/10.1002/adfm.201902564
Wu YX, Li Y, Wang Y, Liu Q, Chen QG, Chen MH (2022) Advances and prospects of PVDF based polymer electrolytes. J Energy Chem 64:62–84. https://doi.org/10.1016/j.jechem.2021.04.007
Saito Y, Kataoka H, Quartarone E, Mustarelli P (2002) Carrier migration mechanism of physically cross-linked polymer gel electrolytes based on PVDF membranes. J Phys Chem B 106(29):7200–7204. https://doi.org/10.1021/jp020633v
Wieczorek W, Such K, Wyciślik H, Płocharski J (1989) Modifications of crystalline structure of peo polymer electrolytes with ceramic additives. Solid State Ion 36(3):255–257. https://doi.org/10.1016/0167-2738(89)90185-9
Capuano F, Croce F, Scrosati B (1991) Composite polymer electrolytes. J Electrochem Soc 138(7):1918–1922. https://doi.org/10.1149/1.2085900
Shen BS, Lang JW, Guo RS, Zhang X, Yan XB (2015) Engineering the electrochemical capacitive properties of microsupercapacitors based on graphene quantum dots/MnO2 using ionic liquid gel electrolytes. ACS Appl Mater Interfaces 7(45):25378–25389. https://doi.org/10.1021/acsami.5b07909
Deng XY, Li JJ, Zhu S, Ma LY, Zhao NQ (2019) Boosting the capacitive storage performance of MOF-derived carbon frameworks via structural modulation for supercapacitors. Energy Storage Mater 23:491–498. https://doi.org/10.1016/j.ensm.2019.04.015
Wang J, Chen G, Song S (2020) Na-ion conducting gel polymer membrane for flexible supercapacitor application. Electrochim Acta 330:135322. https://doi.org/10.1016/j.electacta.2019.135322
Watanabe M (2021) Advances in organic ionic materials based on ionic liquids and polymers. B Chem Soc Jpn 94(11):2739–2769. https://doi.org/10.1246/bcsj.20210281
Ravi M, Kim S, Ran F, Kim DS, Lee YM, Ryou M-H (2021) Hybrid gel polymer electrolyte based on 1-methyl-1-propylpyrrolidinium bis(trifluoromethanesulfonyl) imide for flexible and shape-variant lithium secondary batteries. J Membr Sci 621:119018. https://doi.org/10.1016/j.memsci.2020.119018
Hou X, Siow KS (2001) Electrochemical characterization of plasticized polymer electrolytes based on ABS/PMMA blends. J Solid State Electrochem 5(4):293–299. https://doi.org/10.1007/s100080000144
Lun P, Liu P, Lin H, Dai Z, Zhang Z, Chen D (2019) Ionic conductivity promotion of polymer membranes with oxygen-ion conducting nanowires for rechargeable lithium batteries. J Membr Sci 580:92–100. https://doi.org/10.1016/j.memsci.2019.03.006
Guo Y, Chen X, Xie Y, Shen Z, Ling Y, Xue X, Tong Y, Wang J, Zhang W, Zhao J (2022) A gel polymer electrolyte film based on chitosan derivative and ionic liquid for the LiFePO4 cathode solid Li metal battery. Mater Today Commun 31:103597. https://doi.org/10.1016/j.mtcomm.2022.103597
Jiao S, Lei H, Tu J, Zhu J, Wang J, Mao X (2016) An industrialized prototype of the rechargeable Al/AlCl3-[EMIm]Cl/graphite battery and recycling of the graphitic cathode into graphene. Carbon 109:276–281. https://doi.org/10.1016/j.carbon.2016.08.027
Dam T, Tripathy SN, Paluch M, Jena SS, Pradhan DK (2016) Investigations of relaxation dynamics and observation of nearly constant loss phenomena in PEO20-LiCF3SO3-ZrO2 based polymer nano-composite electrolyte. Electrochim Acta 202:147–156. https://doi.org/10.1016/j.electacta.2016.03.134
Tang J, Muchakayala R, Song S, Wang M, Kumar KN (2016) Effect of EMIMBF4 ionic liquid addition on the structure and ionic conductivity of LiBF4-complexed PVdF-HFP polymer electrolyte films. Polym Test 50:247–254. https://doi.org/10.1016/j.polymertesting.2016.01.023
Capiglia C, Saito Y, Kataoka H, Kodama T, Quartarone E, Mustarelli P (2000) Structure and transport properties of polymer gel electrolytes based on PVdF-HFP and LiN(C2F5SO2)2. Solid State Ion 131(3):291–299. https://doi.org/10.1016/S0167-2738(00)00678-0
Li W, Meng Q, Zheng Y, Zhang Z, Xia W, Xu Z (2010) Electric energy storage properties of poly(vinylidene fluoride). Appl Phys Lett 96(19):192905. https://doi.org/10.1063/1.3428656
Xu D, Su J, Jin J, Sun C, Ruan Y, Chen C, Wen Z (2019) In situ generated fireproof gel polymer electrolyte with Li6.4Ga0.2La3Zr2O12 as initiator and ion-conductive filler. Adv Energy Mater 9(25):1900611. https://doi.org/10.1002/aenm.201900611
Salimi A, Yousefi AA (2003) Analysis method: FTIR studies of β-phase crystal formation in stretched PVDF films. Polym Test 22(6):699–704. https://doi.org/10.1016/S0142-9418(03)00003-5
Yang Y, Wu Q, Wang D, Ma C, Chen Z, Zhu C, Gao Y, Li C (2020) Decoupling the mechanical strength and ionic conductivity of an ionogel polymer electrolyte for realizing thermally stable lithium-ion batteries. J Membr Sci 595:117549. https://doi.org/10.1016/j.memsci.2019.117549
Zhang M, Zuo Q, Wang L, Yu S, Mai Y, Zhou Y (2020) Poly(ionic liquid)-based polymer composites as high-performance solid-state electrolytes: benefiting from nanophase separation and alternating polymer architecture. Chem Commun 56(57):7929–7932. https://doi.org/10.1039/D0CC03281F
Fan J, Xiao Q, Fang Y, Li L, Feng W, Yuan W (2019) Reversible intercalation of 1-ethyl-3-methylimidazolium cations into MoS2 from a pure ionic liquid electrolyte for dual-ion cells. Chemelectrochem 6(3):676–683. https://doi.org/10.1002/celc.201801583
Li Z, Liu J, Li J, Kang F, Gao F (2018) A novel graphite-based dual ion battery using PP14NTF2 ionic liquid for preparing graphene structure. Carbon 138:52–60. https://doi.org/10.1016/j.carbon.2018.06.002
Li Z, Liu J, Niu B, Li J, Kang F (2018) A novel graphite–graphite dual ion battery using an AlCl3–[EMIm]Cl liquid electrolyte. Small 14(28):1800745. https://doi.org/10.1002/smll.201800745
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The present work was supported by the National Natural Science Foundation of China (grant no. 51764008).
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Yong Zeng: data curation, writing—original draft, and writing—reviewing and editing. Keliang Wang: formal analysis and resources. Xiang Ke: formal analysis and investigation. Xiaoqing Tan: visualization. Bo Jiang and Weichen Zhu: validation. Rengui Xiao: methodology, resources, and funding acquisition.
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Zeng, Y., Wang, K., Ke, X. et al. Study on ionic liquid-based gel polymer electrolytes for dual-graphite battery systems. Ionics 29, 1381–1393 (2023). https://doi.org/10.1007/s11581-023-04893-4
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DOI: https://doi.org/10.1007/s11581-023-04893-4