Abstract
A facile and simple solid phase method has been proposed to prepare SnO2 with SnSe as the precursor. The as-obtained powders were characterized by XRD, indicating that this material was almost pure SnO2. SEM and TEM images reveal that the microscopic morphology of SnO2 material was affected by the heating rates during the formation process of SnSe. The electrochemical performance of SnO2 as anode material for Li-ion batteries was investigated, which demonstrate that the as-prepared SnO2 at heating rate of 10 °C min−1 and packed by copper foil exhibits as high as 899.5 mAh g–1 initial charge capacity at a current density of 0.1 A g−1. Moreover, the SnO2 material shows a good rate performance, suggesting its promising application as anode material for Li-ion batteries.
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Sui YL, Zhou J, Wang XW, Wu L, Zhong SK, Li YG (2021) Recent advances in black– phosphorus–based materials for electrochemical energy storage. Mater Today 42:117–136
Nie Y, Xiao W, Miao C, Wang JL, Tan Y, Xu MB, Wang CJ (2021) Improving the structural stability of Ni–rich LiNi0.81Co0.15Al0.04O2 cathode materials with optimal content of trivalent Al ions doping for lithium ions batteries. Ceram Int 47:9717–9726
Liu YJ, Guo H, Zhang BH, Wen GY, Vajtai R, Wu L, Ajayan PM, Wang L (2020) Sustainable synthesis of N–doped hollow porous carbon spheres via a spray–drying method for lithium–sulfur storage with ultralong cycle life. Batter Supercaps 3:1201–1208
Qu XY, Yu ZL, Ruan DS, Dou AC, Su MR, Zhou Y, Liu YJ, Chu DW (2020) Enhanced electrochemical performance of Ni–rich cathode materials with Li1.3Al0.3Ti1.7(PO4)3 coating. ACS Sustain Chem Eng 8:5819–5830
Li MQ, Su AB, Qin QW, Qin Y, Dou AC, Zhou Y, Su MR, Liu YJ (2021) High–rate capability of columbite CuNb2O6 anode materials for lithium–ion batteries. Mater Lett 284:128915
Ma XH, Wei YY, Ding W, Zhou JF, Zi ZF, Dai JM (2017) Synthesis of MnO@multi–walled CNTs composite film electrodes for lithium–ion batteries by an improved electrostatic spray deposition method. J Alloys Compd 717:69–77
Ma BX, Ye YY, Qiao F, Qian MF, Cao X, Wei YY, Liu J, Sha ML, Zi ZF, Daibet JM (2020) Homogeneous MnO nanoparticles fabricated by electrostatic spray precipitation and lithium–storage performances. Scr Mater 187:76–81
Ma XH, Wei YY, Liang CH, Zi ZF, Zhou JH, Dai JM, Zhu XB (2017) Three–dimensional MnO/reduced graphite oxide composite films as anode materials for high performance lithium–ion batteries. Ceram Int 43:10873–10880
Ma XH, Cheng L, Li LL, Cao X, Ye YY, Wei YY, Wu YD, Sha ML, Zi ZF, Dai JM (2020) Influence of cut–off voltage on the lithium storage performance of Nb12W11O63 anode. Electrochim Acta 332:135380
Ma XH, Cao X, Ye YY, Qiao F, Qian MF, Wei YY, Wu YD, Zi ZF, Dai JM (2020) Study on low–temperature performances of Nb16W5O55 anode for lithium–ion batteries. Solid State Ionics 353:115376
Dong WJ, Xu JJ, Wang C, Lu Y, Liu XY, Wang X, Yuan XT, Wang Z, Lin TQ, Sui ML, Chen I-W, Huang FQ (2017) A robust and conductive black tin oxide nanostructure makes efficient lithium–ion batteries possible. Adv Mater 29:1700136
Xia SB, Li FS, Shen X, Li X, Cai XL, Liu JJ (2019) Heterostructural SnO/SnO2@C composite fabricated from tin–based coordination polymer as high–performance anode materials for lithium ion batteries. Matter Lett 251:94–97
Tian QH, Zhang F, Zhang W, Yang L (2019) Non–smooth carbon coating porous SnO2 quasi–nanocubes towards high lithium storage. Electrochim Acta 307:393–402
Jin RC, Meng YF, Li GH (2017) Multiwalled carbon nanotubes@C@SnO2 quantum dots and SnO2 quantum dots@C as high rate anode materials for lithium–ion batteries. Appl Surf Sci 423:476–483
Li HJ, Su QM, Kang JW, Huang M, Feng M, Feng HG, Huang P, Du GH (2018) Porous SnO2 hollow microspheres as anodes for high–performance lithium ion battery. Matter Lett 217:276–280
Saikia D, Deka JR, Chou CJ, Kao HM, Yang YC (2019) 3D interpenetrating cubic mesoporous carbon supported nanosized SnO2 as an efficient anode for high performance lithium–ion batteries. J Alloys Compd 791:892–904
Wang HM, Yan Y, Chen G (2019) The effects of confinement on TiO2@SnO2@TiO2 hollow spheres for high reversible lithium storage capacity. J Alloys Compd 778:375–381
Chang LM, Yi Z, Wang ZM, Wang LM, Cheng Y (2019) Ultrathin SnO2 nanosheets anchored on graphene with improved electrochemical kinetics for reversible lithium and sodium storage. Appl Surf Sci 484:646–654
Sun L, Si HC, Zhang YX, Shi Y, Wang K, Liu JG, Zhang YH (2019) Sn–SnO2 hybrid nanoclusters embedded in carbon nanotubes with enhanced electrochemical performance for advanced lithium ion batteries. J Power Sources 415:126–135
Yao WQ, Wu SB, Zhan L, Wang YL (2019) Two–dimensional porous carbon–coated sandwich–like mesoporous SnO2/graphene/mesoporous SnO2 nanosheets towards high–rate and long cycle life lithium–ion batteries. Chem Eng J 361:329–341
Hong ZM, Tian QH, Zhang W, Yang L (2019) The preparation of a new quasi–elliptic TiO2/SnO2/C composite and its lithium storage. Matter Lett 237:45–48
Yang J, Chen S, Tang JJ, Tian HY, Zhou XY (2018) The effect of passivation film in preparation 3D structural carbon paper/tin oxide@carbon as freestanding anode for lithium–ion batteries. Appl Surf Sci 435:203–209
Ngoc TM, Duy NV, Hung CM, Hoa ND, Nguyen H, Tonezzer M, Hieu NV (2019) Self–heated Ag–decorated SnO2 nanowires with low power consumption used as a predictive virtual multisensor for H2S–selective sensing. Anal Chim Acta 1069:108–116
Wu L, Zheng J, Wang L, Xiong XH, Shao Y, Wang G, Wang JH, Zhong SK, Wu MH (2019) PPy–encapsulated SnS2 nanosheets stabilized by defects on TiO2 support as durable anode material for lithium ion battery. Angew Chem Int Ed 58:811–815
Zhou XY, Huang B, Zou YL, Xie J, Yang J (2014) Cotton–templated fabrication of hierarchical SnO2 mesoporous microtubes as the anode material of lithium ion battery. Matter Lett 120:279–282
Liu R, Li D, Wang C, Li N, Li Q, Lu X, Spendelow JS, Wu G (2014) Core–shell structured hollow SnO2–polypyrrole nanocomposite anodes with enhanced cyclic performance for lithium–ion batteries. Nano Energy 6:73–81
Yu ZL, Qu XY, Dou AC, Zhou Y, Su MR, Liu YJ (2021) Carbon–coated cation–disordered rocksalt–type transition metal oxide composites for high energy Li–ion batteries. Ceram Int 47:1758–1765
Wang HJ, Jiang GW, Tan XJ, Liao JK, Yang X, Yuan R, Chai YQ (2018) Simple preparation of SnO2/C nanocomposites for lithium ion battery anode. Inorg Chem Commun 95:67–72
Wang F, Jiao HX, He EK, Yang SA, Chen YM, Zhao MS, Song XP (2016) Facile synthesis of ultrafine SnO2 nanoparticles embedded in carbon networks as a high–performance anode for lithium–ion batteries. J Power Sources 326:78–83
Han F, Li WC, Li MR, Lu AH (2012) Fabrication of superior–performance SnO2@C composites for lithium–ion anodes using tubular mesoporous carbon with thin carbon walls and high pore volume. J Mater Chem 22:9645–9651
Tian QH, Mao YN, Zhang XZ, Yang L (2018) Heterogeneous nanocrystals assembled TiO2/SnO2/C composite for improved lithium storage. Appl Surf Sci 447:408–415
Zhou X, Wan LJ, Guo YG (2013) Binding SnO2 nanocrystals in nitrogen–doped graphene sheets as anode materials for lithium–ion batteries. Adv Mater 25:2152–2157
Yuan S, Zhu YH, Li W (2016) Surfactant–free aqueous synthesis of pure single–crystalline SnSe nanosheet clusters as anode for high energy and power density sodium ion batteries. Adv Mater 29:27874214
Wang W, Zheng H, Liu Q (2017) Ultrathin Layered SnSe Nanoplates for Low Voltage, High–Rate, and Long–Life Alkali–Ion Batteries. Small 13:1702228
Chen JS, Cheah YL, Chen YT, Jayaprakash N, Lou XW (2009) SnO2 nanoparticles with controlled carbon nanocoating as high–capacity anode materials for lithium–ion batteries. J Phys Chem C 113:20504–20508
Narsimulu D, Nagaraju G, Sekhar SC (2021) Three–dimensional porous SnO2/carbon cloth electrodes for high–performance lithium and sodium ion batteries. Appl Surf Sci 538:148033
Park MS, Wang GX, Kang YM, Wexler D, Dou SX, Liu HK (2007) Preparation and electrochemical properties of SnO2 nanowires for application in lithium–ion batteries. Angew Chem Int Ed 46:750–753
Zhou D, Song WL, Fang LZ (2015) Hollow core–shell SnO2/C fibers as highly stable anodes for lithium–ion batteries. ACS Appl Mater Interfaces 7:21472–21478
Bard AJ, Faulkner LR (1980) Electrochemical methods. Wiley
Chen KF, Song SY, Xue DF (2015) Faceted Cu2O structures with enhanced Li–ion battery anode performances. Cryst Eng Comm 17:2110–2117
Park JC, Kim J, Kwon H, Song H (2009) Gram–scale synthesis of Cu2O nanocubes and subsequent oxidation to CuO hollow nanostructures for lithium–ion battery anode materials. Adv Mater 21:803–807
Acknowledgements
The project was sponsored by the Jiangsu Postdocroral Science Foundation (2020Z090), China Postdoctoral Science Foundation (2020M671361), National Natural Science Foundation of China (51774150, 51974137 and 52004103), and the Young talents training Program of Jiangsu university (2017).
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No conflict of interest exits in the submission of this manuscript, and manuscript is approved by all authors for publication. I would like to declare on behalf of my co-authors that the work described was original research that has not been published previously, and not under consideration for publication elsewhere, in whole or in part. All the authors listed have approved the manuscript that is enclosed.
All authors: Mingru su, Tian Gao, Shuai Liu, Ke Liu, Kai Fu, Aichun Dou, Yunjian Liu.
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Su, M., Gao, T., Zhu, G. et al. A facile fabrication of nanometer tetragonal rod–like SnO2 as anode for lithium ion batteries. Ionics 27, 4731–4737 (2021). https://doi.org/10.1007/s11581-021-04045-6
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DOI: https://doi.org/10.1007/s11581-021-04045-6