Abstract
Mesocarbon microbeads (MCMBs) have a unique structure consisting of graphite-like carbon crystallites covered by spherical surfaces. Their potential anode performance for sodium-ion batteries is investigated. The carbon crystallites in the MCMBs being prepared at 800 °C have a wider crystallites’ interlayer spacing (d = 0.347 nm) than graphite and are stacked by 5–6 graphene layers with an average crystal width of 3.18 nm. MCMBs present a reversible capacity of ~ 180 mAh g−1 and a coulombic efficiency of ~ 99% during 100 discharge/charge cycles. Their superior electrochemical performance is attributed to their unique structure. We propose that sodium is stored in MCMBs mainly by an intercalation mechanism. After sodium intercalation in carbon crystallites, the carbon atoms of graphene layers stack in an AABAA… type, and the sodium atoms exist between the layers of AA with a detected expanded interlayer spacing of 0.437 nm.
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References
Larcher D, Tarascon JM (2015) Towards greener and more sustainable batteries for electrical energy storage. Nat Chem 7(1):19–29
Palomares V, Serras P, Villaluenga I, Hueso KB, Gonzalez JC, Rojo T (2012) Na-ion batteries, recent advances and present challenges to become low cost energy storage systems. Energy Environ Sci 5(3):5884–5901
Slater MD, Kim D, Lee E, Johnson CS (2013) Sodium-ion batteries. Adv Funct Mater 23:947–958
Yabuuchi N, Kubota K, Dahbi M, Komaba S (2014) Research development on sodium-ion batteries. Chem Rev 114(23):11636–11682
Wang LP, Yu L, Wang X, Srinivasan M, Xu ZJ (2015) Recent developments in electrode materials for sodium-ion batteries. J Mater Chem A 3(18):9353–9378
Cao B, Liu H, Xu B, Lei Y, Chen X, Song H (2016) Mesoporous soft carbon as an anode material for sodium ion batteries with superior rate and cycling performance. J Mater Chem A 4(17):6472–6478
Hwang JY, Myung ST, Sun YK (2017) Sodium-ion batteries: present and future. Chem Soc Rev 46(12):3529–3614
Saurel D, Orayech B, Xiao B, Carriazo D, Li X, Rojo T (2018) From charge storage mechanism to performance: a roadmap toward high specific energy sodium-ion batteries through carbon anode optimization. Adv Energy Mater 8(17):1703268
Li Y, Lu Y, Adelhelm P, Titirici MM, Hu YS (2019) Intercalation chemistry of graphite: alkali metal ions and beyond. Chem Soc Rev 48(17):4655–4687
Wen Y, He K, Zhu Y, Han F, Xu Y, Matsuda I, Ishii Y, Cumings J, Wang C (2014) Expanded graphite as superior anode for sodium-ion batteries. Nat Commun 5:4033
Zhao J, Zou X, Zhu Y, Xu Y, Wang C (2016) Electrochemical intercalation of potassium into graphite. Adv Funct Mater 26:8103–8110
Cao Y, Xiao L, Sushko ML, Wang W, Schwenzer B, Xiao J, Nie Z, Saraf LV, Yang Z, Liu J (2012) Sodium ion insertion in hollow carbon nanowires for battery applications. Nano Lett 12:3783–3787
Brooks JD, Taylor GH (1965) Formation of graphitizing carbons from the liquid phase. Nature 206(4985):697–699
Sun S, Wang C, Chen M, Li M, Wang L (2014) A method to observe the structure of the interface between mesocarbon microbeads and pitch. J Colloid Interface Sci 426:206–208
Zhao D, Ru Q, Hu S, Hou X (2017) Design and synthesis of a novel 3D hierarchical mesocarbon microbead as anodes for lithium ion batteries and sodium ion batteries. Ionics 23:897–905
Tatsumi K, Iwashita N, Sakaebe H, Shioyama H, Higuchi S, Mabuchi A, Fujimoto H (1995) The influence of the graphitic structure on the electrochemical characteristics for the anode of secondary lithium batteries. J Electrochem Soc 142(3):716–720
Mabuchi A, Tokumitsu K, Fujimoto H, Kasuh T (1995) The influence of the graphitic structure on the electrochemical characteristics for the anode of secondary lithium batteries. J Electrochem Soc 142(4):1041–1046
Mabuchi A, Fujimoto H, Tokumitsu K, Kasuh T (1995) Charge-discharge mechanism of graphitized mesocarbon microbeads. J Electrochem Soc 142(9):3049–3051
Song LJ, Liu SS, Yu BJ, Wang CY, Li MW (2015) Anode performance of mesocarbon microbeads for sodium-ion batteries. Carbon 95:972–977
Stevens DA, Dahn JR (2001) The mechanisms of lithium and sodium insertion in carbon materials. J Electrochem Soc 148(8):A803–A811
Luo W, Jian Z, Xing Z, Wang W, Bommier C, Lerner MM, Ji X (2015) Electrochemically expandable soft carbon as anodes for Na-ion batteries. ACS Cent Sci 1(9):516–522
Stevens DA, Dahn JR (2000) High capacity anode materials for rechargeable sodium-ion batteries. J Electrochem Soc 147(4):1271–1273
Ponrouch A, Goňi AR, Palacín MR (2013) High capacity hard carbon anodes for sodium ion batteries in additive free electrolyte. Electrochem Commun 27:85–88
Bommier C, Luo W, Gao WY, Greaney A, Ma S, Ji X (2014) Predicting capacity of hard carbon anodes in sodium-ion batteries using porosity measurements. Carbon 76:165–174
Zhang B, Ghimbeu CM, Laberty C, Vix-Guterl C, Tarascon JM (2016) Correlation between microstructure and Na storage behavior in hard carbon. Adv Energy Mater 6:1501588
Alvin S, Yoon D, Chandra C, Cahyadi HS, Park JH, Chang W, Chung KY, Kim J (2019) Revealing sodium ion storage mechanism in hard carbon. Carbon 145:67–81
Zhu J, Chen C, Lu Y, Ge Y, Jiang H, Fu K, Zhang X (2015) Nitrogen-doped carbon nanofibers derived from polyacrylonitrile for use as anode material in sodium-ion batteries. Carbon 94:189–195
Tang K, Fu L, White RJ, Yu L, Titirici MM, Antonietti M, Maier J (2012) Hollow carbon nanospheres with superior rate capability for sodium-based batteries. Adv Energy Mater 2(7):873–877
Jiang Z, Alamgir M, Abraham KM (1995) The electrochemical intercalation of Li into graphite in Li/polymer electrolyte/graphite cells. J Electrchem Soc 142(2):333–340
Jache B, Adelhelm P (2014) Use of graphite as a highly reversible electrode with superior cycle life for sodium-ion batteries by making use of co-intercalation phenomena. Angew Chem Int Ed 53(38):10169–10173
Lin MC, Gong M, Lu B, Wu Y, Wang DY, Guan M, Angell M, Chen C, Yang J, Hwang BJ, Dai H (2015) An ultrafast rechargeable aluminum-ion battery. Nature 520(7547):325–328
Petkov V, Timmons A, Camardese J, Ren Y (2011) Li insertion in ball-milled graphitic carbon studied by total x-ray diffraction. J Phys Condens Matter 23:435003
Dresselhaus MS, Dresselhaus G (1981) Intercalation compounds of graphite. Adv Phys 30(2):139–326
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Wang, JX., Zhang, YP., Guo, Y. et al. Mesocarbon microbeads with superior anode performance for sodium-ion batteries. Ionics 27, 677–682 (2021). https://doi.org/10.1007/s11581-020-03835-8
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DOI: https://doi.org/10.1007/s11581-020-03835-8