Abstract
Herein, core-shell carbon sphere@nickel oxide (Cs@NiO) composites were fabricated by a facile hydrothermal method followed by calcination. The resultant Cs@NiO composites are composed of randomly distributed NiO nanoneedles coated on carbon sphere surfaces, which exhibit the rambutan-like structure. As electrode materials for supercapacitor, the core-shell Cs@NiO delivers a high specific capacitance of 555 F/g at the current density of 1 A/g, and an outstanding rate capability of about 85.6% capacity retention from 1 to 10 A/g. Meanwhile, the capacitance degradation is only 5% after 1000 continuous charge-discharge cycles with a current density of 10 A/g. These excellent electrochemical performances can be attributed to the enhanced electronic conductivity, the improved surface activity and the facilitated charge transportation during charging and discharging process, which are caused by the introduction of carbon sphere and the appropriate structure, respectively.
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References
Westover AS, Tian JW, Bernath S, Oakes L, Edwards R, Shabab FN, Chatterjee S, Anilkumar AV, Pint CL (2014) A multifunctional load-bearing solid-state supercapacitor. Nano Lett 14:3197–3202
Wang R, Xu C, Lee JM (2016) High performance asymmetric supercapacitors: New NiOOH nanosheet/graphene hydrogels and pure graphene hydrogels. Nano Energy 19:210–221
Wang XF, Yin YJ, Hao CL, You Z (2015) A high-performance three-dimensional micro supercapacitor based on ripple-like ruthenium oxide-carbon nanotube composite films. Carbon 82:436–445
Gao Z, Yang W, Wang J, Song N, Li X (2015) Flexible all-solid-state hierarchical NiCo2O4/porous graphene paper asymmetric supercapacitors with an exceptional combination of electrochemical properties. Nano Energy 13:306–317
Zhu YG, Wang Y, Shi YM, Wong JI, Yang HY (2014) CoO nanoflowers woven by CNT network for high energy density flexible micro-supercapacitor. Nano Energy 3:46–54
Teng S, Siegel G, Wang W, Tiwariz A (2014) Carbonized wood for supercapacitor electrodes. ECS Solid State Lett 3:M25–M28
Zhao YQ, Lu M, Tao PY, Zhang YJ, Gong XT, Yang Z, Zhan g GQ, Li HL (2016) Hierarchically porous and heteroatom doped carbon derived from tobacco rods for supercapacitors. J Power Sources 307:391-400.
Zhang Y, Wang J, Wei H, Hao J, Mu J, Cao P, Wang J, Zhao S (2016) Hydrothermal synthesis of hierarchical mesoporous NiO nanourchins and their supercapacitor application. Mater Lett 162:67–70
Han D, Xu P, Jing X, Wang J, Yang P, Shen Q, Liu J, Song D, Gao Z, Zhang M (2013) Trisodium citrate assisted synthesis of hierarchical NiO nanospheres with improved supercapacitor performance. J Power Sources 235:45–53
Cao F, Pan GX, Xia XH, Tang PS, Chen HF (2014) Synthesis of hierarchical porous NiO nanotube arrays for supercapacitor application. J Power Sources 264:161–167
Han D, Xu P, Jing X, Wang J, Song D, Liu J, Zhang M (2013) Facile approach to prepare hollow core–shell NiO microspherers for supercapacitor electrodes. J Solid State Chem 203:60–67
Li Q, Liang CL, Lu XF, Tong YX, Li GR (2015) Ni@NiO core-shell nanoparticle tube arrays with enhanced supercapacitor performance. J Mater Chem A 3:6432–6439
Zhao B, Zhuang H, Fang T, Jiao Z, Liu R, Ling X, Lu B, Jiang Y (2014) Selfassembly of NiO/graphene with three-dimension hierarchical structure as high performance electrode material for supercapacitors. J Alloy Compound 597:291–298
Yi H, Wang HW, Jing YT, Peng TQ, Wang XF (2015) Asymmetric supercapacitors based on carbon nanotubes@NiO ultrathin nanosheets core-shell composites and MOF-derived porous carbon polyhedrons with super-long cycle life. J Power Sources 285:281–290
Pan Y, Mei Z, Yang Z, Zhang W, Pei B, Yao H (2014) Facile synthesis of mesoporous MnO2/C spheres for supercapacitor electrodes. Chem Eng J 242:397–403
Zhang S, Hu R, Dai P, Yu X, Ding Z, Wu M, Li G, Ma Y, Tu C (2017) Synthesis of rambutan-like MoS2/mesoporous carbon spheres nanocomposites with excellent performance for supercapacitors. Appl Surf Sci 396:994–999
Tang S, Tang Y, Vongehr S, Zhao X, Meng X (2009) Nanoporous carbon spheres and their application in dispersing silver nanoparticles. Appl Surf Sci 255:6011–6016
Jahromi SP, Pandikumar A, Goh BT, Lim YS, Basirun WJ, Lim HN, Huang NM (2015) Influence of particle size on performance of a nickel oxide nanoparticlebased supercapacitor. RSC Adv 5:14010–14019
Zhang J, Zeng D, Zhao S, Wu J, Xu K, Zhu Q, Zhang G, Xie C (2015) Room temperature NO2 sensing: what advantage does the rGO-NiO nanocomposite have over pristine NiO? Phys Chem Chem Phys 17:14903–14911
Zhang H, Guo D, Zhu J, Li Q, Chen L, Wang T (2015) A layer-by-layer deposition strategy of fabricating NiO@rGO composites for advanced electrochemical capacitors. Electrochim Acta 152:378–382
Zang L, Zhu JY, Xia YC (2014) Facile synthesis of porous NiO nanofibers for high-performance supercapacitors. J Mater Eng Perform 23:679–683
Zhang H, Kuila T, Kim NH, Yu DS, Lee JH (2014) Simultaneous reduction, exfoliation, and nitrogen doping of graphene oxide via a hydrothermal reaction for energy storage electrode materials. Carbon 69:66–78
Zhu YQ, Guo HZ, Wu Y, Cao CB, Tao S, Wu ZY (2014) Surface-enabled superior lithium storage of high-quality ultrathin NiO nanosheets. J Mater Chem A 2:7904–7911
Chen G, Guan H, Dong CJ, Xiao XC, Wang YD (2016) Effect of calcination temperatures on the electrochemical performances of nickel oxide/reduction graphene oxide (NiO/RGO) composites synthesized by hydrothermal method. J Phys Chem Solids 98:209–219
Yao M, Hu Z. Xu Z, Liu Y, Liu P, Zhang Q (2015) Template synthesis and characterization of nanostructured hierarchical mesoporous ribbon-like NiO as high performance electrode material for supercapacitor. Electrochim Acta 158:96-104.
Deng P, Zhang H, Chen Y, Li Z, Huang Z, Xu X, Li Y, Shi Z (2015) Facile fabrication of graphene/nickel oxide composite with superior supercapacitance performance by using alcohols-reduced graphene as substrate. J Alloy Compound 644:165–171
Feng X, Zhou J, Wang L, Li Y, Huang Z, Chen S, Ma Y, Wang L, Yan X (2015) Synthesis of shape-controlled NiO-graphene nanocomposites with enhanced supercapacitive properties. New J Chem 39:4026–4034
Liu W, Lu C, Wang X, Liang K, Tay BK (2015) In situ fabrication of threedimensional, ultrathin graphitae/carbon nanotube/NiO composite as binder-free electrode for high-performance energy storage. J Mater Chem A 3:624–633
Lu XF, Lin J, Huang ZX, Li GR (2015) Three-dimensional nickel oxide@carbon hollow hybrid networks with enhanced performance for electrochemical energy storage. Electrochim Acta 161:236–244
Madhu R, Veeramani V, Chen SM, Veerakumar P, Liu SB (2015) Functional porous carbon/nickel oxide nanocomposites as binder-free electrodes for supercapacitors. Chem Eur J 21:8200–8206
Wang X, Wang X, Yi L, Liu L, Dai Y, Wu H (2013) Preparation and capacitive properties of the core–shell structure carbon aerogel microbeads-nanowhiskerlike NiO composites. J Power Sources 224:317–323
Zeng W, Zhang GH, Hou SC, Wang TH, Duan HG (2015) Facile synthesis of graphene@NiO/MoO3 composite nanosheet arrays for high-performance supercapacitors. Electrochim Acta 151:510–516
Acknowledgements
This work was financially supported by the Application Basic Research Fund of Yunnan Province (grant no. 2014FB110) and the National Natural Science Foundation of China (grant nos. 11564042 and 11464049).
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Chen, G., Guan, H., Dong, C. et al. Synthesis of core-shell carbon sphere@nickel oxide composites and their application for supercapacitors. Ionics 24, 513–521 (2018). https://doi.org/10.1007/s11581-017-2204-9
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DOI: https://doi.org/10.1007/s11581-017-2204-9