Abstract
Agar as a natural polymer is used to prepare quasi-solid-state polymer electrolytes (QSPEs). Two different iodide salts namely sodium iodide (NaI) and potassium iodide (KI) are incorporated. To enhance the ionic conductivity of the QSPE system, 1-methyl-3-propylimidazolium iodide (MPII) ionic liquid is added. The highest ionic conductivity of 1.48 × 10−3 S cm−1 was achieved after addition of 50 wt.% of KI and 3.0 g of MPII ionic liquid. QSPEs are studied for temperature-dependent ionic conductivity behavior. QSPEs are studied for structural properties using Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The structural studies revealed that the complexation between agar polymer, iodide salts, and MPII ionic liquid has occurred. QSPEs are sandwiched between counter and working electrodes to fabricated DSSC and analyzed under sun simulator. The highest efficiency of 2.16% is achieved with incorporation of 3.0 g MPII ionic liquid.
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References
Grätzel M (2006) The advent of mesoscopic injection solar cells. Prog Photovolt Res Appl 14(5):429–442
El Chaar L, Lamont LA, El Zein N (2011) Review of photovoltaic technologies. Renew Sust Energ Rev 15(5):2165–2175
Aziz MF, Buraidah MH, Careem MA, Arof AK (2015) PVA based gel polymer electrolytes with mixed iodide salts (K + I- and Bu4N + I-) for dye-sensitized solar cell application. Electrochim Acta 182:217–223
Khanmirzaei MH, Ramesh S, Ramesh K (2015) Hydroxypropyl cellulose based non-volatile gel polymer electrolytes for dye-sensitized solar cell applications using 1-methyl-3-propylimidazolium iodide ionic liquid. Sci Rep 5:18056
Khanmirzaei MH, Ramesh S, Ramesh K (2015) Polymer electrolyte based dye-sensitized solar cell with rice starch and 1-methyl-3-propylimidazolium iodide ionic liquid. Mater Des 85:833–837
Lee JH, Park CH, Jung JP, Kim JH (2015) Worm-like mesoporous TiO2 thin films templated using comb copolymer for dye-sensitized solar cells with polymer electrolyte. J Power Sources 298:14–22
Wei W, Song D, Kang YS (2015) Stepwise cosensitization for high efficiency dye-sensitized solar cells utilizing solid-state polymer electrolytes. Mater Lett 161:435–438
He R, Echeverri M, Ward D, Zhu Y, Kyu T (2016) Highly conductive solvent-free polymer electrolyte membrane for lithium-ion batteries: effect of prepolymer molecular weight. J Membr Sci 498:208–217
Kuo P-L, Tsao C-H, Hsu C-H, Chen S-T, Hsu H-M (2016) A new strategy for preparing oligomeric ionic liquid gel polymer electrolytes for high-performance and nonflammable lithium ion batteries. J Membr Sci 499:462–469
Sivaraman P, Shashidhara K, Thakur AP, Samui AB, Bhattacharyya AR (2015) Nanocomposite solid polymer electrolytes based on polyethylene oxide, modified nanoclay, and tetraethylammonium tetrafluoroborate for application in solid-state supercapacitor. Polym Eng Sci 55(7):1536–1545
Yang L, Hu J, Lei G, Liu H (2014) Ionic liquid-gelled polyvinylidene fluoride/polyvinyl acetate polymer electrolyte for solid supercapacitor. Chem Eng J 258:320–326
Patru A, Rabis A, Temmel SE, Kotz R, Schmidt TJ (2016) Pt/IrO2 TiO2 cathode catalyst for low temperature polymer electrolyte fuel cell application in MEAs, performance and stability issues. Catal Today 262:161–169
Sasikala S, Selvaganesh SV, Sahu AK, Carbone A, Passalacqua E (2016) Block co-polymer templated mesoporous carbon-Nafion hybrid membranes for polymer electrolyte fuel cells under reduced relative humidity. J Membr Sci 499:503–514
Khanmirzaei MH, Ramesh S, Ramesh K (2015) Effect of different iodide salts on ionic conductivity and structural and thermal behavior of rice-starch-based polymer electrolytes for dye-sensitized solar cell application. Ionics 21(8):2383–2391
Ng HM, Ramesh S, Ramesh K (2015) Efficiency improvement by incorporating 1-methyl-3-propylimidazolium iodide ionic liquid in gel polymer electrolytes for dye-sensitized solar cells. Electrochim Acta 175:169–175
Rahman MYA, Ahmad A, Umar AA, Taslim R, Su’ait MS, Salleh MM (2014) Polymer electrolyte for photoelectrochemical cell and dye-sensitized solar cell: a brief review. Ionics 20(9):1201–1205
Leones RFS, Rodrigues LC, Marrucho IM, Esperanca JMSS, Pawlicka A, Silva MM (2012) Investigation of polymer electrolyte based on agar and ionic liquids. Express Polym Lett 6(12):1007–1016
Koh JH, Ahmad Z, Mohamad A (2012) Bacto agar-based gel polymer electrolyte. Ionics 18(4):359–364
Rajendran S, Babu R, Usha Rani M (2011) Effect of complexing salt on conductivity of PVC/PEO polymer blend electrolytes. Bull Mater Sci 34(7):1525–1530
Tambelli CC, Bloise AC, Rosário AV, Pereira EC, Magon CJ, Donoso JP (2002) Characterisation of PEO–Al2O3 composite polymer electrolytes. Electrochim Acta 47(11):1677–1682
Pitawala HMJC, Dissanayake MAKL, Seneviratne VA (2007) Combined effect of Al2O3 nano-fillers and EC plasticizer on ionic conductivity enhancement in the solid polymer electrolyte (PEO)9LiTf. Solid State Ionics 178(13–14):885–888
Klongkan S, Pumchusak J (2015) Effects of Nano alumina and plasticizers on morphology, ionic conductivity, thermal and mechanical properties of PEO-LiCF3SO3 solid polymer electrolyte. Electrochim Acta 161:171–176
Kaya S, Kaya C (2015) A simple method for the calculation of lattice energies of inorganic ionic crystals based on the chemical hardness. Inorg Chem 54(17):8207–8213
Freitas FS, JND F, Ito BI, M-AD P, Nogueira AF (2009) Electrochemical and structural characterization of polymer gel electrolytes based on a PEO copolymer and an imidazolium-based ionic liquid for dye-sensitized solar cells. Acs Appl Mater Inter 1(12):2870–2877
Campbell JLE, Johnson KE (1993) Speciation of the proton in ambient-temperature molten-salts. Inorg Chem 32(18):3809–3815
Yang Y, Gao J, Yi P, Cui J, Guo X (2015) The influence of Co3O4 concentration on quasi-solid state dye-sensitized solar cells with polymer electrolyte. Solid State Ionics 279:1–5
Buraidah MH, Teo LP, Yong CMA, Shah S, Arof AK (2016) Performance of polymer electrolyte based on chitosan blended with poly(ethylene oxide) for plasmonic dye-sensitized solar cell. Opt Mater 57:202–211
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This work was supported by the Fundamental Research Grant Scheme (FP012-2015A) from Ministry of Education, Malaysia, University of Malaya.
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Nadia, S.R., Khanmirzaei, M.H., Ramesh, S. et al. Quasi-solid-state agar-based polymer electrolytes for dye-sensitized solar cell applications using imidazolium-based ionic liquid. Ionics 23, 1585–1590 (2017). https://doi.org/10.1007/s11581-016-1946-0
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DOI: https://doi.org/10.1007/s11581-016-1946-0