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Almond shell-based activated nanoporous carbon electrode for EDLCs

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Abstract

Almond shell-based chemically treated and activated nanoporous charcoal powder (AS(T)) has been successfully prepared by chemical activation method using potassium hydroxide (KOH) as an activating agent. The as-synthesized AS(T) was systematically characterized by various techniques like N2 adsorption, scanning electron microscopy (SEM), X-ray diffraction, and thermogravimetric analysis. The AS(T)-based nanoporous activated charcoal is tested as an electrode material with ionic liquid-based polymer gel electrolyte for electrochemical double-layer capacitors (EDLCs). EDLCs prepared from AS(T) exhibit specific capacitance of 986.3 mF cm−2 (equivalent to single-electrode specific capacitance of 563.6 F g−1). The energy density of 62.8 Wh kg−1 and power density of 2.1 kW kg−1 have been observed for nanoporous AS(T)-based EDLCs.

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Acknowledgments

The authors are grateful to the Madhya Pradesh Council of Science and Technology, Madhya Pradesh, India, for providing financial support through Grant-in-Aid for Scientific Research vide sanction no. 3683/CST/R&D/Phy & Engg. Sc/2012, Bhopal (dated: 03.11.2012). The authors are also thankful to Rakesh Srivastava, HEG, India; Dr. S.A. Hashmi, University of Delhi, India; and Dr. O.P. Modi, AMPRI, India, for providing SEM, BET, TGA, and XRD results.

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Correspondence to S. K. Tripathi.

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Jain, A., Tripathi, S.K. Almond shell-based activated nanoporous carbon electrode for EDLCs. Ionics 21, 1391–1398 (2015). https://doi.org/10.1007/s11581-014-1282-1

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  • DOI: https://doi.org/10.1007/s11581-014-1282-1

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