Abstract
Organic and carbon-based lithium-ion batteries possess abundant resources, nontoxicity, environmental friendliness, and high performance, and they have been widely studied in the past decades. However, it remains a challenge to construct such batteries with high capacity, high cycling stability, and high conductivity simultaneously. Here, we elaborately design and integrate organic polymer (p-FcPZ) with graphene network to create a hybrid material (p-FcPZ@G) for high-performance lithium-ion batteries (LIBs). The bi-polar polymer p-FcPZ containing multiple redox-active sites endows p-FcPZ@G with both remarkable cycling stability and high capacity. The porous conductive graphene network with a large surface area facilitates rapid ions/electrons transportation, resulting in superior rate performance. Therefore, the half-cell based on p-FcPZ@G cathode exhibits simultaneously high capacity (∼250 mA h g−1 at 50 mA g−1), excellent cycling stability (retention of 99.999% per cycle for 10,000 cycles at 2,000 mA g−1) and superior rate performance. Additionally, the graphene-based full cell assembled with p-FcPZ@G cathode and graphene anode also demonstrates comprehensively high electrochemical performance.
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This work was supported by the National Natural Science Foundation of China (52090034), the Ministry of Science and Technology of China (2020YFA0711500), and the Higher Education Discipline Innovation Project (B12015).
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Zhao, Y., Ni, M., Xu, N. et al. High-performance lithium-ion batteries based on polymer/graphene hybrid cathode material. Sci. China Chem. 66, 2683–2689 (2023). https://doi.org/10.1007/s11426-023-1681-x
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DOI: https://doi.org/10.1007/s11426-023-1681-x