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Progress in organocatalytic asymmetric (4+3) cycloadditions for the enantioselective construction of seven-membered rings

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Abstract

Chiral seven-membered ring systems such as seven-membered carbocycles and heterocycles are widely found in natural products and pharmaceuticals. Therefore, the catalytic enantioselective construction of such frameworks has evoked considerable interest in the field of chemistry. Among the various approaches, organocatalytic asymmetric (4+3) cycloadditions are highly effective for the enantioselective construction of seven-membered rings. Over the past two decades, substantial efforts have been devoted to this field and chemists have developed various organocatalytic asymmetric (4+3) cycloadditions. This review summarizes the progress in organocatalytic asymmetric (4+3) cycloadditions from 2003 to early 2022 and provides insights into challenging issues faced in this research field, enabling the future development of this field.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (22125104, 21831007), the Natural Science Foundation of Jiangsu Province (BK20210916), and the High Education Natural Science Foundation of Jiangsu Province (21KJB150009).

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Authors and Affiliations

  1. Research Center of Chiral Functional Heterocycles, School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou, 221116, China

    Wei Tan, Jia-Yi Zhang, Cong-Hui Gao & Feng Shi

  2. School of Petrochemical Engineering, Changzhou University, Changzhou, 213164, China

    Feng Shi

  3. School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, 453007, China

    Feng Shi

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  1. Wei Tan
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  2. Jia-Yi Zhang
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  3. Cong-Hui Gao
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  4. Feng Shi
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Tan, W., Zhang, JY., Gao, CH. et al. Progress in organocatalytic asymmetric (4+3) cycloadditions for the enantioselective construction of seven-membered rings. Sci. China Chem. 66, 966–992 (2023). https://doi.org/10.1007/s11426-022-1471-2

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