Skip to main content
SpringerLink
Log in

Synthesis and characterization of dendronized hyperbranched polymers through the “A3+B2” approach

  • Articles
  • Published:
Science China Chemistry Aims and scope Submit manuscript

Abstract

Dendronized hyperbranched polymer (DHP) is a new kind of polymer, which combines the advantages of dendrimers and hyperbranched polymers. In this work, two dendronized hyperbranched polymers, DHPG0 and DHPG1, were successfully prepared through the simple “A3+B2” type Sonogashira coupling reaction. The nonlinear optical (NLO) effects of DHPG0 and DHPG1, characterized by the d 33 values, were 183 and 220 pm V–1 respectively, higher than those of their analogues of dendronized polymers and dendrimers, thanks to the special topological structure. Also, the obtained polymers displayed excellent solubility, good processability, and high thermal stability.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Burland MD, Miller RD, Walsh CA. Chem Rev, 1994, 94: 31–75

    Article  CAS  Google Scholar 

  2. Marder SR, Kippelen B, Jen AKY, Peyghambarian N. Nature, 1997, 388: 845–851

    Article  CAS  Google Scholar 

  3. Lee M, Katz HE, Erben C, Gill DM, Gopalan P, Heber JD, Mc Gee DJ. Science, 2002, 298: 1401–1403

    Article  CAS  Google Scholar 

  4. Dalton LR, Sullivan PA, Bale DH. Chem Rev, 2010, 110: 25–55

    Article  CAS  Google Scholar 

  5. Shi Y, Zhang C, Zhang H, Bechtel JH, Dalton LR, Robinson BH, Steier WH. Science, 2000, 288: 119–122

    Article  CAS  Google Scholar 

  6. Mclaughlin CV, Hayden M, Polishak B, Huang S, Luo JD, Kim TD, Jen AKY. Appl Phys Lett, 2008, 92: 151107

    Article  Google Scholar 

  7. Luo JD, Zhou XH, Jen AKY. J Mater Chem, 2009, 19: 7410–7424

    Article  CAS  Google Scholar 

  8. Li Z, Li QQ, Qin JG. Polym Chem, 2011, 2: 2723–2740

    Article  CAS  Google Scholar 

  9. Wu WB, Qin JG, Li Z. Polymer, 2013, 54: 4351–4382

    Article  CAS  Google Scholar 

  10. Robinson BH, Dalton LR. J Phys Chem A, 2000, 104: 4785–4795

    Article  CAS  Google Scholar 

  11. Robinson BH, Dalton LR, Harper HW, Ren A, Wang F, Zhang C, Todorova G, Lee M, Aniszfeld R, Garner S, Chen A, Steier WH, Houbrecht S, Persoons A, Ledoux I, Zyss J, Jen AKY. Chem Phys, 1999, 245: 35–50

    Article  CAS  Google Scholar 

  12. Dalton LR, Steier WH, Robinson BH, Zhang C, Ren A, Garner S, Chen A, Londergan T, Irwin L, Carlson B, Fifield L, Phelan G, Kincaid C, Amend J, Jen AKY. J Mater Chem, 1999, 9: 1905–1920

    Article  CAS  Google Scholar 

  13. Li Z, Li Z, Di C, Zhu ZC, Li QQ, Zeng Q, Zhang K, Liu YQ, Ye C, Qin JG. Macromolecules, 2006, 39: 6951–6961

    Article  CAS  Google Scholar 

  14. Zeng Q, Li Z, Li Z, Ye C, Qin JG, Tang BZ. Macromolecules, 2007, 40: 5634–5637

    Article  CAS  Google Scholar 

  15. Li QQ, Li Z, Zeng FX, Gong W, Li Z, Zhu ZC, Zeng Q, Yu SS, Ye C, Qin JG. J Phys Chem B, 2007, 111: 508–514

    Article  CAS  Google Scholar 

  16. Wu WB, Ye C, Qin JG, Li Z. Chem Asian J, 2013, 8: 1836–1846

    Article  CAS  Google Scholar 

  17. Wu WB, Huang LJ, Xiao L, Huang Q, Tang RL, Ye C, Qin JG, Li Z. RSC Adv, 2012, 2: 6520–6526

    Article  CAS  Google Scholar 

  18. Kim TD, Kang JW, Luo JD, Jang SH, Ka JW, Tucker N, Benedict JB, Dalton LR, Gray T, Overney RM, Park DH, Herman WN, Jen AKY. J Am Chem Soc, 2007, 129: 488–489

    Article  CAS  Google Scholar 

  19. Gray T, Kim TD, Knorr DB Jr, Luo JD, Jen AKY, Overney RM. Nano Lett, 2008, 8: 754–759

    Article  CAS  Google Scholar 

  20. Chen CF. Sci China Chem, 2015, 58: 1089

    Article  CAS  Google Scholar 

  21. Zhang JX, Wang GW. Sci China Chem, 2015, 58: 1674–1694

    Article  CAS  Google Scholar 

  22. Wang RB, Yuan WZ, Zhu XY. Chin J Polym Sci, 2015, 33: 680–687

    Article  CAS  Google Scholar 

  23. Wu WB, Tang RL, Li QQ, Li Z. Chem Soc Rev, 2015, 44: 3997–4022

    Article  CAS  Google Scholar 

  24. Walter MV, Malkoch M. Chem Soc Rev, 2012, 41: 4593–4609

    Article  CAS  Google Scholar 

  25. Li WS, Aida T. Chem Rev, 2009, 109: 6047–6076

    Article  CAS  Google Scholar 

  26. Helms B, Meijer EW. Science, 2006, 313: 929–930

    Article  CAS  Google Scholar 

  27. Boas U, Heegaard PMH. Chem Soc Rev, 2004, 33: 43–63

    Article  CAS  Google Scholar 

  28. Wu WB, Huang LJ, Fu YJ, Ye C, Qin JG, Li Z. Chin Sci Bull, 2013, 58: 2753–2761

    Article  CAS  Google Scholar 

  29. Wu WB, Zhen X, Li Z. J Mater Chem C, 2014, 2: 8122–8130

    Article  CAS  Google Scholar 

  30. Wu WB, Wang ZP, Xiao R, Xu Z, Li Z. Polym Chem, 2015, 6: 4396–4403

    Article  CAS  Google Scholar 

  31. Tang RL, Chen H, Zhou SM, Xiang WD, Tang X, Liu BW, Dong YQ, Zeng HY, Li Z. Polym Chem, 2015, 6: 5580–5589

    Article  CAS  Google Scholar 

  32. Yin XY, Tang RL, Li QQ, Li Z. Sci Sin Chim, 2016, 46: 429–437

    Google Scholar 

  33. Li Z, Wu WB, Ye C, Qin JG, Li Z. Polymer, 2012, 53: 153–160

    Article  Google Scholar 

  34. Li Z, Wu WB, Li QQ, Yu G, Xiao L, Liu YQ, Ye C, Qin JG, Li Z. Angew Chem Int Ed, 2010, 122: 2823–2827

    Article  Google Scholar 

  35. Miao XP, Guo YS, He LF, Meng Y, Li XY. Chin J Polym Sci, 2015, 33: 1574–1585

    Article  CAS  Google Scholar 

  36. Yan DY. Sci China Chem, 2015, 58: 835–838

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Wuhan University, Wuhan, 430072, China

    Guangchao Liu, Pengyu Chen, Runli Tang & Zhen Li

Authors
  1. Guangchao Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Pengyu Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Runli Tang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zhen Li
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Zhen Li.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, G., Chen, P., Tang, R. et al. Synthesis and characterization of dendronized hyperbranched polymers through the “A3+B2” approach. Sci. China Chem. 59, 1561–1567 (2016). https://doi.org/10.1007/s11426-016-0250-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11426-016-0250-5

Keywords

Search

Navigation