Abstract
Purpose
The remediation of diesel-contaminated hydrophobic soil is difficult due to the inability of aqueous phase remedial agents to infiltrate the soil. This novel laboratory study enhanced the gravity-driven infiltration of water and oxidant solution into the hydrophobic soil by pretreatment. For this purpose, the hydrophobic soil was pretreated (partially liquid saturating) using 0.1% sodium hexa-metaphosphate (Na-HMP) and 0.5% alpha olefin sulfonate (AOS).
Methods
The diesel-contaminated soil (34,167 ± 560 mg TPH/kg) was partially saturated with 0.5 pore volumes of Na-HMP and surfactant mixture solution. The infiltration experiment of the pretreated soil was conducted by pouring a solution (water/oxidant) provided from the Marriott reservoir over the digital balance.
Results and discussion
This study did not observe any natural infiltration of water or oxidant reagent into the diesel-contaminated soil. After the pretreatment, the cumulative infiltration of water to the pretreated soil increased to 5.17 cm after 40 min. The natural infiltration occurred due to the dispersion of soil particles and reduction of hydrophobicity by the Na-HMP and AOS, respectively. Widened soil pores were observed after pretreatment using the scanning electron microscopy (SEM) analysis. The infiltration of 5% Na2S2O8 solution was 5.80 cm after 40 min when the diesel-contaminated soil was pretreated with 0.1% Na-HMP and 0.5% AOS.
Conclusions
Pretreatment using Na-HMP and AOS can enhance the remediation of highly hydrophobic and low-permeability soils. This finding can provide an insight into enhancing the soil remediation efficiency by increasing the gravity-driven uniform delivery of the remediation agent into the undisturbed soil.
Graphical abstract
We’re sorry, something doesn't seem to be working properly.
Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.
Data availability
The datasets generated and/or analyzed during the current study are available from the corresponding author on reasonable request.
Abbreviations
- TPH:
-
Total petroleum hydrocarbon
- AOS:
-
Sodium alpha olefin sulfonate (surfactant)
- Na-HMP:
-
Sodium hexa-metaphosphate
- PV:
-
Pore volume
- CEC:
-
Cation exchange capacity
- SEM:
-
Scanning electron microscopy
- DCM:
-
Dichloromethane
- GC-FID:
-
Gas chromatography-flame ionization detector
- ISCO:
-
In situ chemical oxidation
- CMC:
-
Critical micelle concentration
- PS:
-
Sodium persulfate
- R:
-
Alkyl group of an organic molecule
References
Adams RH, Cerecedo-Lo’pez RA, Alejandro-A’lvarez LA, Dominguez-Rodriguez VI, Nieber JL (2016) Treatment of water-repellent petroleum-contaminated soil from Bemidji, Minnesota, by alkaline desorption. Int J Environ Sci Technol 13:2249–2260
Aeppli C, Swarthout RF, O’Neil GW, Katz SD, Nabi D, Ward CP, Nelson RK, Sharpless CM, Reddy CM (2018) How persistent and bioavailable are oxygenated Deepwater horizon oil transformation products? Environ Sci Technol 52(13):7250–7258
Andreola F, Castellini E, Manfredini T, Romagnoli M (2004) The role of sodium hexametaphosphate in the dissolution process of kaolinite and kaolin. J Eur Ceram Soc 24:2113–2124
Andreola F, Castellini E, Lusvardi G, Menabue L, Romania M (2007) Release of ions from kaolinite dispersed in deflocculant solutions. Appl Clay Sci 36(4):271–278
ASTM (2007) Standard test method for particle size analysis of soils, D 422–63, West Conshohocken, USA
Bajagain R, Park Y, Jeong S-W (2018) Feasibility of oxidation-biodegradation serial foam spraying for total petroleum hydrocarbon removal without soil disturbance. Sci Total Environ 626:1236–1242
Bajagain R, Gautam P, Jeong S-W (2019) Degradation of petroleum hydrocarbons in unsaturated soil and effects on subsequent biodegradation by potassium permanganate. Environ Geochem Health 42:1705–1714
Bajagain R, Gautam P, Jeong S-W (2020) Biodegradation and post-oxidation of fuel-weathered field soil Sci Total Environ 139452
Bennett JM, Marchuk A, Marchuk S, Raine S (2019) Towards predicting the soil-specific threshold electrolyte concentration of soil as a reduction in saturated hydraulic conductivity: the role of clay net negative charge. Geoderma 337:122–131
Besha AT, Bekele DN, Naidu R, Chadalavada S (2018) Recent advances in surfactant-enhanced in situ chemical oxidation for the remediation of non-aqueous phase liquid contaminated soils and aquifers. Environ Technol Innov 9:303–322
Borselli L, Camicelli S, Fermi GA, Pagliai M, Lucamante G (1996) Effects of gypsum on hydrological, mechanical and porosity properties of a kaolinitic crusting soil. Soil Technol 9:39–54
Burghal AA (2015) Isolation and identification of actinomycetes strains from oil refinery contaminated soil, Basrah-Iraq. Int J Innov Eng Technol 5(2):20–27
Chattopadhyay P, Karthick RA (2017) Characterization and application of surfactant foams produced from ethanol-sodium lauryl sulfate-silica nanoparticle mixture for soil remediation. Macromol Symp 376:1600182
Chaudhary DK, Bajagain R, Jeong S-W, Kim J (2020) Biodegradation of diesel oil and n-alkanes (C18, C20, and C22) by a novel strain Acinetobacter sp. K-6 in unsaturated soil. Environ Eng Res 25:290–298
Dontsova KM, Norton LD (2002) Clay dispersion, infiltration, and erosion as influenced by exchangeable Ca and Mg. Soil Sci 167(3):184–193
Elmashad ME (2017) Effect of chemical additives on consistency, infiltration rate and swelling characteristics of bentonite. Water Sci 31:177–188
Gardner KH, Arias MS (2000) Clay swelling and formation permeability reductions induced by a nonionic surfactant. Environ Sci Technol 34:160–166
Gautam P, Bajagain R, Jeong S-W (2019) Soil infiltration capacity of chemical oxidants used for risk reduction of soil contamination. Ecotoxicol Environ Saf 183 (109548)
Gautam P, Bajagain R, Jeong S-W (2020) Combined effects of soil particle size with washing time and soil-to-water ratio on removal of total petroleum hydrocarbon from fuel contaminated soil. Chemosphere 250(126206):126206
Gu B, Doner HE (1993) Dispersion and aggregation of soils as influenced by organic and inorganic polymers. Soil Sci Soc Am J 57:709–716
Haghollahi A, Fazaelipoor MH, Schaffie M (2016) The effect of soil type on the bioremediation of petroleum contaminated soils. J Environ Manag 180:197–201
Hu Z, He G, Liu Y, Dong C, Wu X, Zhao W (2013) Effects of surfactant concentration on alkyl chain arrangements in dry and swollen organic montmorillonite. Appl Clay Sci 75-76:134–140
Ishiguro M, Koopal LK (2016) Surfactant adsorption to soil components and soils. Adv Colloid Interf Sci 231:59–102
Jeong S-W (2019) Estimation of remediation cost for reducing cancer and non-cancer risk of a fuel contaminated site. J Korean Soc Environ Eng 41:286–291
Kan AT, Fu G, Hunter M, Chen W, Ward CH, Tomson MB (1998) Irreversible sorption of neutral hydrocarbons to sediments: experimental observations and model predictions. Environ Sci Technol 32:892–902
Karthick RA, Chattopadhyay P (2017) Remediation of diesel contaminated soil by Tween-20 foam stabilized by silica nanoparticles. Int J Chem Eng Appl 8(3):194–198
Karthick A, Roy B, Chattopadhyay P (2019a) Comparison of zero-valent iron and iron oxide nanoparticle stabilized alkyl polyglucoside phosphate foams for remediation of diesel-contaminated soils. J Environ Manag 240:93–107
Karthick A, Roy B, Chattopadhyay P (2019b) A review on the application of chemical surfactant and surfactant foam for remediation of petroleum oil contaminated soil. J Environ Manag 243:178–205
Karthick A, Chauhan M, Krzan M, Chattopadhyay P (2019c) Potential of surfactant foam stabilized by ethylene glycol and allyl alcohol for the remediation of diesel contaminated soil 14, 100363
Khalladi R, Benhabiles O, Bentahar F, Moulai-Mostefa N (2009) Surfactant remediation of diesel fuel polluted soil. J Hazard Mater 164:1179–1184
Kim D, Kim S, An Y-J (2019) Research trend for on-site soil ecotoxicity evaluation methods for field soil. J Korean Soc Environ Eng 41:125–131
Konečný F, Boháček Z, Müller P, Kovářová M, Sedláčková I (2003) Contamination of soils and groundwater by petroleum hydrocarbons and volatile organic compounds - case study: ELSLAV BRNO. Bull Geosci 78(3):225–239
Litvina M, Todoruk TR, Langford CH (2003) Composition and structure of agents responsible for development of water repellency in soils following oil contamination. Environ Sci Technol 37:2883–2888
Lominchar MA, Lorenzo D, Romero A, Santos A (2017) Remediation of soil contaminated by PAHs and TPH using alkaline activated persulfate enhanced by surfactant addition at flow conditions. J Chem Technol Biotechnol 93(5):1270–1278
Ma M (2012) The dispersive effect of sodium hexa-metaphosphate on kaolinite in saline water. Clay Clay Miner 60(4):405–410
Masy T, Demaneche S, Tromme O, Thonart P, Jacques P, Hiligsmann S, Vogel TM (2016) Hydrocarbon biostimulation and bioaugmentation in organic carbon and clay-rich soils. Soil Biol Biochem 99:66–74
Pacwa-Płociniczak M, Płociniczak T, Iwan J, Zarska M, Chorązewski M, Dzida M, Piotrowska-Seget Z (2016) Isolation of hydrocarbon-degrading and biosurfactant-producing bacteria and assessment their plant growth-promoting traits. J Environ Manag 168:175–184
Peng Z, Darnault CJG, Tian F, Baveye PC, Hu H (2017) Influence of anionic surfactant on saturated hydraulic conductivity of loamy sand and sandy loam soils. Water 9:1–15
Pittman F, Mohammed A, Cey E (2019) Effects of antecedent moisture and macroporosity on infiltration and water flow in frozen soil. Hydrol Process 34(3):795–809
Quirk JP, Schofield RK (1955) The effect of electrolyte concentration on soil permeability. J Soil Sci 6:163–178
Rahbari-Sisakht M, Pouranfard A, Darvishi P, Ismail AF (2016) Biosurfactant production for enhancing the treatment of produced water and bioremediation of oily sludge under the conditions of Gachsaran oil field. J Chem Technol Biotechnol 92(5):1053–1064
Roy JL, McGill WB (2000) Flexible conformation in organic matter coatings: an hypothesis about soil water repellency. Can J Soil Sci 80(1):143–152
Roy JL, McGill WB, Lowen HA, Johnson RL (2000) Hydrophobic soils: site characterization and tests of hypotheses concerning their formation. Final Report on PTAC RFP (1999/2000). Petroleum technology Alliance Canada (PTAC)/Canadian Association of Petroleum Producers (CAPP) Environmental Research Advisory Council (ERAC). Alberta, Canada
Salehpour Z, Mirhabibi AR, Javadpour J, Aghababazadeh R, Brydson R (2009) A study on the effects of three types of deflocculants and the increase in the pH on the rheological behavior of nano carbon suspensions. J Nanosci Nanotechnol 9(7):4507–4513
Siegrist RL, Crimi M, Simpkin TJ (2011) In situ chemical oxidation for ground-water remediation, in; Oxidant delivery approaches and contingency planning, Chapter 11. Springer, New York
Srivastava VJ, Hudson JM, Cassidy DP (2016) In situ solidification and in situ chemical oxidation combined in a single application to reduce contaminant mass and leachability in soil. J Environ Chem Eng 4:2857–2864
Zhou Z, Liu X, Sun K, Lin C, Ma J, He M, Ouyang W (2019) Persulfate-based advanced oxidation processes (AOPs) for organic-contaminated soil remediation: a review. Chem Eng J 372:836–851
Funding
This work was supported by the National Research Foundation of Korea (2018R1A2B6006139).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Code availability
Not applicable
Additional information
Responsible editor: Zhaohui Wang
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary information
ESM 1
(DOCX 417 kb)
Rights and permissions
About this article
Cite this article
Gautam, P., Jeong, SW. Pretreatment of diesel-contaminated hydrophobic soil using surfactant and sodium hexa-metaphosphate (Na-HMP) to improve infiltration of aqueous phase remedial agents in unsaturated soil. J Soils Sediments 21, 948–956 (2021). https://doi.org/10.1007/s11368-020-02822-w
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11368-020-02822-w