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Quantifying the resuspension of sediment and associated metallic contaminants with fallout radionuclide measurements in a channelized river draining an industrial catchment

  • Sediments, Sec 3 • Hillslope and River Basin Sediment Dynamics • Research Article
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Abstract

Purpose

Contamination of river sediment reaches problematic levels in industrialised regions. This study investigates the relevance of using beryllium-7 (7Be), a short-lived environmental radionuclide (53 days half-life), for quantifying the deposition and resuspension of sediment and associated metallic contaminants in a heavily polluted channelized river of Northern France (The Lower Scarpe River).

Materials and methods

Activities in 7Be were measured in bed and suspended sediments collected each month over a hydrological year. Suspended sediments were analysed for metal contents (Pb, Zn, Cd, Cu). The determination of short-term sediment dynamics is based on the variation of total 7Be inventory between two successive samplings. Total inventory of 7Be consists of two components, i.e., the residual inventory and the new inventory.

Results and discussion

Inventories of 7Be in sediment varied from 1 to 135 mBq cm−2. Observed spatial and temporal variations reflected the dynamic behaviour of sediment in the studied channel section. The succession of sediment deposition and resuspension periods was demonstrated during the study, with maximum deposition and erosion rates of 0.3 ± 0.2 and −0.46 ± 0.05 g cm−2 month−1, respectively. A sediment resuspension rate of 0.06 g cm−2 month−1 supplied to the water column a flux of 12, 13, 23 and 145 μg cm−2 month−1 of Cd, Cu, Pb and Zn, respectively. During this 15-month study, 28 to 50 % of Pb that was deposited in the riverbed sediment was resuspended, thereby contributing to the (short term) degradation of water quality.

Conclusions

The present work provides a useful tool for examining the role of sediment as a sink or source of contamination for the water column. It produces knowledge of how sediment processes affect the fate and the transport of contaminants and the implications for future downstream fluxes.

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Acknowledgements

This study was financially supported by the European Union (FEDER) and French authorities (DIREN). Water discharge data were provided by ‘Voies Navigables de France’. We gratefully acknowledge Vincent Ledoux (Société des Eaux de Douai), William Guerin (Agence de l’Eau Artois-Picardie), and Olivier Masson (Institut de Radioprotection et de Sûreté Nucléaire) for providing rainfall records, maps and 7Be and 210Pb activities in rainfall, respectively. We also gratefully acknowledge Manon Heysck, Florent Mourier, Bertrand Girondelot, Terence Daumeries and Philippe Bataillard (CNRSSP) for their assistance during fieldwork. The authors also gratefully thank the two anonymous reviewers whose suggestions greatly improved the quality of the manuscript.

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Correspondence to Mathilde Zebracki.

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Table S1 Grain size distribution in bed sediment (%). Table S2 Grain size distribution in suspended sediment (%). Table S3 Activities in 137Cs and 210Pbxs (Bq kg−1) and 7Be/210Pbxs activity ratio in suspended sediment. Activities in 7Be and 210Pb (Bq kg−1) and activity ratio 7Be/210Pb in rainwater samples collected each month from August 2005 to September 2006 (source: French Institute of Radioprotection and Nuclear Safety, OPERA-Air network). Fraction of recent sediment in suspended sediment (%). Table S4. Characteristics of suspended sediment collected at the lift station “Vallée de Scarpe”: fraction of fine material (<63 μm, in %); 7Be activities (Bq kg−1); metal contents (Cu and Pb in μg g−1, Cd and Zn in mg g−1). Table S5. Monthly flux of contaminants associated with sediment dynamics (μg cm−2 month−1). (XLSX 53 kb)

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Figure S1 Plot of 137Cs activity versus fraction of fine material in bed and suspended sediment (SS). (XLSX 58 kb)

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Zebracki, M., Alary, C., Lefèvre, I. et al. Quantifying the resuspension of sediment and associated metallic contaminants with fallout radionuclide measurements in a channelized river draining an industrial catchment. J Soils Sediments 16, 294–308 (2016). https://doi.org/10.1007/s11368-015-1303-3

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