Abstract
The hydrophobicity of silica and composite aerogels has enabled them to acquire applications in a variety of fields. With remarkable structural, morphological, and physiochemical properties such as high porosity, surface area, chemical stability, and selectivity, these materials have gained much attention of researchers worldwide. Moreover, the hydrophobic conduct has enabled these aerogels to adsorb substances, i.e., organic pollutants, without collapsing the pore and network structure. Hence, considering such phenomenal properties and great adsorption potential, exploiting these materials for environmental and biomedical applications is trending. The present study explores the most recent advances in synthetic approaches and resulting properties of hydrophobic silica and composite aerogels. It presents the various precursors and co-precursors used for hydrophobization and gives a comparative analysis of drying methods. Moreover, as a major focus, the work presents the recent progress where these materials have shown promising results for various environmental remediation and biomedical applications. Finally, the bottlenecks in synthesis and applicability along with future prospects are given in conclusions.
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Adapted from ref. (Pierre and Rigacci 2011)
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Adapted from ref. (Anderson and Carroll 2011)
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Adapted from ref. (Anderson and Carroll 2011)
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Adapted from ref. (Wu et al. 2020)
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Adapted from ref. (Zhao et al. 2019)
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Adapted from ref. (Qian et al. 2021)
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Adapted from ref. (Menshutina et al. 2018)
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The data in this manuscript is available with the corresponding author and can be provided on reasonable request.
R eferences
Adebajo MO, Frost RL, Kloprogge JT et al (2003) Porous materials for oil spill cleanup: a review of synthesis and absorbing properties. J Porous Mater 10:159–170. https://doi.org/10.1023/A:1027484117065
Akhter F, Rao AA, Abbasi MN et al (2022) A comprehensive review of synthesis, applications and future prospects for silica nanoparticles (SNPs). SILICON. https://doi.org/10.1007/s12633-021-01611-5
Akhter F, Soomro SA, Inglezakis VJ (2021a) Silica aerogels; a review of synthesis, applications and fabrication of hybrid composites. J Porous Mater 28:1387–1400. https://doi.org/10.1007/s10934-021-01091-3
Akhter F, Soomro SA, Jamali AR et al (2021b) Rice husk ash as green and sustainable biomass waste for construction and renewable energy applications: a review. Biomass Convers Biorefin. https://doi.org/10.1007/s13399-021-01527-5
Akhter F, Soomro SA, Jamali AR, Inglezakis VJ (2023) Structural, morphological and physiochemical analysis of SiC8H20O4/C2H5O/C7H16 modified mesoporous silica aerogels. Phys Chem Res 11:1–8. https://doi.org/10.22036/PCR.2022.332609.2044
Al-Husseny WH, Al-Sharuee IF, Ali R (2022) Water glass based superhydrophobic silica aerogel in different environmental of preparation. New Mater Compd Appl 6:127–139
Aminoroaya A, Bagheri R, Nouri Khorasani S, et al (2022) Mesoporous silica aerogel reinforced dental composite: effects of microstructure and surface modification. J Mech Behav Biomed Mater 125. https://doi.org/10.1016/J.JMBBM.2021.104947
Anderson AM, Carroll MK (2011) Hydrophobic silica aerogels: review of synthesis, properties and applications. Aerogels Handbook 47–77. https://doi.org/10.1007/978-1-4419-7589-8_3
Anderson AM, Carroll MK, Green EC et al (2010) Hydrophobic silica aerogels prepared via rapid supercritical extraction. J Solgel Sci Technol 53:199–207. https://doi.org/10.1007/s10971-009-2078-z
Anderson AM, Wattley CW, Carroll MK (2009) Silica aerogels prepared via rapid supercritical extraction: effect of process variables on aerogel properties. J Non Cryst Solids 355:101–108. https://doi.org/10.1016/j.jnoncrysol.2008.10.005
Arenillas A, Menéndez JA, Reichenauer G, et al (2019) Properties of carbon aerogels and their organic precursors. 87–121. https://doi.org/10.1007/978-3-030-13897-4_3
Bangi UKH, Patil B, Pawar RC, Park HH (2020) Influence of various sol–gel parameters on the physico-chemical properties of sulfuric acid chelated zirconia aerogels dried at ambient pressure. Macromol Symp 393. https://doi.org/10.1002/masy.202000025
Bangi UKH, Rao AV, Rao AP (2008) A new route for preparation of sodium-silicate-based hydrophobic silica aerogels via ambient-pressure drying. Sci Technol Adv Mater 9:35006. https://doi.org/10.1088/1468-6996/9/3/035006
Bhagat SD, Kim YH, Suh KH et al (2008) Superhydrophobic silica aerogel powders with simultaneous surface modification, solvent exchange and sodium ion removal from hydrogels. Microporous Mesoporous Mater 112:504–509. https://doi.org/10.1016/j.micromeso.2007.10.030
Bhagat SD, Oh CS, Kim YH et al (2007) Methyltrimethoxysilane based monolithic silica aerogels via ambient pressure drying. Microporous Mesoporous Mater 100:350–355. https://doi.org/10.1016/j.micromeso.2006.10.026
Bhagat SD, Rao AV (2006) Surface chemical modification of TEOS based silica aerogels synthesized by two step (acid-base) sol-gel process. Appl Surf Sci 252:4289–4297. https://doi.org/10.1016/j.apsusc.2005.07.006
Bokov D, Turki Jalil A, Chupradit S, et al (2021) Nanomaterial by sol-gel method: synthesis and application. Advances in Materials Science and Engineering 2021. https://doi.org/10.1155/2021/5102014
Cashman JL, Nguyen BN, Dosa B, Meador MAB (2020) Flexible polyimide aerogels derived from the use of a neopentyl spacer in the backbone. ACS Appl Polym Mater 2:2179–2189. https://doi.org/10.1021/acsapm.0c00153
Chen K, Feng Q, Ma D, Huang X (2021) Hydroxyl modification of silica aerogel: an effective adsorbent for cationic and anionic dyes. Colloids Surf A Physicochem Eng Asp 616. https://doi.org/10.1016/j.colsurfa.2021.126331
Chen Y, Liu Y, Li Y et al (2020) Functional wastepaper-montmorillonite composite aerogel for Cd2+ adsorption. Environ Sci Pollut Res 27:38644–38653. https://doi.org/10.1007/S11356-020-09907-6
Cheng P, Wang C, Kaneti YV et al (2020) Practical MOF nanoarchitectonics: new strategies for enhancing the processability of MOFs for practical applications. Langmuir 36:4231–4249. https://doi.org/10.1021/ACS.LANGMUIR.0C00236
Ciogli A, Buonsenso F, Proietti N, et al (2022) Preparation of a high-density vinyl silica gel to anchor cysteine via photo-click reaction and its applications in hydrophilic interaction chromatography. J Chromatogr A 1675. https://doi.org/10.1016/J.CHROMA.2022.463173
De Marco I, Miranda S, Riemma S, Iannone R (2016) LCA of starch aerogels for biomedical applications. Chem Eng Trans 49:319–324. https://doi.org/10.3303/CET1649054
Dhaneswara D, Fatriansyah JF, Situmorang FW, Haqoh AN (2020) Synthesis of amorphous silica from rice husk ash: comparing HCl and CH3COOH acidification methods and various alkaline concentrations. Int J Technol 11:200–208. https://doi.org/10.14716/ijtech.v11i1.3335
Dhavale RP, Parale VG, Kim THYK-YH-N-RH-H (2020) Enhancement in the textural properties and hydrophobicity of tetraethoxysilane-based silica aerogels by phenyl surface modification. J Microelectron Packag Soc 27:27–32. https://doi.org/10.6117/kmeps.2020.27.2.027
Ding J, Zhong K, Liu S et al (2020) Flexible and super hydrophobic polymethylsilsesquioxane based silica aerogel for organic solvent adsorption via ambient pressure drying technique. Powder Technol 373:716–726. https://doi.org/10.1016/j.powtec.2020.07.024
Du D, Jiang Y, Feng JJ et al (2020) Facile synthesis of silica aerogel composites via ambient-pressure drying without surface modification or solvent exchange. Vacuum 173:109117. https://doi.org/10.1016/j.vacuum.2019.109117
El Rassy H, Maury S, Buisson P, Pierre AC (2004) Hydrophobic silica aerogel–lipase biocatalysts: possible interactions between the enzyme and the gel. J Non Cryst Solids 350:23–30. https://doi.org/10.1016/J.JNONCRYSOL.2004.06.021
Farjood M, Zanjanchi MA (2022) Enhanced photocatalytic activity of nano-silica/copper plasmon by aminofunctional silane for dye pollutant degradation. Environ Sci Pollut Res. https://doi.org/10.1007/S11356-022-21145-6
Feng J, Wang X, Han S et al (2019a) An ionic-liquid-modified melamine-formaldehyde aerogel for in-tube solid-phase microextraction of estrogens followed by high performance liquid chromatography with diode array detection. Microchim Acta 186:1–8. https://doi.org/10.1007/S00604-019-3909-4/TABLES/3
Feng T, Ye X, Zhao Y et al (2019b) Magnetic silica aerogels with high efficiency for selective adsorption of pyrethroid insecticides in juices and tea beverages. New J Chem 43:5159–5166. https://doi.org/10.1039/C8NJ05962D
Ferreira-Gonçalves T, Constantin C, Neagu M, et al (2021) Safety and efficacy assessment of aerogels for biomedical applications. Biomed Pharmacotherapy 144. https://doi.org/10.1016/J.BIOPHA.2021.112356
Galebach PH, Soeherman JK, Wittrig AM et al (2019) Supercritical methanol depolymerization and hydrodeoxygenation of maple wood and biomass-derived oxygenates into renewable alcohols in a continuous flow reactor. ACS Sustain Chem Eng 7:15361–15372. https://doi.org/10.1021/acssuschemeng.9b02704
Gauthier BM, Bakrania SD, Anderson AM, Carroll MK (2004) A fast supercritical extraction technique for aerogel fabrication. In: J Non-Cryst Solids pp 238–243
Ge D, Yang L, Li Y, Zhao JP (2009) Hydrophobic and thermal insulation properties of silica aerogel/epoxy composite. J Non Cryst Solids 355:2610–2615. https://doi.org/10.1016/j.jnoncrysol.2009.09.017
Guo Z, Yang R, Wang T et al (2021) Cost-effective additive manufacturing of ambient pressure-dried silica aerogel. J Manuf Sci E T ASME 143:1–32. https://doi.org/10.1115/1.4048740
Gupta NK, Wu T, Ke Q et al (2022) Recent advances in carbon-silica composites: preparation, properties, and applications. Catalysts 12:573. https://doi.org/10.3390/CATAL12050573
Gurav JL, Rao AV, Bangi UKH (2009) Hydrophobic and low density silica aerogels dried at ambient pressure using TEOS precursor. J Alloys Compd 471:296–302. https://doi.org/10.1016/J.JALLCOM.2008.03.076
Gurav JL, Rao AV, Nadargi DY, Park HH (2010) Ambient pressure dried TEOS-based silica aerogels: good absorbents of organic liquids. J Mater Sci 45:503–510. https://doi.org/10.1007/S10853-009-3968-8
Hæreid S, Einarsrud MA, Scherer GW (1994) Mechanical strengthening of TMOS-based alcogels by aging in silane solutions. J Sol-Gel Sci Technol 1994 3:3 3:199–204. https://doi.org/10.1007/BF00486558
Hrubesh LW, Coronado PR, Satcher JH (2001) Solvent removal from water with hydrophobic aerogels. J Non Cryst Solids 285:328–332. https://doi.org/10.1016/S0022-3093(01)00475-6
Ihsanullah I, Sajid M, Khan S, Bilal M (2022) Aerogel-based adsorbents as emerging materials for the removal of heavy metals from water: progress, challenges, and prospects. Sep Purif Technol 291:120923. https://doi.org/10.1016/J.SEPPUR.2022.120923
Jabbari-Gargari A, Moghaddas J, Hamishehkar H, Jafarizadeh-Malmiri H (2021) Carboxylic acid decorated silica aerogel nanostructure as drug delivery carrier. Microporous Mesoporous Mater 323:111220. https://doi.org/10.1016/J.MICROMESO.2021.111220
Jing Y, Jia M, Xu Z, et al (2022) Facile synthesis of recyclable 3D gelatin aerogel decorated with MIL-88B(Fe) for activation peroxydisulfate degradation of norfloxacin. J Hazard Mater 424. https://doi.org/10.1016/J.JHAZMAT.2021.127503
Kalinin S v., Kheifets LI, Mamchik AI, et al (1999) Influence of the drying technique on the structure of silica gels. J Sol-Gel Sci Technol 1999 15:1 15:31–35. https://doi.org/10.1023/A:1008771829173
Kamel RM, Shahat A, Atta AH, Farag-Allah MMA (2022) Development of a novel and potential chemical sensor for colorimetric detection of Pd(II) or Cu(II) in E-wastes. Microchem J 172:106951. https://doi.org/10.1016/J.MICROC.2021.106951
Kesserwan F, Ahmad MN, Khalil M, El-Rassy H (2020) Hybrid CaO/Al2O3 aerogel as heterogeneous catalyst for biodiesel production. Chem Eng J 385. https://doi.org/10.1016/J.CEJ.2019.123834
Khedkar MV, Jadhav SA, Somvanshi SB, et al (2020) Physicochemical properties of ambient pressure dried surface modified silica aerogels: effect of pH variation. SN Appl Sci 2. https://doi.org/10.1007/s42452-020-2463-3
Kim M, Eo K, Lim HJ, Kwon YK (2018) Low shrinkage, mechanically strong polyimide hybrid aerogels containing hollow mesoporous silica nanospheres. Compos Sci Technol 165:355–361. https://doi.org/10.1016/J.COMPSCITECH.2018.07.021
Lee CJ, Kim GS, Hyun SH (2002) Synthesis of silica aerogels from waterglass via new modified ambient drying. J Mater Sci 37:2237–2241. https://doi.org/10.1023/A:1015309014546
Leventis N (2011) Interpenetrating organic/inorganic networks of resorcinol formaldehyde/metal oxide Aerogels. In: Aerogels Handbook. Springer New York, pp 287–313
Li D, Tian X, Wang Z, et al (2020a) Multifunctional adsorbent based on metal-organic framework modified bacterial cellulose/chitosan composite aerogel for high efficient removal of heavy metal ion and organic pollutant. Chem Eng J 383. https://doi.org/10.1016/J.CEJ.2019.123127
Li P, Kim S, Jin J, et al. (2020b) Efficient photodegradation of volatile organic compounds by iron-based metal-organic frameworks with high adsorption capacity. Appl Catal B 263. https://doi.org/10.1016/J.APCATB.2019.118284
Liang W, Wang B, Cheng J, et al. (2021a) 3D, eco-friendly metal-organic frameworks@carbon nanotube aerogels composite materials for removal of pesticides in water. J Hazard Mater 401. https://doi.org/10.1016/J.JHAZMAT.2020.123718
Liu D, Chen C, Zhou Y, et al (2021) 3D-printed, high-porosity, high-strength graphite aerogel. Small Methods 5. https://doi.org/10.1002/SMTD.202001188
Liu H, Jiang C, Li H, Chen Z (2019) Preparation of FeBTC/silica aerogels by a co-sol-gel process for organic pollutant adsorption. Mater Res Express 6. https://doi.org/10.1088/2053-1591/ab5076
Liu H, Sha W, Cooper AT, Fan M (2009) Preparation and characterization of a novel silica aerogel as adsorbent for toxic organic compounds. Colloids Surf A Physicochem Eng Asp 347:38–44. https://doi.org/10.1016/j.colsurfa.2008.11.033
Liu Q, Li S, Yu H et al (2020) Covalently crosslinked zirconium-based metal-organic framework aerogel monolith with ultralow-density and highly efficient Pb(II) removal. J Colloid Interface Sci 561:211–219. https://doi.org/10.1016/J.JCIS.2019.11.074
Liu SW, Wei Q, Cui SP et al (2016) Hydrophobic silica aerogel derived from wheat husk ash by ambient pressure drying. J Solgel Sci Technol 78:60–67. https://doi.org/10.1007/s10971-015-3928-5
Ma S, Zhang M, Nie J et al (2019) Design of double-component metal–organic framework air filters with PM2.5 capture, gas adsorption and antibacterial capacities. Carbohydr Polym 203:415–422. https://doi.org/10.1016/J.CARBPOL.2018.09.039
Maleki H, Durães L, Portugal A (2015) Development of mechanically strong ambient pressure dried silica aerogels with optimized properties. J Phys Chem C 119:7689–7703. https://doi.org/10.1021/JP5116004
Maleki H, Durães L, Portugal A (2014) An overview on silica aerogels synthesis and different mechanical reinforcing strategies. J Non Cryst Solids 385:55–74. https://doi.org/10.1016/j.jnoncrysol.2013.10.017
Mary SK, Koshy RR, Arunima R, et al (2022) A review of recent advances in starch-based materials: bionanocomposites, pH sensitive films, aerogels and carbon dots. Carbohydrate Polymer Technol Appl 3. https://doi.org/10.1016/j.carpta.2022.100190
Menshutina N, Tsygankov P, Ivanov S (2018) Synthesis and properties of silica and alginate hybrid aerogel particles with embedded carbon nanotubes (CNTs) for selective sorption. Materials (Basel) 12. https://doi.org/10.3390/MA12010052
Meti P, Mahadik DB, Lee K-Y et al (2022) Overview of organic–inorganic hybrid silica aerogels: progress and perspectives. Mater Des 222:111091. https://doi.org/10.1016/J.MATDES.2022.111091
Miner MR, Hosticka B, Norris PM (2004) The effects of ambient humidity on the mechanical properties and surface chemistry of hygroscopic silica aerogel. J Non Cryst Solids 350:285–289. https://doi.org/10.1016/J.JNONCRYSOL.2004.06.023
Mohd Joharudin NF, Latif NA, Mustapa MS, et al (2020) Physical properties and hardness of treated amorphous silica as reinforcement of AA7075 recycled aluminum chip. IOP Conf Ser Mater Sci Eng 824. https://doi.org/10.1088/1757-899X/824/1/012015
Mohseni-Bandpei A, Eslami A, Kazemian H et al (2022) Enhanced adsorption and recyclability of surface modified hydrophobic silica aerogel with triethoxysilane: removal of cefixime by batch and column mode techniques. Environ Sci Pollut Res. https://doi.org/10.1007/S11356-022-22277-5
Nah HY, Kim Y, Kim T et al (2020) Comparisonal studies of surface modification reaction using various silylating agents for silica aerogel. J Solgel Sci Technol 96:346–359. https://doi.org/10.1007/s10971-020-05399-5
Nematidil N, Nezami S, Mirzaie F et al (2021) Fabrication and characterization of a novel nanoporous nanoaerogel based on gelatin as a biosorbent for removing heavy metal ions. J Solgel Sci Technol 97:721–733. https://doi.org/10.1007/s10971-020-05439-0
Noroozi M, Panahi-Sarmad M, Abrisham M et al (2019) Nanostructure of aerogels and their applications in thermal energy insulation. ACS Appl Energy Mater 2:5319–5349. https://doi.org/10.1021/ACSAEM.9B01157
Nuzhdin AL, Shalygin AS, Artiukha EA et al (2016) HKUST-1 silica aerogel composites: Novel materials for the separation of saturated and unsaturated hydrocarbons by conventional liquid chromatography. RSC Adv 6:62501–62507. https://doi.org/10.1039/C6RA06522H
Okutucu B (2021) The medical applications of biobased aerogels: ‘Natural aerogels for medical usage.’ Med Devices Sens 4. https://doi.org/10.1002/MDS3.10168
Panda D, Gangawane KM (2022) Superhydrophobic hybrid silica-cellulose aerogel for enhanced thermal, acoustic, and oil absorption characteristics. J Mater Sci 57:13385–13402. https://doi.org/10.1007/S10853-022-07506-Z/FULLTEXT.HTML
Parvathy Rao A, Venkateswara Rao A (2008) Microstructural and physical properties of the ambient pressure dried hydrophobic silica aerogels with various solvent mixtures. J Non Cryst Solids 354:10–18. https://doi.org/10.1016/J.JNONCRYSOL.2007.07.021
Peng H, Xiong W, Yang Z, et al (2021) Facile fabrication of three-dimensional hierarchical porous ZIF-L/gelatin aerogel: highly efficient adsorbent with excellent recyclability towards antibiotics. Chem Eng J 426. https://doi.org/10.1016/J.CEJ.2021.130798
Peng H, Xiong W, Yang Z et al (2022) Advanced MOFs@aerogel composites: construction and application towards environmental remediation. J Hazard Mater 432:128684. https://doi.org/10.1016/J.JHAZMAT.2022.128684
Pierre AC, Rigacci A (2011) SiO2 aerogels. aerogels handbook. Springer, New York, pp 21–45
Pinto I, Silvestre JD, de Brito J, Júlio MF (2020) Environmental impact of the subcritical production of silica aerogels. J Clean Prod 252. https://doi.org/10.1016/j.jclepro.2019.119696
Poco JF, Coronado PR, Pekala RW, Hrubesh LW (1996) Rapid supercritical extraction process for the production of silica aerogels. In: Materials Research Society Symposium - Proceedings. Mater Res Soc pp 297–302
Prakash SS, Sankaran CJ, Hurd AJ, Rao SM (1995) Silica aerogel films prepared at ambient pressure by using surface derivatization to induce reversible drying shrinkage. Nature 374:439–443. https://doi.org/10.1038/374439a0
Qian H, Li W, Wang X, et al. (2021) Simultaneous growth of graphene/mesoporous silica composites using liquid precursor for HPLC separations. Appl Surf Sci 537. https://doi.org/10.1016/j.apsusc.2020.148101
Rao AV, Kulkarni MM (2002) Hydrophobic properties of TMOS/TMES-based silica aerogels. Mater Res Bull 37:1667–1677. https://doi.org/10.1016/S0025-5408(02)00795-X
Rego RM, Kuriya G, Kurkuri MD, Kigga M (2021) MOF based engineered materials in water remediation: Recent trends. J Hazard Mater 403. https://doi.org/10.1016/J.JHAZMAT.2020.123605
Ren J, Feng J, Wang L, et al. (2021) High specific surface area hybrid silica aerogel containing POSS. Microporous Mesoporous Mater 310. https://doi.org/10.1016/J.MICROMESO.2020.110456
Ren W, Wei Z, Xia X, et al. (2020a) CO2 adsorption performance of CuBTC/graphene aerogel composites. J Nanoparticle Res 22. https://doi.org/10.1007/S11051-020-04933-4
Reynolds JG, Coronado PR, Hrubesh LW (2010) Hydrophobic aerogels for oil-spill cleanup? Intrinsic Absorbing Properties 23:831–843. https://doi.org/10.1080/009083101316931906
Rodríguez-Dorado R, López-Iglesias C, García-González CA et al (2019) Design of aerogels, cryogels and xerogels of alginate: effect of molecular weight, gelation conditions and drying method on particles’ micromeritics. Molecules 24:4–6. https://doi.org/10.3390/molecules24061049
Saad N, Chaaban M, Patra D et al (2020) Molecularly imprinted phenyl-functionalized silica aerogels: selective adsorbents for methylxanthines and PAHs. Microporous Mesoporous Mater 292:109759. https://doi.org/10.1016/j.micromeso.2019.109759
Scherer GW, Gross J, Hrubesh LW, Coronado PR (2002) Optimization of the rapid supercritical extraction process for aerogels. J Non Cryst Solids 311:259–272. https://doi.org/10.1016/S0022-3093(02)01379-0
Shanmugam G, Gunasekaran E, Karuppusamy RS et al (2020) Utilization of aerogel in building construction-a review. IOP Conf Ser Mater Sci Eng 955:012032. https://doi.org/10.1088/1757-899X/955/1/012032
Shewale PM, Rao AV, Rao AP (2008) Effect of different trimethyl silylating agents on the hydrophobic and physical properties of silica aerogels. Appl Surf Sci 254:6902–6907. https://doi.org/10.1016/J.APSUSC.2008.04.109
Shimizu T, Kanamori K, Nakanishi K (2017) Silicone-based organic–inorganic hybrid aerogels and xerogels. Chem Eur J 23:5176–5187. https://doi.org/10.1002/CHEM.201603680
Siddiqui B, Rehman A ur, Haq I ul, et al. (2022) Exploiting recent trends for the synthesis and surface functionalization of mesoporous silica nanoparticles towards biomedical applications. Int J Pharm X 4. https://doi.org/10.1016/j.ijpx.2022.100116
Singh N, Vinjamur M, Mukhopadhyay M (2022) Influence of drug properties on loadings and release kinetics of drugs from silica aerogels loaded in supercritical CO2. J Supercrit Fluids 181:105510. https://doi.org/10.1016/J.SUPFLU.2021.105510
Ślosarczyk A (2017) Recent advances in research on the synthetic fiber based silica aerogel nanocomposites. Nanomaterials 7. https://doi.org/10.3390/nano7020044
Smirnova I, Gurikov P (2017) Aerogels in chemical engineering: strategies toward tailor-made aerogels. Annu Rev Chem Biomol Eng 8:307–334. https://doi.org/10.1146/annurev-chembioeng-060816-101458
Sroysee W, Kongsawatvoragul K, Phattharaphuti P et al (2022) Enzyme-immobilized 3D silver nanoparticle/graphene aerogel composites towards biosensors. Mater Chem Phys 277:125572. https://doi.org/10.1016/J.MATCHEMPHYS.2021.125572
Štandeker S, Novak Z, Knez Ž (2007) Adsorption of toxic organic compounds from water with hydrophobic silica aerogels. J Colloid Interface Sci 310:362–368. https://doi.org/10.1016/J.JCIS.2007.02.021
Sun M, Li C, Feng J, et al (2022) Development of aerogels in solid-phase extraction and microextraction. TrAC - Trends Anal Chem 146. https://doi.org/10.1016/j.trac.2021.116497
Sun T, Hao S, Fan R et al (2020a) Hydrophobicity-adjustable MOF constructs superhydrophobic MOF-rGO aerogel for efficient oil-water separation. ACS Appl Mater Interfaces 12:56435–56444. https://doi.org/10.1021/ACSAMI.0C16294
Valencia L, Abdelhamid HN (2019) Nanocellulose leaf-like zeolitic imidazolate framework (ZIF-L) foams for selective capture of carbon dioxide. Carbohydr Polym 213:338–345. https://doi.org/10.1016/J.CARBPOL.2019.03.011
Vareda JP, Durães L (2019) Efficient adsorption of multiple heavy metals with tailored silica aerogel-like materials. Environ Technol (united Kingdom) 40:529–541. https://doi.org/10.1080/09593330.2017.1397766
Venkateswara Rao A, Hegde ND, Hirashima H (2007) Absorption and desorption of organic liquids in elastic superhydrophobic silica aerogels. J Colloid Interface Sci 305:124–132. https://doi.org/10.1016/j.jcis.2006.09.025
Wang H, Gong Y, Wang Y (2014) Cellulose-based hydrophobic carbon aerogels as versatile and superior adsorbents for sewage treatment. RSC Adv 4:45753–45759. https://doi.org/10.1039/C4RA08446B
Wang H, Zhang Y, Xiong J et al (2022) Regenerated cellulose microspheres-aerogel enabled sustainable removal of metal ions for water remediation. J Mater Sci 57:8016–8028. https://doi.org/10.1007/S10853-022-07175-Y/FULLTEXT.HTML
Wang X, Du T, Wang J et al (2018) Assessment of graphene aerogel matrix solid-phase dispersion as sample preparation for the determination of chlorophenols in soil. New J Chem 42:6778–6784. https://doi.org/10.1039/C8NJ00942B
Wang X, Jana SC (2013) Synergistic hybrid organic-inorganic aerogels. ACS Appl Mater Interfaces 5:6423–6429. https://doi.org/10.1021/AM401717S
Wu T, Dong J, de France K et al (2020) Porous carbon frameworks with high CO2 capture capacity derived from hierarchical polyimide/zeolitic imidazolate frameworks composite aerogels. Chem Eng J 395:124927. https://doi.org/10.1016/J.CEJ.2020.124927
Xie H, He Z, Liu Y et al (2022) Efficient antibacterial agent delivery by mesoporous silica aerogel. ACS Omega 7:7638–7647. https://doi.org/10.1021/ACSOMEGA.1C06198
Yahya EB, Alzalouk MM, Alfallous KA, Abogmaza AF (2020) Antibacterial cellulose-based aerogels for wound healing application: a review. Biomed Res Therapy 7:4032–4040. https://doi.org/10.15419/BMRAT.V7I10.637
Yao J, Gao X, Wu Y et al (2022) High-temperature resistant ambient pressure-dried aluminum doped silica aerogel from inorganic silicon and aluminum sources. Ceram Int 48:15006–15016. https://doi.org/10.1016/J.CERAMINT.2022.02.029
Younus AR, Iqbal J, Muhammad N, et al (2019) Nonenzymatic amperometric dopamine sensor based on a carbon ceramic electrode of type SiO2/C modified with Co3O4 nanoparticles. Microchim Acta 186. https://doi.org/10.1007/S00604-019-3605-4
Yu Y, Shi X, Liu L, Yao J (2021) Highly compressible and durable superhydrophobic cellulose aerogels for oil/water emulsion separation with high flux. J Mater Sci 56:2763–2776. https://doi.org/10.1007/s10853-020-05441-5
Zarinwall A, Maurer V, Pierick J et al (2022) Amorphization and modified release of ibuprofen by post-synthetic and solvent-free loading into tailored silica aerogels. Drug Deliv 29:2086–2099. https://doi.org/10.1080/10717544.2022.2092237
Zhang C, Jia M, Xu Z et al (2022) Constructing 2D/2D N-ZnO/g-C3N4 S-scheme heterojunction: efficient photocatalytic performance for norfloxacin degradation. Chem Eng J 430:132652. https://doi.org/10.1016/J.CEJ.2021.132652
Zhang S, Zhao M, Li H et al (2021a) Facile in situ synthesis of ZIF-67/cellulose hybrid membrane for activating peroxymonosulfate to degrade organic contaminants. Cellulose 28:3585–3598. https://doi.org/10.1007/S10570-021-03717-W
Zhang X, Chen Z, Zhang J, et al (2021b) Hydrophobic silica aerogels prepared by microwave irradiation. Chem Phys Lett 762. https://doi.org/10.1016/j.cplett.2020.138127
Zhang X, Liang Q, Han Q et al (2016) Metal–organic frameworks@graphene hybrid aerogels for solid-phase extraction of non-steroidal anti-inflammatory drugs and selective enrichment of proteins. Analyst 141:4219–4226. https://doi.org/10.1039/C6AN00353B
Zhang Y, Liu F, Yang Z et al (2021c) Weakly hydrophobic nanoconfinement by graphene aerogels greatly enhances the reactivity and ambient stability of reactivity of MIL-101-Fe in Fenton-like reaction. Nano Res 14:2383–2389. https://doi.org/10.1007/S12274-020-3239-1
Zhang Y, Xiang L, Shen Q, et al (2021d) Rapid synthesis of dual-mesoporous silica aerogel with excellent adsorption capacity and ultra-low thermal conductivity. J Non Cryst Solids 555. https://doi.org/10.1016/j.jnoncrysol.2020.120547
Zhang Z, Shen J, Ni X, et al (2007) Hydrophobic silica aerogels strengthened with nonwoven fibers. 43:1663–1670. https://doi.org/10.1080/10601320600934792
Zhao X, Liu S, Peng J et al (2019) Facile one-pot synthesized hydrothermal carbon from cyclodextrin: a stationary phase for hydrophilic interaction liquid chromatography. J Chromatogr A 1585:144–151. https://doi.org/10.1016/J.CHROMA.2018.11.064
Zhou B, Shen J, Wu Y et al (2007) Hydrophobic silica aerogels derived from polyethoxydisiloxane and perfluoroalkylsilane. Mater Sci Eng, C 27:1291–1294. https://doi.org/10.1016/j.msec.2006.06.032
Zhu F, Guo J, Zeng F et al (2010) Preparation and characterization of porous carbon material-coated solid-phase microextraction metal fibers. J Chromatogr A 1217:7848–7854. https://doi.org/10.1016/J.CHROMA.2010.10.080
Zhu J, Hu J, Jiang C et al (2019) Ultralight, hydrophobic, monolithic konjac glucomannan-silica composite aerogel with thermal insulation and mechanical properties. Carbohydr Polym 207:246–255. https://doi.org/10.1016/j.carbpol.2018.11.073
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Faheem Akhter, Abdul Rauf Jamali, Mahmood Nabi Abbasi, Mukhtiar Ali Mallah: introduction, synthesis routes, drying of wet gel; Faheem Akhter, Ahsan Atta Rao, Shafeeque Ahmed Wahocho: comparison of drying methods, synthesis of hydrophobic silica and composite aerogels; Faheem Akhter, Hafiz Anees-ur-Rehman, Zubair Ahmed Chandio: applications, conclusions.
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Akhter, F., Jamali, A.R., Abbasi, M.N. et al. A comprehensive review of hydrophobic silica and composite aerogels: synthesis, properties and recent progress towards environmental remediation and biomedical applications. Environ Sci Pollut Res 30, 11226–11245 (2023). https://doi.org/10.1007/s11356-022-24689-9
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DOI: https://doi.org/10.1007/s11356-022-24689-9