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Heavy metal pollution and mobility of sediment in Tajum River caused by artisanal gold mining in Banyumas, Central Java, Indonesia

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Abstract

The heavy metals Cu, Pb, Zn, and Cd in the stream sediment of the Tajum River were studied based on 12 sediment samples obtained from upstream to downstream. The artisanal mining activities in the study area generated mining processing waste (tailing) and are the primary source of heavy metal pollution. The samples were analyzed for metal concentration as well as metal mobility based on sequential extraction analysis. Heavy metal analysis for the concentration of the metals showed that the value of Cu, Pb, Zn, and Cd in sediment samples transcends the mean crust. The change of the heavy metal concentrations in stream sediment between the upstream and downstream areas showed that higher levels were located near mining activities in upstream and that these decreased with distance to downstream. The result of the sequential extraction study revealed that Cu and Pb were more found in the exchangeable and carbonate fraction of about 26% and 24%. Meanwhile, Zn and Cd were present in the Fe–Mn oxide, an organic and residual fraction of about 90% and 85%, respectively. The mobility factor assessment revealed that the heavy metals investigated had an average mobility factor of 25.89%, 23.9%, 14.4 %, and 9.24% for Cu, Pb, Zn, and Cd, respectively. Overall, Zn and Cd in sediment in the study area were less mobile compared with Cu and Pb.

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References

  • Adewumi AJ, Laniyan TA (2020) Contamination, sources and risk assessments of metals in media from Anka artisanal gold mining area, Northwest Nigeria. Sci Total Environ 718:137235

    Article  CAS  Google Scholar 

  • Aghili S, Vaezihir A, Hosseinzadeh M (2018) Distribution and modeling of heavy metal pollution in the sediment and water mediums of Pakhir River, at the downstream of Sungun mine tailing dump, Iran. Environ Earth Sci 77:128

    Article  Google Scholar 

  • Aspinall C (2001) Small-scale mining in Indonesia. International Institute for Environment and Development, Mining Minerals and Sustainable Development Report, Jakarta

  • Audry S, Grosbois C, Bril H, Schäfer J, Kierczak J, Blanc G (2010) Post-depositional redistribution of trace metals in reservoir sediments of a mining/smelting-impacted watershed (the Lot River, SW France). Appl Geochem 25(6):778–794

    Article  CAS  Google Scholar 

  • Budianta W, Fahmi FL, Arifudin WIW (2019) The distribution and mobility of mercury from artisanal gold mining in river sediments and water, Banyumas, Central Java, Indonesia. Environ Earth Sci 78:90

    Article  Google Scholar 

  • Byrne P, Wood PJ, Reid I (2012) The impairment of river systems by metal mine contamination: a review including remediation options. Crit Rev Environ Sci Technol 42(19):2017–2077

    Article  CAS  Google Scholar 

  • Calmano W, Hong J, Förstner U (1993) Binding and mobilization of heavy metals in contaminated sediments affected by pH and redox potential. Water Sci Technol 28(8-9):223–235

    Article  CAS  Google Scholar 

  • Chen M, Li F, Tao M, Hu L, Shi Y, Liu Y (2019) Distribution and ecological risks of heavy metals in river sediments and overlying water in typical mining areas of China. Mar Pollut Bull 146:893–899

    Article  CAS  Google Scholar 

  • Davutluoglu OI, Seckin S, Ersu CB, Yilmaz T, Sari B (2011) Heavy metal content and distribution in surface sediments of the Seyhan River, Turkey. J Environ Manag 92(9):2250–2259

    Article  CAS  Google Scholar 

  • Djuri M, Samodra H, Gafoer S (1996) Geological map of Purwokerto dan Tegal sheet Central Java, Scale 1:100.000. National Geological Agency, Bandung

  • Dudka S, Adriano DC (1997) Environmental impacts of metal ore mining and processing: a review. J Environ Qual 26(3):590–602

    Article  CAS  Google Scholar 

  • El-Azim HA, El-Moselhy KM (2005) Determination and partitioning of metals in sediments along the Suez Canal by sequential extraction. J Mar Syst 56(3-4):363–374

    Article  Google Scholar 

  • Guevara RA, Sahuquillo A, Rubio R, Rauret G (2004) Assessment of metal mobility in dredged harbour sediments from Barcelona, Spain. Sci Total Environ 321(1-3):241–255

    Article  Google Scholar 

  • Hakim F (2014) Geologi, Alterasi, Mineralisasi Bijih, dan Karakteristik Fluida Hidrotermal pada Endapan Emas Epitermal Sulfidasi Rendah di Daerah Cihonje-Paningkaban, Kecamatan Gumelar, Kabupaten Banyumas, Propinsi Jawa Tengah, Undergraduate thesis, Gadjah Mada University, Indonesia (in Indonesia language – unpublished)

  • Hudson-Edwards KA (2003) Sources, mineralogy, chemistry and fate of heavy metal-bearing particles in mining-affected river systems. Mineral Mag 67(2):205–217

    Article  CAS  Google Scholar 

  • Hudson-Edwards KA, Macklin MG, Miller JR, Lechler PJ (2001) Sources, distribution and storage of heavy metals in the Rı́o Pilcomayo, Bolivia. J Geochem Explor 72:229–250

    Article  CAS  Google Scholar 

  • Kabala C, Singh BR (2001) Fractionation and mobility of copper, lead, and zinc in soil profiles in the vicinity of a copper smelter. J Environ Qual 30:485–492

    Article  CAS  Google Scholar 

  • Karbassi AR, Monavari SM, Nabi Bidhendi GR, Nouri J, Nematpour K (2008) Metal pollution assessment of sediment and water in the Shur River. Environ Monit Assess 147:107–116

    Article  CAS  Google Scholar 

  • Khadhar S, Sdiri A, Chekirben A, Azouzi R, Charef A (2020) Integration of sequential extraction, chemical analysis and statistical tools for the availability risk assessment of heavy metals in sludge amended soil. Environ Pollut 263:114543

  • Klubi E, Abril JM, Mantero J, García-Tenorio R, Nyarko E (2020) Environmental radioactivity and trace metals in surficial sediments from estuarine systems in Ghana (Equatorial Africa), impacted by artisanal gold-mining. J Environ Radioact 218:106260

    Article  CAS  Google Scholar 

  • Li J (2014) Risk assessment of heavy metals in surface sediments from the Yanghe River, China. Int J Environ Res Public Health 11(12):12441–12453

    Article  CAS  Google Scholar 

  • Li XH, Tang ZL, Chu FY, Yang LY (2011) Characteristics of distribution and chemical speciation of heavy metals in environmental mediums around Jinchang mining city, Northwest China. Environ Earth Sci 64(6):1667–1674

    Article  CAS  Google Scholar 

  • Li L, Jiang M, Liu Y, Shen X (2019) Heavy metals inter-annual variability and distribution in the Yangtze River estuary sediment, China. Mar Pollut Bull 141:514–520

    Article  CAS  Google Scholar 

  • Li M, Zhang Q, Sun X, Karki K, Zeng C, Pandey A, Rawat B, Zhang F (2020) Heavy metals in surface sediments in the trans-Himalayan Koshi River catchment: distribution, source identification and pollution assessment. Chemosphere 244:125410

    Article  CAS  Google Scholar 

  • Macklin MG (1996) Fluxes and storage of sediment associated heavy metals in floodplain systems: assessment and river basin management issues at a time of rapid environmental change. In: Anderson MG, Walling DE, Bates PD (eds) Floodplain Processes. John Wiley & Sons, Chichester, pp 441–460

    Google Scholar 

  • Naji A, Ismail A, Ismail AR (2010) Chemical speciation and contamination assessment of Zn and Cd by sequential extraction in surface sediment of Klang River, Malaysia. Microchem J 95(2):285–292

    Article  CAS  Google Scholar 

  • Niane B, Moritz R, Guédron S, Ngom PM, Pfeifer HR, Mall I, Poté J (2014) Effect of recent artisanal small-scale gold mining on the contamination of surface river sediment: case of Gambia River, Kedougou region, southeastern Senegal. J Geochem Explor 144:517–527

    Article  CAS  Google Scholar 

  • Papadopoulos D, Pantazi C, Sauvides C, Haralambous AJ, Papadopoulos A, Loizidou MA (1997) Study on heavy metal pollution in marine sediments and their removal from dredged material. J Environ Sci Health 32:347–360

    Google Scholar 

  • Prihatmoko S, Digdowirogo, Kusumanto D (2002) Potensi Cebakan Mineral di Jawa Tengah dan Daerah Istimewa Yogyakarta. In: Proceedings XXXII Annual Convention of the Indonesian Association of Geologists (IAGI) (in Indonesian language)

  • Ramirez M, Massolo S, Frache R, Correa JA (2005) Metal speciation and environmental impact on sandy beaches due to El Salvador copper mine, Chile. Mar Pollut Bull 50(1):62–72

    Article  CAS  Google Scholar 

  • Reilly SB, Schierl R, Nowak D, Siebert U, Frederick J, Teorgi F, Ismawati Y (2016) A preliminary study on health effects in villagers exposed to mercury in a small-scale artisanal gold mining area in Indonesia. Environ Res 149:274–281

    Article  Google Scholar 

  • Resongles E, Casiot C, Freydier R, Dezileau L, Viers J, Poulichet FE (2014) Persisting impact of historical mining activity to metal (Pb, Zn, Cd, Tl, Hg) and metalloid (As, Sb) enrichment in sediments of the Gardon River, Southern France. Sci Total Environ 481:509–521

    Article  CAS  Google Scholar 

  • Santos JL, Malvar JL, Martín J, Aparicio I, Alonso E (2020) Distribution of metals in sediments of the Guadiamar river basin 20 years after the Aznalcóllar mine spill: bioavailability and risk assessment. J Environ Manag 260:110146

    Article  CAS  Google Scholar 

  • Sims DB, Francis A (2010) Anthropogenic influences on geogenic trace elements and contamination in wash sediments from historical mining activities in the Carnation Wash system, Nelson, Nevada (USA). Int J Soil Sediment Water 3:1

    Google Scholar 

  • Sundaray SK, Nayak BB, Lin S, Bhatta D (2011) Geochemical speciation and risk assessment of heavy metals in the river estuarine sediments—a case study: Mahanadi Basin, India. J Hazard Mater 186(2-3):1837–1846

    Article  CAS  Google Scholar 

  • Tessier A, Campbell PGC, Bisson M (1979) Sequential extraction procedure for the speciation of particulate trace metals. Anal Chem 51(7):844–851

    Article  CAS  Google Scholar 

  • Tokalioğlu S, Kartal S, Elc IL (2000) Determination of heavy metals and their speciation in lake sediments by flame atomic absorption spectrometry after a four-stage sequential extraction procedure. Anal Chim Acta 413(1-2):33–40

    Article  Google Scholar 

  • Tüzen M (2003) Determination of trace metals in the River Yeşilırmak sediments in Tokat, Turkey using sequential extraction procedure. Microchem J 74(1):105–110

    Article  Google Scholar 

  • Venkatramanan S, Chung SY, Ramkumar T, Gnanachandrasamy G, Kim TH (2015) Evaluation of geochemical behavior and heavy metal distribution of sediments: the case study of the Tirumalairajan river estuary, southeast coast of India. Int J Sediment Res 30(1):28–38

    Article  Google Scholar 

  • Violante A, Cozzolino V, Perelomov L, Caporale AG, Pigna M (2010) Mobility and bioavailability of heavy metals and metalloids in soil environments. J Soil Sci Plant Nutr 10(3):268–292

    Article  Google Scholar 

  • Wang XS, Zhu GC, Wang SJ, Wan WY, Tan YB (2010) Distribution and chemical partitioning of heavy metals in marine near-shore sediment cores: a case study from the Xugou, Lianyungang, China. Environ Monit Assess 177(1-4):263–272

    Article  Google Scholar 

  • Wedepohl KH (1995) The composition of the continental crust. Geochim Cosmochim Acta 59(7):1217–1232

    Article  CAS  Google Scholar 

  • Weisz M, Polyak K, Hlavay J (2000) Fractionation of elements in sediment samples collected in rivers and harbors at Lake Balaton and its catchment area. Microchem J 67(1):207–217

    Article  CAS  Google Scholar 

  • Xiaohong F, Peng B, Wang X, Song Z, Zhou D, Wang Q, Qin Z, Tan C (2019) Distribution, contamination and source identification of heavy metals in bed sediments from the lower reaches of the Xiangjiang River in Hunan province, China. Sci Total Environ 689:557–570

    Article  Google Scholar 

  • Yolcubal I, Demiray AD, Çiftçi E, Sanğu E (2016) Environmental impact of mining activities on surface water and sediment qualities around Murgul copper mine, Northeastern Turkey. Environ Earth Sci 75:1415

    Article  Google Scholar 

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Acknowledgments

The author thanks the Geoscience Center Georg-August-Universität Göttingen, Germany, for the laboratory facility for part of analyzing the samples under Erasmus project by European Union on research fellowship program. The author also thanks to Hans Ruppert, Wiebke Fahlbusch, Volker Karius, and Benedikt Sauer for valuable discussion. The author thanks Eska Rutana for picture editing in the manuscript and Fraga L. Fahmi for help conducting sediment sampling in the field. The author thanks Fahmi Hakim for the sharing of a geological map. The author also thanks Hinode Laboratory, Tokyo Institute of Technology Japan, for providing facility on the sample analysis. The author thanks respected reviewers for their valuable comments in improving the manuscript.

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  1. Department of Geological Engineering, Faculty of Engineering, Universitas Gadjah Mada, Jl. Grafika 2 Kampus UGM, Yogyakarta, Indonesia

    Wawan Budianta

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Budianta, W. Heavy metal pollution and mobility of sediment in Tajum River caused by artisanal gold mining in Banyumas, Central Java, Indonesia. Environ Sci Pollut Res 28, 8585–8593 (2021). https://doi.org/10.1007/s11356-020-11157-5

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