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Assessment of arsenic removal efficiency by an iron oxide-coated sand filter process

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Abstract

Arsenic is among the most dangerous contaminants which can limit groundwater use for drinking water consumption. Among the most diffused As-removal technologies around the world, adsorptive media systems are usually favored for relatively low cost and simplicity of operation. This study examines the performance of a laboratory-scale iron oxide-coated sand (IOCS) column filter, to remove arsenic (arsenate (As[V]) and arsenite (As[III])) from groundwater. This technology could be adopted in small communities, as it showed consistent removal rates of 99% with an easy-to-operate process. Some considerations about the possible introduction of such technology in developing countries are provided, highlighting the general impacts to human health related to high arsenic concentrations in groundwater. This, among other adsorption processes, could be recommended as a sustainable mean of ensuring good drinking water quality in developing regions, reducing human health impacts.

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References

  • Agusa T, Trang PTK, Lan VM, Anh DH, Tanabe S, Viet PH, Berg M (2014) Human exposure to arsenic from drinking water in Vietnam. Sci Total Environ 488:562–569

    Article  CAS  Google Scholar 

  • Ahmed MF, Ahuja S, Alauddin M, Hug SJ, Lloyd JR, Pfaff A, Pichler T, Saltikov C, Stute M, Van Geen A (2006) Ensuring safe drinking water in Bangladesh. Science 314(5806):1687–1688

    Article  CAS  Google Scholar 

  • Altaş L, Işık M, Kavurmacı M (2011) Determination of arsenic levels in the water resources of Aksaray Province, Turkey. J Environ Manag 92(9):2182–2192

    Article  CAS  Google Scholar 

  • Azhdarpoor A, Nikmanesh R, Samaei MR (2015) Removal of arsenic from aqueous solutions using waste iron columns inoculated with iron bacteria. Environ Technol 36(20):2525–2531

    Article  CAS  Google Scholar 

  • Bhattacharya P, Nordqvist S, Jacks G (1995) Status of arsenic contamination in the soils around a formerwood preservation facility at Konsterud, Kristinehamns Municipality, Varmlands County, Western Sweden. Norges Geologiske Undersokelse, Report 95. 138, 70–72

  • Callegari A, Boguniewicz-Zablocka J, Capodaglio AG (2017) Experimental application of an advanced separation process for NOM removal from surface drinking water supply. Separations 4(32)

  • Callegari A, Hlavinek P, Capodaglio AG (2018) Production of energy (biodiesel) and recovery of materials (biochar) from pyrolysis of waste urban sludge. Revista Ambiente e Agua. Article in press

  • Capodaglio AG (2017) In-stream detection of waterborne priority pollutants, and applications in drinking water contaminant warning systems. Water Sci Technol Water Supply 17(3):707–725

    Article  Google Scholar 

  • Capodaglio AG, Molognoni D, Dallago E, Liberale A, Cella R, Longoni P, Pantaleoni L (2013) Microbial fuel cells for direct electrical energy recovery from urban wastewaters. Sci World J 3:1–8

    Article  CAS  Google Scholar 

  • Capodaglio AG, Callegari A, Cecconet D, Molognoni D (2017) Sustainability of decentralized wastewater treatment technologies. Water Pract Technol 12(2):463–477

    Article  Google Scholar 

  • Cecconet D, Devecseri M, Callegari A, Capodaglio AG (2018) Effects of process operating conditions on the autotrophic denitrification of nitrate-contaminated groundwater using bioelectrochemical systems. Sci Total Environ 613-614:663–671

    Article  CAS  Google Scholar 

  • Chamberlain JF, Sabatini DA (2014) Water-supply options in arsenic-affected regions in Cambodia: targeting the bottom income quintiles. Sci Total Environ 488:521–531

    Article  CAS  Google Scholar 

  • Çiftçi TD, Yayayürük O, Henden E (2011) Study of arsenic (III) and arsenic (V) removal from waters using ferric hydroxide supported on silica gel prepared at low pH. Environ Technol 32(3):341–351

    Article  CAS  Google Scholar 

  • Dalla Libera N, Fabbri P, Mason L, Piccinini L, Pola M (2017) Exceedance probability map: a tool helping the definition of arsenic natural background level (NBL) within the Drainage Basin to the Venice Lagoon (NE Italy). Geophys Res Abstr 19:EGU2017–EGU6388

    Google Scholar 

  • Duarte AA, Cardoso SJ, Alçada AJ (2009) Emerging and innovative techniques for arsenic removal applied to a small water supply system. Sustainability 1(4):1288–1304

    Article  CAS  Google Scholar 

  • Gentry PR, Clewell HJ, Greene TB, Franzen AC, Yager JW (2014) The impact of recent advances in research on arsenic cancer risk assessment. Regul Toxicol Pharmacol 69(1):91–104

    Article  CAS  Google Scholar 

  • Guo X, Fujino Y, Ye X, Liu J, Yoshimura T (2006) Association between multi-level inorganic arsenic exposure from drinking water and skin lesions in China. Int J Environ Res Public Health 3(3):262–267

    Article  CAS  Google Scholar 

  • Hering JG, Elimelech M (1995) International perspective on arsenic in groundwater: problems and treatment strategies, Proceedings of the American Water Works Association, Annual Conference. June 18–22

  • Jadhav SV, Bringas E, Yadav GD, Rathod VK, Ortiz I, Marathe KV (2015) Arsenic and fluoride contaminated groundwaters: a review of current technologies for contaminants removal. J Environ Manag 162:306–325

    Article  CAS  Google Scholar 

  • Jain CK, Ali I (2000) Arsenic occurrence, toxicity and speciation techniques. Water Res 34(17):4304–4312

    Article  CAS  Google Scholar 

  • Johnson DL, Pilson ME (1972) Spectrophotometric determination of arsenite, arsenate, and phosphate in natural waters. Anal Chim Acta 58(2):289–299

    Article  CAS  Google Scholar 

  • Joshi A, Chaudhuri M (1996) Removal of arsenic from ground water by iron oxide-coated sand. J Environ Eng 122(8):769–771

    Article  CAS  Google Scholar 

  • Kabir F, Chowdhury S (2017) Arsenic removal methods for drinking water in the developing countries: technological developments and research needs. Environ Sci Pollut Res 24(31):24102–24120

    Article  CAS  Google Scholar 

  • Katsoyiannis IA, Voegelin A, Zouboulis AI, Hug SJ (2015) Enhanced as (III) oxidation and removal by combined use of zero valent iron and hydrogen peroxide in aerated waters at neutral pH values. J Hazard Mater 297:1–7

    Article  CAS  Google Scholar 

  • Kundu S, Pal A, Ghosh SK, Mandal M, Pal T (2004) Removal of arsenic from water using hardened paste of Portland cement. Environ Technol 25(3):301–309

    Article  CAS  Google Scholar 

  • Liao L, Jean JS, Chakraborty S, Lee MK, Kar S, Yang HJ, Li Z (2016) Hydrogeochemistry of groundwater and arsenic adsorption characteristics of subsurface sediments in an alluvial plain, SW Taiwan. Sustainability. 8(12):1305

    Article  CAS  Google Scholar 

  • Liao X, Wu Z, Ma X, Gong X, Yan X (2017) Interactive effects of PAHs with different rings and As on their uptake, transportation, and localization in As hyperaccumulator. Environ Sci Pollut Res 24(33):26136–26141

    Article  CAS  Google Scholar 

  • Litter MI, Alarcón-Herrera MT, Arenas MJ, Armienta MA, Avilés M, Cáceres RE, Cipriani HN, Cornejo L, Dias LE, Fernández Cirelli A, Farfán EM, Garrido L, Lorenzo L, Morgada ME, Olmos-Márquez MA (2012) Small-scale and household methods to remove arsenic from water for drinking purposes in Latin America. Sci Total Environ 429:107–122

    Article  CAS  Google Scholar 

  • Maduabuchi JM, Adigba EO, Nzegwu CN, Oragwu CI, Okonkwo IP, Orisakwe OE (2007) Arsenic and chromium in canned and non-canned beverages in Nigeria: a potential public health concern. Int J Environ Res Public Health 4(1):28–33

    Article  CAS  Google Scholar 

  • Martin DF, Martin BB, Alldredge R (2008) Arsenic, nitrate, and perchlorate in water – dangers, distribution, and removal. Bull Hist Chem 33(1):17–24

    CAS  Google Scholar 

  • Martin R, Dowling K, Pearce D, Sillitoe J, Florentine S (2014) Health effects associated with inhalation of airborne arsenic arising from mining operations. Geosciences 4(3):128–175

    Article  Google Scholar 

  • McGuigan CF, Hamula CLA, Huang S, Gabos S, Le XC (2010) A review on arsenic concentrations in Canadian drinking water. Environ Rev 18:291–307

    Article  CAS  Google Scholar 

  • Mehta VS, Chaudhari SK (2015) Arsenic removal from simulated groundwater using household filter columns containing iron filings and sand. J Water Proc Eng 6:151–157

    Article  Google Scholar 

  • Molognoni D, Devecseri M, Cecconet D, Capodaglio AG (2017) Cathodic groundwater denitrification with a bioelectrochemical system. J Water Proc Eng 19:67–73

    Article  Google Scholar 

  • Montgomery MA, Elimelech M (2007) Water and sanitation in developing countries: including health in the equation. Environ Sci Technol 41(1):17–24

    Article  Google Scholar 

  • National Research Council-NRC (1999) Arsenic in drinking water. National Academy of Sciences, National Research Council Report, Washington DC. USA

  • Pandey PK, Yadav S, Pandey M (2007) Human arsenic poisoning issues in central-east Indian locations: biomarkers and biochemical monitoring. Int J Environ Res Public Health 4(1):15–22

    Article  CAS  Google Scholar 

  • Pous N, Casentini B, Rossetti S, Fazi S, Puig S, Aulenta F (2015) Anaerobic arsenite oxidation with an electrode serving as the sole electron acceptor: a novel approach to the bioremediation of arsenic-polluted groundwater. J Hazard Mater 283:617–622

    Article  CAS  Google Scholar 

  • Rahman MM, Asaduzzaman M, Naidu R (2013a) Consumption of arsenic and other elements from vegetables and drinking water from an arsenic-contaminated area of Bangladesh. J Hazard Mater 262:1056–1063

    Article  CAS  Google Scholar 

  • Rahman IM, Begum ZA, Sawai H, Maki T, Hasegawa H (2013b) Decontamination of spent iron-oxide coated sand from filters used in arsenic removal. Chemosphere 92(2):196–200

    Article  CAS  Google Scholar 

  • Rasool A, Xiao T, Farooqi A, Shafeeque M, Liu Y, Kamran MA et al (2017) Quality of tube well water intended for irrigation and human consumption with special emphasis on arsenic contamination at the area of Punjab, Pakistan. Environ Geochem health 39(4):847–863

    Article  CAS  Google Scholar 

  • Ratnaike RN (2003) Acute and chronic arsenic toxicity. Postgrad Med J 79(933):391–396

    Article  CAS  Google Scholar 

  • Sankar MS, Vega MA, Defoe PP, Kibria MG, Ford S, Telfeyan K, Neal A, Mohajerin TJ, Hettiarachchi GM, Barua S, Hobson C, Johannesson K, Datta A (2014) Elevated arsenic and manganese in groundwaters of Murshidabad, West Bengal, India. Sci Total Environ 488:570–579

    Article  CAS  Google Scholar 

  • Smith AH, Goycolea M, Haque R, Biggs ML (1998) Marked increase in bladder and lung cancer mortality in a region of Northern Chile due to arsenic in drinking water. Am J Epidemiol 147:660–669

    Article  CAS  Google Scholar 

  • Stauder S, Stevanovic Z, Richter C, Milanovic S, Tucovic A, Petrovic B (2012) Evaluating bank filtration as an alternative to the current water supply from deeper aquifer: a case study from the Pannonian Basin, Serbia. Water Resour Manag 26(2):581–594

    Article  Google Scholar 

  • Thakur JK, Thakur RK, Ramanathan AL, Kumar M, Singh SK (2010) Arsenic contamination of groundwater in Nepal—an overview. Water 3(1):1–20

    Article  CAS  Google Scholar 

  • Thirunavukkarasu OS, Viraraghavan T, Subramanian KS (2003) Arsenic removal from drinking water using iron oxide-coated sand. Water Air Soil Pollut 142(1):95–111

    Article  CAS  Google Scholar 

  • Torretta V (2013) Environmental and economic aspects of water kiosks: case study of a medium-sized Italian town. Waste Manag 33(5):1057–1063

    Article  Google Scholar 

  • US-EPA (2001) Treatment of arsenic residuals from drinking water removal processes. United States Environmental Protection Agency, Office of Research Development, Washington, DC 20460, EPA/600/R-01/033

  • US-EPA (2011) Costs of arsenic removal technologies for small water systems. U.S. EPA arsenic removal technology demonstration program, Washington DC 20460, EPA/600/R-11/090

  • Villholth KG, Rajasooriyar LD (2010) Groundwater resources and management challenges in Sri Lanka—an overview. Water Res Manag 24(8):1489–1513

    Article  Google Scholar 

  • World Health Organization-WHO (2011) Arsenic in drinking-water. Background document for development of WHO Guidelines for Drinking-water Quality. World Health Organization, Washington, DC

    Google Scholar 

  • Xia Y, Wade TJ, Wu K, Li Y, Ning Z, Le XC, He X, Chen B, Feng Y, Mumford JL (2009) Well water arsenic exposure, arsenic induced skin-lesions and self-reported morbidity in Inner Mongolia. Int J Environ Res Public Health 6(3):1010–1025

    Article  CAS  Google Scholar 

  • Zouboulis AI, Katsoyiannis IA (2005) Recent advances in the bioremediation of arsenic-contaminated groundwaters. Environ Int 31:213–219

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Civil Engineering and Architecture, University of Pavia, Via Ferrata 3, 27100, Pavia, Italy

    Arianna Callegari & Andrea G. Capodaglio

  2. Department of Theoretical and Applied Sciences, University of Insubria, Via G.B. Vico 46, 21100, Varese, Italy

    Navarro Ferronato, Elena Cristina Rada & Vincenzo Torretta

Authors
  1. Arianna Callegari
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  2. Navarro Ferronato
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  3. Elena Cristina Rada
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  4. Andrea G. Capodaglio
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  5. Vincenzo Torretta
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Correspondence to Vincenzo Torretta.

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The authors declare that they have no conflict of interests.

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Responsible editor: Ioannis A. Katsoyiannis

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Callegari, A., Ferronato, N., Rada, E.C. et al. Assessment of arsenic removal efficiency by an iron oxide-coated sand filter process. Environ Sci Pollut Res 25, 26135–26143 (2018). https://doi.org/10.1007/s11356-018-2674-y

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  • DOI: https://doi.org/10.1007/s11356-018-2674-y

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