Abstract
Tributyltin is listed as one of the priority substances in the European Water Framework Directive (WFD). Despite its decreasing input in the environment, it is still present and has to be monitored. In the European Metrology Research Programme project ENV08, a sensitive and reliable analytical method according to the WFD was developed to quantify this environmental pollutant at a very low limit of quantification. With the development of such a primary reference method for tributyltin, the project helped to improve the quality and comparability of monitoring data. An overview of project aims and potential analytical tools is given.
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Aguerre S, Lespes G, Desauziers V, Potin-Gautier M (2001) Speciation of organotins in environmental samples by SPME-GC: comparison of four specific detectors: FPD, PFPD, MIP-AES and ICP-MS. J Anal At Spectrom 16:263–269
Alasonati E, Fabbri B, Fettig I, Yardin C, Del Castillo Busto ME, Richter J, Philipp R, Fisicaro P (2015) Experimental design for TBT quantification by isotope dilution SPE–GC–ICP–MS under the European water framework directive. Talanta 134:576–586. doi:10.1016/j.talanta.2014.11.064
Bhosle NB, Garg A, Jadhav S, Harjee R, Sawant SS, Venkat K, Anil AC (2004) Butyltins in water, biofilm, animals and sediments of the west coast of India. Chemosphere 57:897–907. doi:10.1016/j.chemosphere.2004.06.037
BIPM (1998) Proceedings of the 4th meeting of CCQM
Centineo G, Rodríguez-González P, González E, García Alonso JI, Sanz-Medel A, Cardona N, Aranda Mares J, Nebot S (2006) Isotope dilution GC-MS routine method for the determination of butyltin compounds in water. Anal Bioanal Chem 384:908–914. doi:10.1007/s00216-005-0061-2
Clough R, Harrington CF, Hill SJ, Madrid Y, Tyson JF (2013) Atomic spectrometry update. Elemental speciation review. J Anal At Spectrom 28:1153–1195. doi:10.1039/c3ja90039h
Coscollà C, Navarro-Olivares S, Martí P, Yusà V (2014) Application of the experimental design of experiments (DoE) for the determination of organotin compounds in water samples using HS-SPME and GC–MS/MS. Talanta 119:544–552. doi:10.1016/j.talanta.2013.11.052
de Carvalho Oliveira R, Santelli RE (2010) Occurrence and chemical speciation analysis of organotin compounds in the environment: a review. Talanta 82:9–24. doi:10.1016/j.talanta.2010.04.046
Devos C, David F, Sandra P (2012) A new validated analytical method for the determination of tributyltin in water samples at the quantification level set by the European Union. J Chromatogr A 1261:151–157. doi:10.1016/j.chroma.2012.07.072
Encinar JR, Monterde Villar MI, Santamaría VG, García Alonso JI, Sanz-Medel A (2001) Simultaneous determination of mono-, di-, and tributyltin in sediments by isotope dilution analysis using gas chromatography—ICPMS. Anal Chem 73:3174–3180. doi:10.1021/ac010147o
European Communities (22.12.2000) Directive 2000/60/EC of the European Parliament and of the Council of 23 October 2000 establishing a framework for community action in the field of water policy. J Eur Union 43:1
European Communities (24.12.2008) Directive 2008/105/EC of the European Parliament and of the Council of 16 December 2008 on environmental quality standards in the field of water policy, amending and subsequently repealing Council Directives 82/176/EEC, 83/513/EEC, 84/156/EEC, 84/491/EEC, 86/280/EEC and amending Directive 2000/60/EC of the European Parliament and of the Council Official. J Eur Union 105:1
Graceli JB, Sena GC, Lopes PFI, Zamprogno GC, da Costa MB, Godoi AFL, dos Santos DM, de Marchi MRR, dos Santos Fernandez MA (2013) Organotins: a review of their reproductive toxicity, biochemistry, and environmental fate. Reprod Toxicol 36:40–52. doi:10.1016/j.reprotox.2012.11.008
Hoch M (2001) Organotin compounds in the environment—an overview. Appl Geochem 16:719–743. doi:10.1016/S0883-2927(00)00067-6
Hoch M, Schwesig D (2004) Parameters controlling the partitioning of tributyltin (TBT) in aquatic systems. Appl Geochem 19:323–334. doi:10.1016/S0883-2927(03)00131-8
ISO/IEC 17025:2005 General requirements for the competence of testing and calibration laboratories
Lepom P, Brown B, Hanke G, Loos R, Quevauviller P, Wollgast J (2009) Needs for reliable analytical methods for monitoring chemical pollutants in surface water under the European Water Framework Directive. J Chromatogr A 1216:302–315. doi:10.1016/j.chroma.2008.06.017
Peeters K, Iskra J, Zuliani T, Scancar J, Milacic R (2014) The micro-scale synthesis of Sn-117-enriched tributyltin chloride and its characterization by GC-ICP-MS and NMR techniques. Chemosphere 107:386–392. doi:10.1016/j.chemosphere.2014.01.003
Rodriguez-Gonzalez P, Garcia Alonso JI, Sanz-Medel A (2005) Single and multiple spike procedures for the determination of butyltin compounds in sediments using isotope dilution GC-ICP-MS. J Anal At Spectrom 20:1076–1084. doi:10.1039/b505653e
Rüdel H (2003) Case study: bioavailability of tin and tin compounds. Ecotoxicol Environ Saf 56:180–189. doi:10.1016/S0147-6513(03)00061-7
Segovia-Martínez L, Bouzas-Blanco A, Campíns-Falcó P, Seco-Torrecillas A (2010) Improving detection limits for organotin compounds in several matrix water samples by derivatization-headspace-solid-phase microextraction and GC–MS. Talanta 80:1888–1893. doi:10.1016/j.talanta.2009.10.039
Strand J, Glahder CM, Asmund G (2006) Imposex occurrence in marine whelks at a military facility in the high Arctic. Environ Pollut 142:98–102. doi:10.1016/j.envpol.2005.09.014
Sutton PG, Harrington CF, Fairman B, Evans EH, Ebdon L, Catterick T (2000) The small-scale preparation and NMR characterization of isotopically enriched organotin compounds. Appl Organomet Chem 14:691–700. doi:10.1002/1099-0739(200011)14:11<691::aid-aoc62>3.0.co;2-l
Taylor P, Kipphardt H, De Bièvre P (2001) The definition of primary method of measurement (PMM) of the ‘highest metrological quality’: a challenge in understanding and communication. Accred Qual Assur 6:103–106. doi:10.1007/pl00010444
Xiao Q, Hu B, He M (2008) Speciation of butyltin compounds in environmental and biological samples using headspace single drop microextraction coupled with gas chromatography-inductively coupled plasma mass spectrometry. J Chromatogr A 1211:135–141. doi:10.1016/j.chroma.2008.09.089
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The ENV08 project was conducted under the European Metrology Research Programme (EMRP). The EMRP is jointly funded by the EMRP participating countries within EURAMET and the European Union.
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Richter, J., Fettig, I., Philipp, R. et al. Tributyltin—critical pollutant in whole water samples—development of traceable measurement methods for monitoring under the European Water Framework Directive (WFD) 2000/60/EC. Environ Sci Pollut Res 22, 9589–9594 (2015). https://doi.org/10.1007/s11356-015-4614-4
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DOI: https://doi.org/10.1007/s11356-015-4614-4