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Behaviors of Organic and Heavy Metallic Pollutants during Supercritical Water Oxidation of Oil-Based Drill Cuttings

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Abstract

Oil-based drill cuttings (OBDCs), which contain various petroleum hydrocarbons, heavy metals, and alkaline salts, will significantly affect the local ecosystem if left untreated. Supercritical water oxidation (SCWO) is regarded as a potential end-of-pipe technology that is able to degrade organic compounds, stabilize heavy metals, and neutralize alkaline salts simultaneously. In this paper, SCWO of OBDCs was carried out using a batch reactor. Six organic compounds and eight elements were selected as representatives of the petroleum hydrocarbons and heavy metals, respectively, in OBDCs. The effects of the oxygen coefficient (OC), temperature (T), and reaction time (t) on the degradation of petroleum hydrocarbons and the stabilization of heavy metals were evaluated in detail. The results indicated that nearly 100% of naphthalenes and more than 97% of alkanes could be destroyed when T > 475 °C, t > 2 min, and OC > 2.5. The elements Ba, Cr, and Pb were almost completely stabilized in the solid products, and small amounts of Zn and Cu were detected in the liquid products. More than the original contents of Fe, Cr, and Ni were found in the solid products due to the corrosion of the SCWO reactor. The content of alkaline salt in the feed was too low to affect the pH of the liquid products. The results of X-ray diffractometer (XRD) and scanning electron microscope (SEM) analyses suggested that SCWO can efficiently remove organic pollutants from OBDCs but does not obviously affect the microstructure and composition of the inorganic compounds.

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References

  • Annevelink, M., Meesters, J., & Hendriks, A. (2016). Environmental contamination due to shale gas development. Science of the Total Environment, 550, 431–438.

    Article  CAS  Google Scholar 

  • ASME. (2011). Drilling fluids processing handbook. Boston: Elsevier.

    Google Scholar 

  • Ball, A. S., Stewart, R. J., & Schliephake, K. (2012). A review of the current options for the treatment and safe disposal of drill cuttings. Waste Management & Research., 30, 457–473.

    Article  CAS  Google Scholar 

  • Chen, Z., Wang, G., Yin, F., Chen, H., & Xu, Y. (2015). A new system design for supercritical water oxidation. Chemical Engineering Journal., 269, 343–351.

    Article  CAS  Google Scholar 

  • Chen, H., Wang, G., Xu, Y., Chen, Z., & Yin, F. (2016a). Application of red mud as both neutralizer and catalyst in supercritical water oxidation (SCWO) disposal of sewage sludge. RSC Advances., 6, 54202–54214.

    Article  CAS  Google Scholar 

  • Chen, J., Wang, Y., Ding, S., Ding, J., Li, M., Zhang, C., & Zou, M. (2016b). Sub- and super-critical water oxidation of wastewater containing organic and heavy metallic pollutants and recovery of superfine metallic particles. Journal of Environmental Chemical Engineering., 4, 2698–2705.

    Article  CAS  Google Scholar 

  • Chen, Z., Chen, Z., Yin, F., Wang, G., Chen, H., He, C., & Xu, Y. (2017a). Supercritical water oxidation of oil-based drill cuttings. Journal of Hazardous Materials., 332, 205–213.

    Article  CAS  Google Scholar 

  • Chen, Z., Chen, Z., Chen, Q., Yao, G., Tan, Y., & Xu, Y. (2017b). Composition analysis and risk assessment of typical oil-based drill cuttings from shale gas fields. Environmental Engineering, 35, 125–129 (in Chinese).

    Google Scholar 

  • Cui, B., Cui, F., Jing, G., Xu, S., Huo, W., & Liu, S. (2009). Oxidation of oily sludge in supercritical water. Journal of Hazardous Materials, 165, 511–517.

    Article  CAS  Google Scholar 

  • Cui, B., Liu, S., Cui, F., Jing, G., & Liu, X. (2011). Lumped kinetics for supercritical water oxidation of oily sludge. Process Safety and Environmental Protection, 89, 198–203.

    Article  CAS  Google Scholar 

  • Dong, X., Gan, Z., Lu, X., Jin, W., Yu, Y., & Zhang, M. (2015). Study on catalytic and non-catalytic supercritical water oxidation of p-nitrophenol wastewater. Chemical Engineering Journal, 277, 30–39.

    Article  CAS  Google Scholar 

  • Du, X., Zhang, R., Gan, Z., & Bi, J. (2013). Treatment of high strength coking wastewater by supercritical water oxidation. Fuel, 104, 77–82.

    Article  CAS  Google Scholar 

  • Fedyaeva, O. N., & Vostrikov, A. A. (2012). Disposal of hazardous organic substances in supercritical water. Russian Journal of Physical Chemistry B., 6, 844–860.

    Article  CAS  Google Scholar 

  • Gong, Y. M., Wang, S. Z., Tang, X. Y., Xu, D. H., & Ma, H. H. (2014). Supercritical water oxidation of acrylic acid production wastewater. Environmental Technology., 35, 907–916.

    Article  CAS  Google Scholar 

  • Gong, Y., Guo, Y., Wang, S., & Song, W. (2016). Supercritical water oxidation of quinazoline: effects of conversion parameters and reaction mechanism. Water Research, 100, 116–125.

    Article  CAS  Google Scholar 

  • Jin, F. M., Moriya, T., & Enomoto, H. (2003). Oxidation reaction of high molecular weight carboxylic acids in supercritical water. Environmental Science & Technology., 37, 3220–3231.

    Article  CAS  Google Scholar 

  • Jin, F., Zeng, X., Cao, J., Kawasaki, K., Kishita, A., Tohji, K., & Enomoto, H. (2010). Partial hydrothermal oxidation of unsaturated high molecular weight carboxylic acids for enhancing the cold flow properties of biodiesel fuel. Fuel, 89, 2448–2454.

    Article  CAS  Google Scholar 

  • Kogbara, R. B. (2013). A review of the mechanical and leaching performance of stabilized/solidified contaminated soils. Environmental Reviews., 22, 66–86.

    Article  Google Scholar 

  • Kogbara, R. B., Al-Tabbaa, A., & Stegemann, J. A. (2014). Comparisons of operating envelopes for contaminated soil stabilised/solidified with different cementitious binders. Environmental Science and Pollution Research., 21, 3395–3414.

    Article  CAS  Google Scholar 

  • Kogbara, R. B., Ayotamuno, J. M., Onuomah, I., Ehio, V., & Damka, T. D. (2016). Stabilisation/solidification and bioaugmentation treatment of petroleum drill cuttings. Applied Geochemistry, 71, 1–8.

    Article  CAS  Google Scholar 

  • Leonard, S. A., & Stegemann, J. A. (2010). Stabilization/solidification of petroleum drill cuttings. Journal of Hazardous Materials., 174, 463–472.

    Article  CAS  Google Scholar 

  • Liu, K., Zhang, Z., & Zhang, F. (2016). Direct extraction of palladium and silver from waste printed circuit boards powder by supercritical fluids oxidation-extraction process. Journal of Hazardous Materials., 318, 216–223.

    Article  CAS  Google Scholar 

  • O'Brien, C. P., Thies, M. C., & Bruce, D. A. (2005). Supercritical water oxidation of the PCB congener 2-chlorobiphenyl in methanol solutions: a kinetic analysis. Environmental Science & Technology., 39, 6839–6844.

    Article  Google Scholar 

  • Onwudili, J. A., & Williams, P. T. (2007). Reaction mechanisms for the decomposition of phenanthrene and naphthalene under hydrothermal conditions. Journal of Supercritical Fluids., 39, 399–408.

    Article  CAS  Google Scholar 

  • Robinson, J. P., Kingman, S. W., Snape, C. E., Barranco, R., Shang, H., Bradley, M. S. A., & Bradshaw, S. M. (2009). Remediation of oil-contaminated drill cuttings using continuous microwave heating. Chemical Engineering Journal., 152, 458–463.

    Article  CAS  Google Scholar 

  • Sánchez-Oneto, J., Portela, J. R., Nebot, E., & Martínez de la Ossa, E. (2007). Hydrothermal oxidation: application to the treatment of different cutting fluid wastes. Journal of Hazardous Materials., 144, 639–644.

    Article  Google Scholar 

  • Shin, Y. H., Lee, H.-S., Lee, Y.-H., Kim, J., Kim, J.-D., & Lee, Y.-W. (2009). Synergetic effect of copper-plating wastewater as a catalyst for the destruction of acrylonitrile wastewater in supercritical water oxidation. Journal of Hazardous Materials., 167, 824–829.

    Article  CAS  Google Scholar 

  • Watanabe, M., Mochiduki, M., Sawamoto, S., Adschiri, T., & Arai, K. (2001). Partial oxidation of n-hexadecane and polyethylene in supercritical water. Journal of Supercritical Fluids., 20, 257–266.

    Article  CAS  Google Scholar 

  • Xiu, F.-R., Qi, Y., & Zhang, F.-S. (2015). Leaching of Au, Ag, and Pd from waste printed circuit boards of mobile phone by iodide lixiviant after supercritical water pre-treatment. Waste Management., 41, 134–141.

    Article  CAS  Google Scholar 

  • Xu, D., Huang, C., Wang, S., Lin, G., & Guo, Y. (2015). Salt deposition problems in supercritical water oxidation. Chemical Engineering Journal., 279, 1010–1022.

    Article  CAS  Google Scholar 

  • Yan, P., Lu, M., Guan, Y., Zhang, W., & Zhang, Z. (2011). Remediation of oil-based drill cuttings through a biosurfactant-based washing followed by a biodegradation treatment. Bioresource technology., 102, 10252–10259.

    Article  CAS  Google Scholar 

  • Yoko, A., & Oshima, Y. (2013). Recovery of silicon from silicon sludge using supercritical water. Journal of Supercritical Fluids., 75, 1–5.

    Article  CAS  Google Scholar 

  • Zhang, S., Zhang, Z., Zhao, R., Gu, J., Liu, J., Ormeci, B., & Zhang, J. (2017). A review of challenges and recent progress in supercritical water oxidation of wastewater. Chemical Engineering Communications., 204, 265–282.

    Article  CAS  Google Scholar 

  • Zou, D., Chi, Y., Dong, J., Fu, C., Wang, F., & Ni, M. (2013a). Supercritical water oxidation of tannery sludge: stabilization of chromium and destruction of organics. Chemosphere, 93, 1413–1418.

    Article  CAS  Google Scholar 

  • Zou, D., Chi, Y., Fu, C., Dong, J., Wang, F., & Ni, M. (2013b). Co-destruction of organic pollutants in municipal solid waste leachate and dioxins in fly ash under supercritical water using H2O2 as oxidant. Journal of Hazardous Materials., 248–249, 177–184.

    Article  Google Scholar 

  • Zou, D., Chi, Y., Dong, J., Fu, C., & Ni, M. (2014). Supercritical water oxidation of MSW leachate: factor analysis and behavior of heavy metals. Environmental Progress & Sustainable Energy., 33, 1117–1124.

    CAS  Google Scholar 

Download references

Funding

This work was financially supported by the fundamental and frontier planning program of Chongqing (cstc2015jcyjA20010), the science and technology planning program of Land Resource and House Management Office of Chongqing (CQGT-KJ-2014040), and the Open Project Program of State Key Laboratory of Petroleum Pollution Control (PPC2016001), CNPC Research Institute of Safety and Environmental Technology.

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Authors and Affiliations

  1. Chongqing Mineral Resources Development Company Limited, Chongqing, 401123, People’s Republic of China

    Guanghua Yao, Zhong Chen, Qiao Chen, Dongyuan Li, Zhiguo Xie, You Zhou, Xin Xiong & Yuanjian Xu

  2. Environmentally-Benign Chemical Process Research Center, Chongqing Institute of Green and Intelligent Technology (CIGIT), Chinese Academy of Sciences, No.266 Fangzheng Avenue, Beibei District, Chongqing, 400714, People’s Republic of China

    Guanghua Yao, Zhong Chen, Qiao Chen, Zhiguo Xie, You Zhou, Xin Xiong & Yuanjian Xu

  3. University of Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China

    Zhong Chen & Yuanjian Xu

  4. Shandong KERUI Oilfield Service Group Co., Ltd, Dongying, 257100, People’s Republic of China

    Dongyuan Li

Authors
  1. Guanghua Yao
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  2. Zhong Chen
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  3. Qiao Chen
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  4. Dongyuan Li
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  5. Zhiguo Xie
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  6. You Zhou
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  7. Xin Xiong
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  8. Yuanjian Xu
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Corresponding authors

Correspondence to Zhong Chen or Yuanjian Xu.

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Yao, G., Chen, Z., Chen, Q. et al. Behaviors of Organic and Heavy Metallic Pollutants during Supercritical Water Oxidation of Oil-Based Drill Cuttings. Water Air Soil Pollut 229, 102 (2018). https://doi.org/10.1007/s11270-018-3751-z

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  • DOI: https://doi.org/10.1007/s11270-018-3751-z

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