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Spatially Resolved Triboemission Measurements

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Abstract

Electron emission that occurs when surfaces undergo wear has been studied since the 1950s and is the subject of continued speculation due to its possibly crucial role in the formation of boundary lubricating films and the degradation of hard drive lubricants. Despite this, the mechanisms by which this type of emission occurs are poorly understood. In order to shed light on this phenomenon, we report for the first time how friction-stimulated electron emission can be visualized, by scratching an aluminium oxide surface, positioned 10 mm from a microchannel plate (MCP) in a high vacuum. The MCP is coupled with a phosphor screen displaying the spatial distribution of electrons that are emitted in individual bursts as wear is accruing. The probability density of this emission was calculated and the Shannon spectral entropy for a 10-ms time window was found to be 0.11, suggesting that partially deterministic mechanisms are responsible. These emission maps help to elucidate the obscure mechanisms that cause emission, in a way that has not been possible with previous spatially averaged measurements. For example, linear distributions support the theory that electron emission arises due to the formation of surface cracks. In addition to this, as the contact moves over the specimen surface, certain locations show an increased propensity to emit, which further suggests the presence of localized defects. Furthermore, in certain cases, sustained after-emission is observed from localized defects exiting the contact. These results highlight the possibility of using the technique to monitor very low levels of wear and even image crack formation in real time.

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References

  1. Kajdas, C., Furey, M.J., Ritter, A.L., Molina, G.J.: Triboemission as a basic part of the boundary friction regime. Lubr. Sci. 14, 223–254 (2002)

    Article  Google Scholar 

  2. Baxter, W.J.: A study of plastic deformation by exoelectron emission. Vacuum 22, 571–575 (1972)

    Article  Google Scholar 

  3. Becker, K.: Stimulated exoelectron emission from the surface of insulating solids. Crit. Rev. Solid State Sci. 3, 39–81 (1972)

    Article  Google Scholar 

  4. Furey, M.J., Kajdas, C., Kempinski, R., Tripathy, B.: Action mechanism of selected vinyl monomers under boundary lubrication of an alumina-on-alumina system. Lubr. Sci. 10, 3–25 (1997)

    Google Scholar 

  5. Furey, M.J., Kajdas, C.: Tribopolymerization as a Mechanism of Boundary Lubrication. Surface Modification and Mechanisms, Chap. 7. In: Totten G.E., Liang H. (eds.) Marcel-Dekker, New York, pp. 165–201 (2004)

  6. Spikes, H.A.: The history and mechanisms of ZDDP. Tribol. Lett. 17, 469–489 (2004)

    Article  Google Scholar 

  7. Zhoa, X., Bhushan, B.: Studies on degradation mechanisms of lubricants for magnetic thin-film rigid disks. Proc. Inst. Mech. Eng. Part J. Eng. Tribol. 215, 173–188 (2001)

    Article  Google Scholar 

  8. Ishihara, T., Tanaka, K., Fujita, K., Hirao, K., Soga, N.: Full color triboluminescence of rare-earth-doped hexacelsian (BaAl2Si2O8). Solid State Commun. 107, 763–767 (1998)

    Article  Google Scholar 

  9. James, M.R., Wilson, L., Lane, S.J., Gilbert, J.S., Mather, T.A., Harrison, R.G., Martin, R.S.: Electrical charging of volcanic plumes. Space Sci. Rev. 137, 399–418 (2008)

    Article  Google Scholar 

  10. Grunberg, L.: A survey of exo-electron emission phenomena. Br. J. Appl. Phys. 9, 85–93 (1958)

    Article  Google Scholar 

  11. Nakayama, K., Hashimoto, H.: Triboemission from various materials in atmosphere. Wear 147, 335–343 (1991)

    Article  Google Scholar 

  12. Nakayama, K., Suzuki, N., Hashimoto, H.: Triboemission of charged particles and photons from solid surfaces during frictional damage. J. Phys. D Appl. Phys. 25, 303–308 (1992)

    Article  Google Scholar 

  13. Kim, M., Langford, S.C., Dickinson, J.T.: Electron and photon emission accompanying the abrasion of MgO with diamond. Tribol. Lett. 1, 147–157 (1995)

    Article  Google Scholar 

  14. Molina, G.J., Furey, M.J., Ritter, A.L., Kajdas, C.: Triboemission from alumina, single crystal sapphire, and aluminium. Wear 249, 214–219 (2001)

    Article  Google Scholar 

  15. Molina, G.J., Furey, M.J., Ritter, A.L., Kajdas, C.: Frequency analysis and modeling of charged-particle triboemission from ceramics. Wear 255, 686–694 (2003)

    Article  Google Scholar 

  16. Molina, G.J., Furey, M.J., Kajdas, C.: A deterministic-chaos study of electron triboemission outputs. J. Tribol. 129, 679–683 (2007)

    Article  Google Scholar 

  17. Nakayama, K., Bou-Said, B., Ikeda, H.: Tribo-electromagnetic phenomena of hydrogenated carbon films. Tribo-electrons, -ions, -photons and -charging. Trans. ASME J. Tribol. 119, 764–768 (1997)

    Article  Google Scholar 

  18. Dickinson, J.T., Jensen, L.C., Jahan-Latibari, A.: Fracto-emission: the role of charge separation. J. Vac. Sci. Technol. A A2, 1112–1116 (1983)

    Google Scholar 

  19. Nakayama, K., Nevshupa, R.A.: Plasma generation in a gap around a sliding contact. J. Phys. D Appl. Phys. 35, L53–L56 (2002)

    Article  Google Scholar 

  20. Nakayama, K.: Triboplasma generation and triboluminescence: influence of stationary sliding partner. Tribol. Lett. 37, 215–228 (2010)

    Article  Google Scholar 

  21. Matta, C., Eryilmaz, O.L., De Barros Bouchet, M.I., Erdemir, A., Martin, J.M., Nakayama, K.: On the possible role of triboplasma in friction and wear of diamond-like carbon films in hydrogen-containing environments. J. Phys D Appl. Phys. 42, 075307 (2009)

    Article  Google Scholar 

  22. Nakayama, K.: Triboemission from wearing solid surfaces, in ITC Proceedings, Satellite Forum on Tribochemistry, October 28, Tokyo, Japan (1995)

  23. Dickinson, J.T., Scudiero, L., Yasuda, K., Kim, M.-W., Langford, S.C.: Dynamic tribological probes: particle emission and transient electrical measurements. Tribol. Lett. 3, 53–67 (1997)

    Article  Google Scholar 

  24. Molina, G.J., Mazilu, D.A., Furey, M.J., Kajdas, C.: On Tribo-Emission From the Sliding Contact of Si and Ge. The Annals of University “Dunarea De Jos” of Galat i, Romania, VIII (Tribology), pp. 22–29 (2004)

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Acknowledgments

This work was funded through the European Metrology Research Programme (EMRP) Project IND11 MADES. The EMRP is jointly funded by the EMRP participating countries within EURAMET and the European Union. The authors are also very grateful to Dr. Clive Hamer of PCS Instruments for providing the custom-built tribometer adapted in this work and to Professor Iain Baikie of KP Technology (Wick, UK) for insightful discussions.

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Le Rouzic, J., Reddyhoff, T. Spatially Resolved Triboemission Measurements. Tribol Lett 55, 245–252 (2014). https://doi.org/10.1007/s11249-014-0352-x

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