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Synthesis and Catalytic Activity of Heterogenous Hybrid Nanocatalyst of Copper/Palladium MOF, RIT 62-Cu/Pd for Stille Polycondensation of Thieno[2,3-b]pyrrol-5-One Derivatives

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Abstract

In the present work, Cu/Pd based MOF (RIT 62-Cu/Pd) with new organic linker was synthesied using solvothermal method and the synthesized MOF was characterized by X-ray diffraction analysis (XRD), Field Emission Scanning Electron Microscope (FE-SEM) and Fourier transform infrared (FT-IR) spectroscopy. The average particle size of the synthesized MOF RIT 62-Cu were 195 nm and MOF RIT 62-Cu/Pd were between 250 to 320 nm. Thermal analysis studies indicated that the synthesized MOFs were stable upto 500 °C. In the present work, the synthesized MOF RIT 62-Cu/Pd was used as a hybrid nanocatalyst for Stille polycondensation of thieno[2,3-b]pyrrol-5-one derivatives with three different donating groups. The resulting three polymers were characterized by ultraviolet–visible spectrophotometer (UV–Vis), gel permeation chromatography (GPC). The thermal stability of these polymers were studied using thermogravimetric analysis (TGA) and results indicate that polymers are stable upto 460 °C. Further, the reusability of synthesized MOFs showed best catalytic performance in Stille polycondensation with 82.56% polymer yield while the recyclability of the hybrid nanocatalyst was 81.25% at the end of three successive cycle.

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Data Availability

Data that are available for the present study enclosed in the supplementary information and more data can be obtained from the corresponding author by request email.

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Acknowledgements

Authors are thankful to M. S. Ramaiah University of Applied Sciences, Bangalore for providing basic facilities. Authors also acknowledge their thankfulness to Centre for Nano and Soft Materials, Bangalore, Ramaiah Institute of Technology(RIT), Bangalore and IISc, Bangalore for providing the characterization facilities.

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Authors and Affiliations

  1. Department of Chemistry, M. S. Ramaiah University of Applied Sciences, Bangalore, Karnataka, 560058, India

    M. Maya Pai & Sheetal R. Batakurki

  2. Department of Chemistry, M.S. Ramaiah Institute of Technology (Affiliated to VTU), Bangalore, Karnataka, 560054, India

    Basappa C. Yallur

  3. Department of Chemistry, Angadi Institute of Technology and Management (AITM), Belagavi, Karnataka, 590009, India

    Vinayak Adimule

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Contributions

Dr. Sheetal R Batakurki has conceived the work, carried out characterization and contributed in drafting the manuscript. Mrs. Maya Pai M has carried the synthesis of polymers. Dr. Basappa Yallur has designed and synthesised the MOFs. Dr. Vinayak Adimule has contributed for the characterization of the synthesised polymers and partly by manuscript preparation.

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Correspondence to Basappa C. Yallur or Sheetal R. Batakurki.

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Maya Pai, M., Yallur, B.C., Batakurki, S.R. et al. Synthesis and Catalytic Activity of Heterogenous Hybrid Nanocatalyst of Copper/Palladium MOF, RIT 62-Cu/Pd for Stille Polycondensation of Thieno[2,3-b]pyrrol-5-One Derivatives. Top Catal (2022). https://doi.org/10.1007/s11244-022-01618-1

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