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Designing Phase Selectively Soluble Polymer-Supports for Dimethylaminopyridine and Phosphine-Ligated Pd(0) Catalysts

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Abstract

Soluble poly(4-alkylstyrene) containing 4-methyl-, 4-tert-butyl, 4-dodecyl-, and 4-octadecylstyrene were formed either with monomers containing dyes-, ligands, or catalysts or with 5–10 mol% of 4-chloromethylstyrene and studied as supports for ligands or catalysts. Studies with dye-labeled polymers showed that polymers containing longer alkyl groups alone or at ca. 10 mol% loading are highly soluble in heptane can be used to separate and recycle organo- and transition metal catalysts.

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Acknowledgments

We gratefully acknowledge support by the Qatar National Research Fund (Project Number 4-081-1-016) for the studies of separable Pd(0) catalysts and the Robert A. Welch Foundation (Grant A-0639) for studies of poly(4-alkylstyrene) solubility and its use in organocatalysis. Mr. Jakkrit Suriboot is thanked for his assistance in the ICP-MS analysis of the Pd leaching.

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Authors and Affiliations

  1. Department of Chemistry, Texas A&M University, College Station, TX, 77842-3012, USA

    Tatyana V. Khamatnurova, Mitchel Johnson, David Santana & David E. Bergbreiter

  2. Department of Chemistry, Texas A&M University at Qatar, P.O. Box 23874, Doha, Qatar

    Hassan S. Bazzi

Authors
  1. Tatyana V. Khamatnurova
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  2. Mitchel Johnson
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  3. David Santana
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  4. Hassan S. Bazzi
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  5. David E. Bergbreiter
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Corresponding author

Correspondence to David E. Bergbreiter.

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Khamatnurova, T.V., Johnson, M., Santana, D. et al. Designing Phase Selectively Soluble Polymer-Supports for Dimethylaminopyridine and Phosphine-Ligated Pd(0) Catalysts. Top Catal 57, 1438–1444 (2014). https://doi.org/10.1007/s11244-014-0315-3

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  • DOI: https://doi.org/10.1007/s11244-014-0315-3

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