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Synthesis, crystal structure and magnetic properties of a new cyanide-bridged two-dimensional chromium(I)-cobalt(II) ferromagnet based on pentacyanonitrosylchromate(I)

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Abstract

A cyanide-bridged CrI–CoII heterometallic complex {[CoII(LN5)]3[CrI(CN)5(NO)]2·CH3CN·3H2O]} n (LN5 = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene) has been synthesized based on [CoII(LN5)2(H2O)2]·(ClO4)2 and the pentacyanide building block K3[CrI(CN)5(NO)]. Single-crystal X-ray diffraction analysis shows that the complex is a cyanide-bridged two-dimensional Cr I2 Co II3 complex, linked together by hydrogen bonds to form a three-dimensional network. Magnetic investigations show that the magnetic coupling between the Cr(I) and Co(II) centers through the cyanide bridges is ferromagnetic. The complex displays typical soft ferromagnet behavior with a three-dimensional ferromagnetic ordering and T c = 3.5 K.

Graphical Abstract

A new cyanide-bridged 2D Cr I2 Co II3 complex has been synthesized. Magnetic investigations show that the complex is overall ferromagnetic and exhibits typical metamagnet behaviors with T c = 3.5 K.

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Acknowledgements

This work was supported by the Fundamental Research Funds for the Central Universities (2015XKMS047) and the Priority Academic Program Development of Jiangsu Higher Education Institutions.

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Authors and Affiliations

  1. School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, 221116, Jiangsu Province, People’s Republic of China

    Lifang Zhang, Nan Li, Lu Xu & Zhonghai Ni

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  1. Lifang Zhang
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  2. Nan Li
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  3. Lu Xu
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  4. Zhonghai Ni
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Correspondence to Zhonghai Ni.

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Zhang, L., Li, N., Xu, L. et al. Synthesis, crystal structure and magnetic properties of a new cyanide-bridged two-dimensional chromium(I)-cobalt(II) ferromagnet based on pentacyanonitrosylchromate(I). Transit Met Chem 42, 435–441 (2017). https://doi.org/10.1007/s11243-017-0147-7

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