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Synthesis, structure and magnetic properties of two nickel(II) complexes of N-(pyridyl-3-sulfonyl)-l-threonine

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Abstract

Two Ni(II) complexes, [Ni2L2(H2O)4]·4H2O (1) and [Ni(HL)2(H2O)2] n ·3nH2O (2) (H2L = N-(pyridyl-3-sulfonyl)-l-threonine), were obtained from the reactions of Ni(NO3)2 with H2L in MeOH/H2O under different pH values. Upon decreasing the pH, the isolated product changed from complex 1, through a mixture of complexes 1 and 2, to at last complex 2. X-ray crystal structure studies on both complexes showed that complex 1 possesses a dinuclear structure, while complex 2 has a three-dimensional framework structure. Magnetic studies revealed the presence of dominant antiferromagnetic interactions in both complexes.

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Funding

The authors acknowledge the financial support from Guangxi Natural Science Foundation of China (Grant Number 2014GXNSFAA118035).

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Authors and Affiliations

  1. School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin, 541004, People’s Republic of China

    Hui Wang, Jiaojiao Guo, Xiaoling Xu, Pengfei Yao & Yimin Jiang

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  1. Hui Wang
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  2. Jiaojiao Guo
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  3. Xiaoling Xu
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Correspondence to Yimin Jiang.

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Wang, H., Guo, J., Xu, X. et al. Synthesis, structure and magnetic properties of two nickel(II) complexes of N-(pyridyl-3-sulfonyl)-l-threonine. Transit Met Chem 42, 293–299 (2017). https://doi.org/10.1007/s11243-017-0132-1

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  • DOI: https://doi.org/10.1007/s11243-017-0132-1

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