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Synthesis and characterization of copper(II) and nickel(II) coordination polymers containing 2,6-naphthalenedicarboxylate and bis(benzimidazole) ligands

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Abstract

Two coordination polymers, namely [Ni(L1)-(ndc)(H2O)] n (1) and [Cu(L2)0.5(ndc)] n (2) (L1 = 1,3-bis(2-methylbenzimidazol-1-ylmethyl)benzene, L2 = 1,4-bis(2-methylbenzimidazole)butane, H2ndc = 2,6-naphthalenedicarboxylic acid) have been synthesized and characterized by single-crystal and powder X-ray diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis. Complex 1 features a 2D 3-connected hcb network with 63 topology, which is further extended into a 3D supramolecular framework by O–H···O hydrogen bonding interactions. Complex 2 possesses a 3D threefold interpenetrating (4,5)-connected xah topological network, and its Schläfli symbol is (42.62.82)(46.64). Both complexes exhibit intense luminescence emissions in the solid state and promising catalytic activities for the degradation of Congo red azo dye in a Fenton-like process.

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Acknowledgments

The project was supported by the National Natural Science Foundation of China (51474086), Natural Science Foundation – Steel and Iron Foundation of Hebei Province (B2015209299)

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Authors and Affiliations

  1. College of Chemical Engineering, North China University of Science and Technology, 46 West Xinhua Road, Tangshan, 063009, Hebei, People’s Republic of China

    Gui Ying Dong, Yan Qin Zhao, Zeng Chuan Hao & Xiao Xiao Wang

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  1. Gui Ying Dong
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  2. Yan Qin Zhao
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  3. Zeng Chuan Hao
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  4. Xiao Xiao Wang
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Correspondence to Gui Ying Dong.

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Dong, G.Y., Zhao, Y.Q., Hao, Z.C. et al. Synthesis and characterization of copper(II) and nickel(II) coordination polymers containing 2,6-naphthalenedicarboxylate and bis(benzimidazole) ligands. Transition Met Chem 41, 287–294 (2016). https://doi.org/10.1007/s11243-016-0020-0

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