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Three manganese(II) coordination polymers with mixed donor ligands: synthesis, X-ray structures and luminescence properties

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Three new coordination polymers of manganese(II) of formulae [Mn3(phen)2(phdac)3]·2H2O (1), [Mn(4,4′-bipy)(H2O)4](cbprop)(2) and [Mn(2,2′-bipy)(4-nph)(H2O)2]2 (3) (phen = 1,10-phenanthroline, 4,4′-bipy = 4,4′-bipyridine, 2,2′-bipy = 2,2′-bipyridine, H2phdac = 1,4-phenylenediacetic acid, H2cbprop = 4-carboxybenzenepropanoic acid and H2nph = 4-nitrophthalic acid) have been synthesized and structurally characterized by X-ray single-crystal diffraction analysis. The metal complexes possess 2D (1), 1D (2) and 0D (3) dimensionalities. In each case, the crystal packing shows three-dimensional architecture by means of π–π interactions and/or hydrogen bonding supported by coordinated and lattice water molecules. The emission spectra show metal-perturbed intra-ligand π*–π charge transfer transitions for 1 and π*–π and π*–n charge transfer transitions for 3.

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Acknowledgments

This work was financially supported by CSIR, New Delhi, India [No. 01(2536)/11/EMR-II]. S.K.J is thankful to UGC for providing research fellowship.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Technology, Vidyasagar University, Midnapore, 721 102, West Bengal, India

    Debdoot Hazari, Swapan Kumar Jana & Sudipta Dalai

  2. Department of Chemistry, Durham University, Durham, DH13LE, UK

    Horst Puschmann

  3. Department of Chemical and Pharmaceutical Sciences, University of Trieste, 34127, Trieste, Italy

    Ennio Zangrando

Authors
  1. Debdoot Hazari
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  2. Swapan Kumar Jana
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  3. Horst Puschmann
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  4. Ennio Zangrando
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  5. Sudipta Dalai
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Correspondence to Sudipta Dalai.

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Hazari, D., Jana, S.K., Puschmann, H. et al. Three manganese(II) coordination polymers with mixed donor ligands: synthesis, X-ray structures and luminescence properties. Transition Met Chem 40, 595–604 (2015). https://doi.org/10.1007/s11243-015-9952-z

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  • DOI: https://doi.org/10.1007/s11243-015-9952-z

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